Skip to main content

Trace Metal-Sediment Dynamics in Estuaries: Pollution Assessment

  • Chapter
Reviews of Environmental Contamination and Toxicology

Part of the book series: Reviews of Environmental Contamination and Toxicology ((RECT,volume 155))

Abstract

The concentrations of trace metals vary widely in estuaries worldwide, owing to fluxes of metals from natural sources, pulsed anthropogenic inputs, changes in the extent of weathering, erosion, and runoff, complex biogeochemical processes, and a range of bioaccumulation effects that often differ markedly within these coastal ecotones. Because of large natural inputs of trace metals from the weathering and erosion of rocks, soils, and ore-bearing deposits as well as from volcanic activity and atmospheric fallout, it is difficult to assess the effects of elemental inputs from specific human activities. Historically, trace metal pollution increased most markedly in the United States between 1940 and 1970, largely because of human population development in the coastal zone and rapid industrial growth (Kennish 1992, 1994, 1997; Valette-Silver 1993).

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Agemian H, Chau ASY (1976) Evaluation of extraction techniques for the determination of metals in aquatic sediments. Analyst 101: 761–767.

    Article  CAS  Google Scholar 

  • Alexander CR, Smith RG, Calder FD, Schropp SJ, Windom HL (1993) The historical record of metal enrichment in two Florida estuaries. Estuaries 16: 627–637.

    Article  CAS  Google Scholar 

  • Aller RC (1978) Experimental studies of changes produced by deposit feeders on pore waters, sediment, and overlying water chemistry. Am J Sci 278: 1185–1234.

    Article  CAS  Google Scholar 

  • Armannson H, Burton JD, Jones GB, Knap AH (1985) Trace metals and hydrocarbons in sediments from the Southampton Water region, with particular reference to the influence of oil refinery effluent. Mar Environ Res 15: 31–44.

    Article  Google Scholar 

  • Balistrieri L, Brewer PG, Murray, JW (1981) Scavenging residence times of trace metals and surface chemistry of sinking particles in the deep ocean. Deep-Sea Res 28A: 101–121.

    Article  Google Scholar 

  • Batley GE, Gardner D (1978) A study of copper, lead, and cadmium speciation in some estuarine and coastal marine waters. Estuarine Coastal Mar Sci 7: 59–67.

    Article  CAS  Google Scholar 

  • Benjamin MM, Leckie JO (1981) Multiple-site adsorption of Cd, Cu, Zn, and Pb on amorphous iron oxyhydroxide. J Colloid Interface Sci 78: 209–221.

    Article  Google Scholar 

  • Benninger LK, Aller RC, Cochran. JK, Turekian KK (1979) Effects of biological sediment mixing on the 210Pb chronology and trace metal distribution in a Long Island Sound sediment core. Earth Planet Sci Lett 43: 241–259.

    Article  CAS  Google Scholar 

  • Bothner MH, Jahnke RA, Peterson ML, Carpenter R (1980) Rate of mercury loss from contaminated estuarine sediments. Geochim Cosmochim Acta 44: 273–285.

    Article  CAS  Google Scholar 

  • Bopp RF (1979) The geochemistry of PCB’s in the Hudson River. Ph.D. thesis, Colum-bia University, New York.

    Google Scholar 

  • Bopp RF, Simpson HJ, Chillrud SN, Robinson DW (1993) Sediment-derived chronolo-gies of persistent contaminants in Jamaica Bay, New York. Estuaries 16: 608–616.

    Article  CAS  Google Scholar 

  • Bourg ACM, Schindler PW (1978) Ternary surface complexes. 1. Complex formation in the system silica-Cu(II)-ethylenediamine. Chimia 32: 166–168.

    CAS  Google Scholar 

  • Boyle EA, Edmond JM, Sholkovitz ER (1977) The mechanism of iron removal in estuaries. Geochim Cosmochim Acta 41: 1313–1324.

    Article  CAS  Google Scholar 

  • Brannon JM, Engler RM, Rose JR, Hunt PG, Smith I (1976) Selective analytical partitioning of sediments to evaluate potential mobility of chemical constituents during dredging and disposal operations. Report D.76.7. U.S. Army Engineer Waterways Operations, Experiment Station Environmental Effects Laboratory, Vicksburg, MS.

    Google Scholar 

  • Bricker SB (1993) The history of Cu, Pb, and Zn inputs to Narragansett Bay, Rhode Island as recorded by salt-marsh sediments. Estuaries 16: 589–607.

