Emerging contaminants such as pharmaceuticals and biocides are released from sewage treatment plants and also from agricultural fields. They are increasingly monitored in surface and groundwater but are not yet included as priority compounds in European guidelines. Analysis of these mostly polar compounds and their sometimes relevant metabolites is more and more carried out by LC-MS-MS. The main elimination processes in sewage treatment plants are sorption and biodegradation. Both processes are difficult to predict in case of polar compounds and therefore fate studies are essential.
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References
Bester, K., 2006, Personal Care Compounds in the Environment Pathways, Fate and Methods for Determination ISBN-13: 978-3-527-31567-3 published by Wiley-VCH, Weinheim.
BLAC-Report, Pharmaceuticals in the environment (in German), 2003, http://fhh.hamburg.de/stadt/Aktuell/behoerden/bsg/hygiene-umwelt/umwelt/chemikalien/arznei03-pdf,property =source.pdf.
Blüm, W., McArdell, C.S., Hoehn, E., Schaubhut, R., Labhart, W., and Bertschi, S., 2005, Organische Spurenstoffe im Grundwasser des Limmattales: Ergebnisse der Untersuchungskampagne 2004. Zürich: Baudirektion Kanton Zürich, AWEL.
Bendz, D., Paxéus, N.A., Ginn, T.R., and Loge, F.J., 2005, Occurrence and fate of pharmaceutically active compounds in the environment, a case study: Höje River in Sweden. J. Hazard. Mat. 122: 195-204.
Boxall, A.B., Sinclair, C.J., Fenner, K., Kolpin, D., and Maund, S.J., 2004, When synthetic chemicals degrade in the environment. Environ. Sci. Technol. 38: 369A-375A.
Buerge, I.J., Poiger, T., Müller, M.D., and Buser, H.-D., 2006, Combined sewer overflows to surface waters detected by the anthropogenic marker caffeine Environ. Sci. Technol. 40: 4096-4102.
D’Ascenzo, G., Di Corcia, A., Gentili, A., Mancini, R., Mastropasqua, R., Nazzari, M., and Samperi, R., 2005, Fate of natural estrogen conjugates in municipal sewage transport and treatment facilities. Sci. Tot. Environ. 302: 199-209.
Draft proposal to Directive 2000/60/EC, 26.03.2007, http://www.europarl.europa.eu/meetdocs/2004_2009/documents/dv/659/659305/659305en.pdf
Gerecke, A.C., Schärer, M., Singer, H.P., Müller, S.R., Schwarzenbach, R.P., Sägesser, M., Ochsenbein, U., and Popow, G., 2002, Sources of pesticides in surface waters in Switzerland: pesticide load through waste water treatment plants - current situation and reduction potential. Chemosphere 48: 307-315.
Giger, W., Schaffner C., and Kohler H.-P., 2006, Benzotriazole and Tolyltriazole as aquatic contaminants. I. Input and occurrence in rivers and lakes. Environ. Sci. Technol. 40: 7186-7192.
Göbel A., McArdell C.S., Joss A., Siegrist H., and Giger W., 2007, Fate of sulfonamides, macrolides, and trimethoprim in different wastewater treatment technologies. Sci. Tot. Environm. 372: 361-371.
Göbel, A., Thomsen, A., McArdell, C.S., Joss, A., and Giger, W., 2005, Occurrence and sorption behavior of sulfonamides, macrolides, and trimethoprim in activated sludge treatment, Environ. Sci. Technol. 39: 3981-3989.
Golet, E.M., Xifra, I., Siegrist, H., Alder, A.C., and Giger, W., 2003, Environmental exposure assessment of fluoroquinolone antibacterial agents from sewage to soil. Environ. Sci. Technol. 37: 3243-3249.
Hanke, I., Singer, H., McArdell, C.S., Brennwald, M., Traber, D., Muralt, R., Herold, T., Oechslin, R., and Kipfer, R., 2007, Arzneimittel und Pestizide im Grundwasser. GWA 3: 187-196.
Hernández, F., Ibánez, M., Sancho, J.V., and Pozo, O.J., 2004, Comparison of different mass spectrometric techniques combined with liquid chromatography for confirmation of 21 pesticides in environmental water based on the use of identification points. Anal. Chem. 76: 4349-4357.
Hernández, F., Pozo, Ó.J., Sancho, J.V., López, F.J., MarÃn, J.M., and Ibánez, M., 2005, Strategies for quantification and confirmation of multi-class polar pesticides and transformation products in water by LC-MS2 using triple quadrupole and hybrid quadrupole time-of-flight analyzers. TrAC 24: 596-612.
Hollender, J., Singer, H., and Fenner, K., 2006, Combination of linear ion trap with Orbitrap technology to detect and identify metabolites in environmental water samples, in: Proc. 2nd Int. Workshop Liq. Chromatogr.-Tandem Mass Spectrom. Screening Trace Level Quantitation Environ. Food Samples, Barcelona, Spain, September 2006, p. 34.
Hou, B.K., Wackett, L.P., and Ellis, L.B.M., 2003, Microbial pathway prediction: A functional group approach. J. Chem. Inf. Comp. Sci. 43: 1051-1057.
Hu, Q., Noll, R.J., Li, H., Makarov, A., Hardman, M., and Cooks, R.G., 2005, The Orbitrap: A new mass spectrometer. J. Mass Spectrom. 40: 430-443.
Hummel, D., Löffler, D., Fink, G., and Ternes, T.A., 2006, Simultaneous determination of psychoactive drugs and their metabolites in aqueous matrices by liquid chromatography mass spectrometry Environ. Sci. Technol. 40: 7321-7328.
Jahnel, J., Neamtu, M., Schudoma, D., and Frimmel, F.H., 2006, Scientific risk assessment of considered water relevant substances. Acta hydrochim. hydrobiol. 34: 389-397.
Jaworska, J., Dimitrov, S., Nikolova, N., and Mekenyan, O., 2002, Probabilistic assessment of biodegradability based on metabolic pathways: Catabol system. SAR QSAR Environ. Res. 13: 307-323.
Joss, A., Keller, E., Alder, A.C., Göbel, A., McArdell, C.S., Ternes, T., and Siegrist, H., 2005, Removal of pharmaceuticals and fragrances in biological wastewater treatment. Wat. Res. 39: 3139-3152.
Kolpin, D.W., Schnoebelen, D.J., and Thurman, E.M., 2004, Degradates provide insight to spatial and temporal trends of herbicides in ground water. Ground Water 42: 601-608.
Kolpin, D.W., Kalkhoff, S.J., Goolsby, D.A., Sneck-Fahrer, D.A., and Thurman, E.M., 1997, Occurrence of selected herbicides and herbicide degradation products in Iowa’s Grond Water, 1995. Groundwater 35: 679-688.
Kolpin, D.W., Furlong, E.T., Meyer, M.T., Thurman, E.M., Zaugg, S.D., Barber, L.B., and Buxton, H.T., 2