    Article  CAS  Google Scholar 

  • Brinckman FE, Iverson WP (1975) Chemical and bacterial cycling of heavy metals in the estuarine system. In: Church TM (ed) Marine Chemistry of the Coastal Environment, Symposium Services, Vol. 18. American Chemical Society, Washington, DC, pp 319–345.

    Chapter  Google Scholar 

  • Bruland KW (1983) Trace elements in seawater. In: Riley JP, Chester R (eds) Chemical Oceanography. Academic Press, London, pp 157–220.

    Google Scholar 

  • Bruland KW, Bertine K, Koide M, Goldberg ED (1974) History of metal pollution in southern California coastal zone. Environ Sci Technol 8: 425–432.

    Article  CAS  Google Scholar 

  • Burton JD (1976) Basic properties and processes in estuarine chemistry. In: Burton JD, Liss PS (eds) Estuarine Chemistry. Academic Press, London, pp 1–17.

    Google Scholar 

  • Bryan GW (1976) Heavy metal contamination in the sea. In: Johnston RB (ed) Marine Pollution. Academic Press, London, pp 185–302.

    Google Scholar 

  • Bryan GW, Langston WJ (1992) Bioavailability, accumulation, and effects of heavy metals in sediments with special reference to United Kingdom estuaries: a review. Environ Pollut 76: 89–131.

    Article  PubMed  CAS  Google Scholar 

  • Chang LW, Furst A, Nordberg GF (eds) (1995) Toxicology of Metals, Vol. 1. General Toxicity, Carcinogenesis, and Human Exposures. CRC Press, Boca Raton, FL.

    Google Scholar 

  • Clark RB (1992) Marine Pollution, 3rd ed. Clarendon Press, Oxford.

    Google Scholar 

  • Coakley JP, Nagy E, Serodes J-B (1993) Spatial and vertical trends in sediment-phase contaminants in the upper estuary of the St. Lawrence River. Estuaries 16: 653–669.

    Article  CAS  Google Scholar 

  • Cutter GA (1991) Trace elements in estuarine and coastal waters-U.S. studies from 1986–1990. Rev Geophys Suppl, pp 639–644.

    Google Scholar 

  • Cutshall NH, Larsen IL, Nichols MM (1981) Man-made radionuclides confirm the rapid burial of kepone in the James River sediments. Science 213: 440–442.

    Article  PubMed  CAS  Google Scholar 

  • Davis JA, Leckie JO (1978a) Effect of adsorbed complexing ligands on trace metal uptake by hydrous oxides. Environ Sci Technol 12: 1309–1315.

    Article  CAS  Google Scholar 

  • Davis JA, Leckie JO (1978b) Surface ionization and complexation at the oxide/water interface. II. Surface properties of amorphous iron oxyhydroxide and adsorption of metal ions. J Colloid Interface Sci 67: 97–107.

    Article  Google Scholar 

  • Din ZB (1992) Use of aluminum to normalize heavy metal data from estuarine and coastal sediments of Straits of Melaka. Mar Pollut Bull 24: 484–491.

    Article  CAS  Google Scholar 

  • Donat JR, Bruland KW (1995) Trace metals in oceans. In: Salbu B, Steinnes E (eds) Trace Metals in Natural Waters. CRC Press, Boca Raton, FL, pp 247–281.

    Google Scholar 

  • Duinker JC (1980) Suspended matter in estuaries: adsorption and desorption processes. In: Olausson E, Cato I (eds) Chemistry and Biogeochemistry of Estuaries. Wiley, Chichester, pp 121–151.

    Google Scholar 

  • Duinker JC, Nolting RF (1976) Distribution model for particulate trace metals in the Rhine Estuary, southern Bight and Dutch Wadden Sea. Neth J Sea Res 10: 71–102.

    Article  CAS  Google Scholar 

  • Elbaz-Poulichet F, Martin JM (1987) Dissolved Cd behavior in some selected French and Chinese estuaries: consequences on Cd supply to the ocean. Mar Chem 22: 125–136.

    Article  CAS  Google Scholar 

  • Elderfield H, Sholkovitz ER (1987) Rare earth elements in the pore waters of reducing nearshore sediments. Earth Planet Sci Lett 82: 280–292.

    Article  CAS  Google Scholar 

  • Farmer JG, Lovell MA (1984) Massive diagenetic enhancement of manganese in Loch Lomond sediments. Environ Sci Technol 5: 257–262.

    CAS  Google Scholar 

  • Förstner U (1980) Inorganic pollutants, particularly heavy metals in estuaries. In: Olausson E, Cato I (eds) Chemistry and Biogeochemistry of Estuaries. Wiley, Chichester, pp 301–348.

    Google Scholar 

  • Förstner U (1982) Accumulative phases for heavy metals in limnic sediments. Hydrobiologia 91: 269–284.

    Google Scholar 

  • Förstner U, Calmano W, Conradt K, Jaksch H, Schimkus C, Schoer J (1981) Chemical speciation of heavy metals in waste materials (sewage sludge, mining waste, dredge materials, polluted sediments) by sequential extraction. In: Proceedings of the International Conference on Heavy Metals in the Environment. CEP Consultants, Edinburgh, pp 698–708.

    Google Scholar 

  • Fowler SW (1990) Critical review of selected heavy metal and chlorinated hydrocarbon concentrations in the marine environment. Mar Environ Res 29: 1–64.

    Article  CAS  Google Scholar 

  • Fox LE (1983) The removal of dissolved humic acid during estuarine mixing. Est Coastal Shelf Sci 16: 431–440.

    Article  CAS  Google Scholar 

  • Froelich PN, Bender ML, Heatch GR (1977) Phosphorus accumulation rates in metalliferous sediments on the East Pacific Rise. Earth Planet Sci Lett 34: 351–359.

    Article  CAS  Google Scholar 

  • Furness RW, Rainbow PS (eds) (1990) Heavy Metals in the Marine Environment. CRC Press, Boca Raton, FL.

    Google Scholar 

  • Gibbs RJ (1973) Mechanism of trace metal transport in rivers. Nature (Lond) 180: 71–73.

    CAS  Google Scholar 

  • Gibbs RI (1977) Transport phases of transition metals in the Amazon and Yukon Rivers. Geol Soc Am Bull 88: 829–843.

    Article  CAS  Google Scholar 

  • Gibbs RJ (1983) Coagulation rates of clay minerals and natural sediments. J Sediment Petrol 53: 1193–1203.

    CAS  Google Scholar 

  • Gibbs RJ (1986) Segregation of metals by coagulation in estuaries. Mar Chem 18: 149159.

    Google Scholar 

  • Giordano R, Musmeci L, Ciaralli L, Vemillo I, Chirico M, Piccioni A, Costantini S (1992) Total contents and sequential extractions of mercury, cadmium, and lead in coastal sediments. Mar Pollut Bull 24: 350–357.

    Article  CAS  Google Scholar 

  • Goldberg ED, Griffin JJ, Hodge V, Koide M (1979) Pollution history of the Savannah River estuary. Environ Sci Technol 13: 588–593.

    Article  CAS  Google Scholar 

  • Graham WF, Bender ML, Klinkhammer GP (1976) Manganese in Narragansett Bay. Limnol Oceanogr 21: 665–673.

    Article  CAS  Google Scholar 

  • Greenaway AM, Rankine-Jones AI (1992) Elemental concentrations in coastal sediments from Hellshire, Jamaica Mar Pollut Bull 24: 390–394.

    Article  CAS  Google Scholar 

  • Gunther AJ, Davis JA, Phillips DJH (1987) An assessment of the loading of toxic contaminants to the San Francisco Bay-Delta. Technical report, Aquatic Habitat Institute, Richmond, CA.

    Google Scholar 

  • Hart BT, Davies SHR (1981) Trace metal speciation in the freshwater and estuarine regions of the Yarra River, Victoria. Estuarine Coastal Shelf Sci 12: 353–365.

    Article  Google Scholar 

  • Head PC (1985) Practical Estuarine Chemistry: A Handbook. Cambridge University Press, London.

    Google Scholar 

  • Hedges JI (1977) The association of organic molecules with clay minerals in aqueous solutions. Geochim Cosmochim Acta 41: 1119–1123.

    Article  CAS  Google Scholar 

  • Helz GR, Sinex SA (1986) Influence of infrequent floods on the trace metal composition of estuarine sediments. Mar Chem 20: 1–11.

    Article  CAS  Google Scholar 

  • Helz GR, Sinex SA, Ferri KL, Nichols M (1985) Processes controlling Fe, Mn, and Zn in sediments of northern Chesapeake Bay. Estuarine Coastal Shelf Sci 21: 1–16.

    Article  CAS  Google Scholar 

  • Hines ME, Lyons WB, Spencer MJ, Jones, GE (1983) Temporal and vertical sulfate reduction and metal remobilization in estuarine sediments. Estuaries 6: 295–307.

    Google Scholar 

  • Huggett RJ, Bender ME (1980) Kepone in the James River. Environ Sci Technol 14: 918–923.

    Article  PubMed  CAS  Google Scholar 

  • Hung J-J, Shy C-P (1995) Speciation of dissolved selenium in the Kaoping and Erhjen rivers and estuaries, southwestern Taiwan. Estuaries 18: 234–240.

    Article  CAS  Google Scholar 

  • Hunter KA, Liss PS (1979) The surface charge of suspended particles in estuarine and coastal waters. Nature (Lond) 282: 823–825.

    Article  CAS  Google Scholar 

  • Hunter KA, Liss PS (1982) Organic matter and the surface charge of suspended particles in estuarine waters. Limnol Oceanogr 27: 322–335.

    Article  CAS  Google Scholar 

  • Jenne EA (1977) Trace element sorption by sediments and soil. In: Chappell W, Petersen SK (eds) Sites and Processes. Proceedings, Symposium on Molybdenum in the Environment, Vol. 2. Dekker, New York, pp 425–553.

    Google Scholar 

  • Katz A, Kaplan IR (1981) Heavy metals behavior in coastal sediments of Southern California: a critical review and synthesis. Mar Chem 10: 261–299.

    Article  CAS  Google Scholar 

  • Kennish MJ (1986) Ecology of Estuaries, Vol. 1, Chemical and Physical Aspects. CRC Press, Boca Raton, FL.

    Google Scholar 

  • Kennish MJ (1990) Ecology of Estuaries, Vol. 2. Biological Aspects. CRC Press, Boca Raton, FL.

    Google Scholar 

  • Kennish MJ (1992) Ecology of Estuaries: Anthropogenic Aspects. CRC Press, Boca Raton, FL.

    Google Scholar 

  • Kennish MJ (ed) (1994) Practical Handbook of Marine Science, 2nd ed. CRC Press, Boca Raton, FL.

    Google Scholar 

  • Kennish MJ (ed) (1997) Practical Handbook of Estuarine and Marine Pollution. CRC Press, Boca Raton, FL.

    Google Scholar 

  • Kersten M, Forstner U (1987) Effect of sample pretreatment on the reliability of solid speciation data of heavy metals-implications for the study of early diagenetic processes. Mar Chem 22: 299–312.

    Article  CAS  Google Scholar 

  • Kramer CJM, Duinker JC (eds) (1984) Complexation of Trace Metals in Natural Waters. Junk, The Hague, Netherlands.

    Google Scholar 

  • Kranck K (1974) The role of flocculation in the transport of particulate pollutants in the marine environment. In: Proceedings of the International Conference of Persistent Chemicals in Aquatic Ecosystems. National Research Council, Ottawa, pp 41–46.

    Google Scholar 

  • Kranck K (1975) Sediment deposition from flocculated suspensions. Sedimentology 22: 111–123.

    Article  Google Scholar 

  • Kranck K (1981) Particulate matter grain-size characteristics and flocculation in a partially mixed estuary. Sedimentology 28: 107–114.

    Article  Google Scholar 

  • Langston WJ (1986) Metals in sediments and benthic organisms in the Mersey estuary. Estuarine Coastal Shelf Sci 23: 239–261.

    Article  CAS  Google Scholar 

  • Langston WJ (1990) Toxic effects of metals and the incidence of metal pollution in marine ecosystems. In: Furness RW, Rainbow PS (eds) Heavy Metals in the Marine Environment. CRC Press, Boca Raton, FL, pp 101–122.

    Google Scholar 

  • Larson R, Morang A, Gorman L (1997) Monitoring the coastal environment; Part II: Sediment sampling and geotechnical methods. J Coastal Res 13: 308–330.

    Google Scholar 

  • Lindberg SE, Harriss RC (1977) Release of mercury organics from resuspended near-shore sediments. J Water Pollut Control Fed 1977: 2479–2487.

    Google Scholar 

  • Lion LW, Altmann RS, Leckie JO (1982) Trace-metal adsorption characteristics of estuarine particulate matter: evaluation of contributions of Fe/Mn oxide and organic surface coatings. Environ Sci Technol 16: 660–666.

    Article  CAS  Google Scholar 

  • Loring DH (1991) Normalization of heavy metal data from estuarine and coastal sediments. ICES (Int Counc Explor Sea) J Mar Sci 48: 101–115.

    Article  Google Scholar 

  • Loring DH, Rantala RTT (1988) An intercalibration exercise for trace metals in marine sediments. Mar Chem 24: 13–27.

    Article  CAS  Google Scholar 

  • Luoma SN (1983) Bioavailability of trace metals to aquatic organisms-a review. Sci Total Environ 28: 1–22.

    Article  PubMed  CAS  Google Scholar 

  • Luoma SN (1986) A comparison of two methods for determining copper partitioning in oxidized sediments. Mar Chem 20: 45–59.

    Article  CAS  Google Scholar 

  • Luoma SN, Bryan GW (1981) A statistical assessment of the form of trace metals in oxidized estuarine sediments employing chemical extractants. Sci Total Environ 17: 165–196.

    Article  CAS  Google Scholar 

  • Luoma SN, Davis JA (1983) Requirements for modeling trace metal partitioning in oxidized estuarine sediments. Mar Chem 12: 159–181.

    Article  CAS  Google Scholar 

  • Luoma SN, Dagovitz R, Artmann E (1990) Temporally intensive study of trace metals in sediments and bivalves from a large river-estuarine system: Suisun Bay/Delta in San Francisco Bay. Sci Total Environ 97 /98: 685–712.

    Article  PubMed  Google Scholar 

  • Lyman WJ, Glazer AE, Ong JH, Coons SF (1987) An overview of sediment quality in the United States. EPA–905/9–88–002. Office of Water Regulations and Standards, U.S. Environmental Protection Agency, Washington, DC.

    Google Scholar 

  • Lyngby JE, Brix H (1987) Monitoring of heavy metal contamination in the Lim-fjord, Denmark, using biological indicators and sediment. Sci Total Environ 64: 239–252.

    Article  CAS  Google Scholar 

  • Malo BA (1977) Partial extraction of metals from aqueous sediments. Environ Sci Technol 11: 277–282.

    Article  CAS  Google Scholar 

  • Martin JM, Nirel P, Thomas Ai (1987) Sequential extraction techniques: promises and problems. Mar Chem 22: 313–341.

    Article  CAS  Google Scholar 

  • Mayer LM (1982) Aggregation of colloidal iron during estuarine mixing: kinetics, mechanism, and seasonality. Geochim Cosmochim Acta 46: 2527–2535.

    Article  CAS  Google Scholar 

  • McLerran CJ, Holmes CW (1975) Deposition of Zn and Cd by marine bacteria in estuarine sediments. Limnol Oceanogr 19: 998–1005.

    Article  Google Scholar 

  • Meade RH (1972) Transport and deposition of sediments in estuaries. In: Nelson BW (ed) Environmental Framework of Coastal Plain Estuaries. Geol Soc Am Mem 133: 91–120.

    Google Scholar 

  • Millward GE, Turner A (1995) Trace metals in estuaries. Salbu B, Steinnes E (eds) Trace Metals in Natural Waters. CRC Press, Boca Raton, FL, pp 223–245.

    Google Scholar 

  • Morris AW, Mantoura RFC, Bale AJ, Howland RJM (1978) Very low salinity regions of estuaries: important sites for chemical and biological reactions. Nature (Lond) 274: 678–680.

    Article  CAS  Google Scholar 

  • Morris AW, Bale AJ, Howland RJM (1982) The dynamics of estuarine manganese cycling. Estuarine Coastal Shelf Sci 14: 175–192.

    Article  CAS  Google Scholar 

  • Murray JW (1975) The interaction of cobalt with hydrous manganese dioxide. Geochim Cosmochim Acta 39: 635–647.

    Article  CAS  Google Scholar 

  • Murray S, Mayer LM (1986) Retention of Co-60 by the sediments of Montsweag Bay, Maine. Mar Environ Res 18: 29–41.

    Article  CAS  Google Scholar 

  • Nair CK, Balchand AN (1993) Speciation of trace metals in sediments of a tropical estuary. Environ Geol 21: 96–102.

    Article  Google Scholar 

  • Nair CK, Balchand AN, Nambisan PK (1991) Heavy metal speciation in sediments of Cochin estuary determined using chemical extraction techniques. Sci Total Environ 102: 113–128.

    Article  CAS  Google Scholar 

  • National Oceanic and Atmospheric Administration (NOAA) (1991) National Status and Trends Program. Second summary of data on chemical contaminants in sediments from the National Status and Trends Program. NOAA Tech. Mem. NOS OMA 59. U.S. Department of Commerce, National Ocean Service, Rockville, MD.

    Google Scholar 

  • Niencheski LF, Windom HL, Smith R (1994) Distribution of particulate trace metal in Patos Lagoon estuary (Brazil). Mar Pollut Bull 28: 96–108.

    Article  CAS  Google Scholar 

  • Olsen CR, Simpson HJ, Bopp RF, Williams SC, Peng TH, Deck BL (1978) Geochemical analysis of the sediments and sedimentation in the Hudson estuary. J Sediment Petrol 48: 401–418.

    CAS  Google Scholar 

  • Olsen CR, Biscaye PE, Simpson HT, Trier RM, Kostyk N, Bopp RF, Li Y-H, Feely HW (1980) Reactor-released radionuclides and fine-grained sediment transport and accumulation patterns in Barnegat Bay, New Jersey, and adjacent shelf waters. Estuarine Coastal Mar Sci 10: 119–142.

    Article  CAS  Google Scholar 

  • Olsen CR, Simpson HJ, Trier RM (1981) Plutonium, radiocesium and radiocobalt in the sediments of the Hudson River estuary. Earth Planet Sci Lett 55: 377–392.

    Article  CAS  Google Scholar 

  • Olsen CR, Cutshall NH, Larsen IL (1982) Pollutant-particle associations and dynamics in coastal marine environments: a review. Mar Chem 11: 501–533.

    Article  CAS  Google Scholar 

  • Olsen CR, Thein M, Larsen IL, Lowry PD, Mulholland Pi, Cutshall NH, Byrd JT, Windom HL (1989) Plutonium, 2 0Pb and stable isotopes in the Savannah estuary: river-borne versus marine sources. Environ Sci Technol 23: 1475–1481.

    Article  CAS  Google Scholar 

  • Olsen CR, Larsen IL, Mulholland PJ, von Damm KL, Shaffner LC, Diaz RJ, Nichols MM (1993) The concept of an equilibrium surface applied to particle sources and contaminant distributions in estuarine sediments. Estuaries 16: 683–696.

    Article  CAS  Google Scholar 

  • Paalman MAA, Van der Weijden CH, Lock WO (1994) Sorption of cadmium on suspended matter under estuarine conditions: competition and complexation with major seawater ions. Water Air Soil Pollut 73: 49–60.

    Article  CAS  Google Scholar 

  • Panutrakul S, Baeyens W (1991) Behavior of heavy metals in a mud flat of the Scheldt estuary, Belgium. Mar Pollut Bull 22: 128–134.

    Article  CAS  Google Scholar 

  • Paulson Ai, Feely RA, Curl HC Jr, Tennant DA (1989) Estuarine transport of trace metals in a buoyant riverine plume. Estuarine Coastal Shelf Sci 28: 231–248.

    Article  CAS  Google Scholar 

  • Pickering WF (1981) Selective chemical extraction of soil components and bound metal species. Crit Rev Anal Chem 2: 233–266.

    Article  Google Scholar 

  • Postma H (1980) Sediment transport and sedimentation. In: Olausson E, Cato I (eds) Chemistry and Biogeochemistry of Estuaries. Wiley, Chichester, pp 153–186.

    Google Scholar 

  • Prange A, Niedergesäss R, Schnier C (1990) Multielement determination of trace elements in estuaries by TXRF and INAA. In: Michaelis W (ed) Estuarine Water Quality Management. Coastal and Estuarine Studies, Vol. 36. Springer-Verlag, Berlin, pp 429–445.

    Google Scholar 

  • Presley BJ, Trefry JH, Shokes RF (1980) Heavy metal inputs to Mississippi delta sediment. Water Air Soil Pollut 13: 481–494.

    Article  CAS  Google Scholar 

  • Prohic E, Kniewald G (1987) Heavy metal distribution in recent sediments of the Krka River estuary-an example of sequential extraction analysis. Mar Chem 22: 279–297.

    Article  CAS  Google Scholar 

  • Rae JE, Allen JRL (1993) The significance of organic matter degradation in the interpretation of historical pollution trends in depth profiles of estuarine sediment. Estuaries 16: 678–682.

    Article  CAS  Google Scholar 

  • Regnier P, Wollast R (1993) Distribution of trace metals in suspended matter of the Scheldt estuary. Mar Chem 43: 3–19.

    Article  CAS  Google Scholar 

  • Reuter JH (1977) Organic matter in estuaries. Chesapeake Sci 18: 120–127.

    Article  CAS  Google Scholar 

  • Reuter JH, Perdue EM (1977) Importance of heavy metal–organic matter interactions in natural waters. Geochim Cosmochim Acta 41: 325–334.

    Article  CAS  Google Scholar 

  • Rowlatt SM, Lovell DR (1994) Lead, zinc, and chromium in sediments around England and Wales. Mar Pollut Bull 28: 324–330.

    Article  CAS  Google Scholar 

  • Salbu B, Steinnes E (eds) (1995) Trace Elements in Natural Waters. Lewis, Boca Raton, FL.

    Google Scholar 

  • Santschi PH (1984) Particle flux and trace metal residence time in natural waters Limnol Oceanogr 29: 1100–1108.

    CAS  Google Scholar 

  • Santschi PH, Adler D, Admurer M, Li Y-H, Bell J (1980a) Thorium isotopes as analogues for “particle-reactive” pollutants in coastal marine environments. Earth Planet Sci Lett 47: 327–335.

    Article  CAS  Google Scholar 

  • Santschi PH, Li Y-H, Bell JJ, Trier RM, Kowtaluk K (1980b) Plutonium in coastal marine environments. Earth Planet Sci Lett 51: 248–265.

    Article  CAS  Google Scholar 

  • Santschi PH, Nixon S, Pilson M, Hunt C (1984) Accumulation of sediments, trace metals (Pb, Cu), and total hydrocarbons in Narragansett Bay, Rhode Island. Estuarine Coastal Shelf Sci 19: 427–449.

    Article  CAS  Google Scholar 

  • Schnitzer M, Kahn SU (1972) Humic Substances in the Environment. Dekker, New York.

    Google Scholar 

  • Schropp SJ, Lewis FG, Windom HL, Ryan JD, Calder FD, Burney LC (1990) Interpreta- tion of metal concentrations in estuarine sediments of Florida using aluminum as a reference element. Estuaries 13: 227–235.

    Article  CAS  Google Scholar 

  • Sholkovitz ER (1976) Flocculation of dissolved and inorganic matter during the mixing of river water and seawater. Geochim Cosmochim Acta 40: 831–845.

    Article  CAS  Google Scholar 

  • Sinex SA, Wright DA (1988) Distribution of trace metals in the sediments and biota of Chesapeake Bay. Mar Pollut Bull 19: 425–431.

    Article  CAS  Google Scholar 

  • Sinex WA, Cantillo ZY, Helz GR (1980) Accuracy of acid extraction methods for trace metals in sediments. Anal Chem 52: 2342–2346.

    Article  CAS  Google Scholar 

  • Spencer DW, Bacon MP, Brewer PG (1981) Models of the distribution of Pb in a section across the North Equatorial Atlantic Ocean. J Mar Res 39: 119–138.

    CAS  Google Scholar 

  • Stevenson FJ (1982) Humus Chemistry. Wiley, New York.

    Google Scholar 

  • Stickney RR (1984) Estuarine Ecology of the Southeastern United States and Gulf of Mexico. Texas A & M University Press, College Station, TX.

    Google Scholar 

  • Summers JK, Wade TL, Engle VD, Malaeb ZA (1996) Normalization of metal concen- trations in estuarine sediments from the Gulf of Mexico. Estuaries 19: 581–594.

    Article  CAS  Google Scholar 

  • Tessier A, Turner D (eds) (1995) Metal Speciation and Bioavailability. Lewis, Boca Raton, FL.

    Google Scholar 

  • Tessier A, Campbell PGC, Bisson M (1979) Sequential extraction procedure for the speciation of particulate trace metals. Anal Chem 51: 844–850.

    Article  CAS  Google Scholar 

  • Thomson J, Turekian KK, McCaffrey RI (1975) The accumulation of metals and release from sediments of Long Island Sound. In: Cronin LE (ed) Estuarine Research. Academic Press, New York, pp 28–44.

    Google Scholar 

  • Tipping E (1981) The adsorption of aquatic humic substances by iron oxides. Geochim Cosmochim Acta 45: 191–199.

    Article  CAS  Google Scholar 

  • Trefry JH (1977) The transport of heavy metals by the Mississippi River and their fate in the Gulf of Mexico. Ph.D. thesis, Texas A & M University, College Station, TX.

    Google Scholar 

  • Trefry JH, Metz S, Trocine RP, Nelsen TA (1985) A decline in lead transport by the Mississippi River. Science 230: 439–441.

    Article  PubMed  CAS  Google Scholar 

  • Turekian KK (1977) The fate of metals in the ocean. Geochim Cosmochim Acta 41: 1139–1144.

    Article  CAS  Google Scholar 

  • Valette-Silver NJ (1992) Historical reconstruction of contamination using sediment cores. Tech. Mem. NOS/ORCA 65. National Oceanic and Atmospheric Administration, Rockville, MD.

    Google Scholar 

  • Valette-Silver NJ (1993) The use of sediment cores to reconstruct historical trends in contamination of estuarine and coastal sediments. Estuaries 16: 577–588.

    Article  CAS  Google Scholar 

  • Valette-Silver NJ, Bricker SB, Salomon W (1993) Historical trends in contamination of estuarine and coastal sediments: an introduction to the dedicated issue. Estuaries 16: 575–576.

    Article  Google Scholar 

  • van den Berg CMG (1984) Determination of the complexing capacity and conditional stability constants of complexes of copper(II) with natural organic ligands in seawater by cathodic stripping voltammetry of copper—catechol complex ions. Mar Chem 15: 1–18.

    Article  Google Scholar 

  • van den Berg CMG (1993) Complex formation and the chemistry of selected trace elements in estuaries. Estuaries 16: 512–520.

    Article  Google Scholar 

  • van den Berg CMG, Khan SH, Daly PJ, Riley JP, Turner DR (1991) An electrochemical study of Ni, Sb, Se, Sn, U, and V in the estuary of the Tamar. Estuarine Coastal Shelf Sci 33: 309–322.

    Article  Google Scholar 

  • van der Sloot HA, Hoede D, Wijkstra J, Duinker JC, Nolting RF (1985) Anionic species of V, As, Se, Mo, Sb, Te, and W in the Scheldt and Rhine estuaries and the Southern Bight (North Sea). Estuarine Coastal Shelf Sci 21: 633–651.

    Article  Google Scholar 

  • Van Valin R, Morse JW (1982) An investigation of methods commonly used for the selective removal and characterization of trace metals in sediments. Mar Chem 11: 535–564.

    Article  Google Scholar 

  • Velinsky DJ, Wade TL, Schlekat CE, McGee BL, Presley BJ (1994) Tidal river sediments in the Washington, DC area. I. Distribution and sources of trace metals. Estuaries 17: 305–320.

    Article  CAS  Google Scholar 

  • Williams JDH, Jacquet JM, Thomas RL (1976) Form of phosphorus in the surficial sediments of Lake Erie. J Fish Res Board Can 33: 413–429.

    Article  CAS  Google Scholar 

  • Williams SC, Simpson HJ, Olsen CR, Bopp RF (1978) Sources of heavy metals in sediments of the Hudson River estuary. Mar Chem 6: 195–213.

    Article  CAS  Google Scholar 

  • Windom HL, Smith R Jr, Rawlinson C, Hungspreugs M, Dharmvanij S, Wattayakorn G (1988) Trace metal transport in a tropical estuary. Mar Chem 24: 293–305.

    Article  CAS  Google Scholar 

  • Windom HL, Schropp SJ, Calder FD, Ryan JD, Smith RG Jr, Burney LC, Lewis FG, Rawlinson CH (1989) Natural trace metal concentrations in estuarine and coastal marine sediments of the southeastern United States. Environ Sci Technol 23: 314–320.

    Article  CAS  Google Scholar 

  • Windom HL, Byrd J, Smith R Jr, Hungspreugs M, Dharmvanij S, Thumtrakul W, Yeats P (1991) Trace metal nutrient relationships in estuaries. Mar Chem 32: 177–194.

    Article  CAS  Google Scholar 

  • Zhang J, Huang WW, Martin JM (1988) Trace metals distribution in Huanghe (Yellow River) estuarine sediments. Estuarine Coastal Shelf Sci 26: 499–516.

    Article  CAS  Google Scholar 

  • Zwolsman JJG, van Eck GTM (1990) The behavior of dissolved Cd, Cu, and Zn in the Scheldt estuary. In: Michaelis W (ed) Estuarine Water Quality Management. Coastal and Estuarine Studies, Vol. 36. Springer-Verlag, Berlin, pp 413–428.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

George W. Ware

Rights and permissions

Reprints and permissions

Copyright information

© 1998 Springer Science+Business Media New York

About this chapter

Cite this chapter

Kennish, M.J. (1998). Trace Metal-Sediment Dynamics in Estuaries: Pollution Assessment. In: Ware, G.W. (eds) Reviews of Environmental Contamination and Toxicology. Reviews of Environmental Contamination and Toxicology, vol 155. Springer, New York, NY. https://doi.org/10.1007/978-1-4612-1684-1_2

Download citation

  • DOI: https://doi.org/10.1007/978-1-4612-1684-1_2

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4612-7244-1

  • Online ISBN: 978-1-4612-1684-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics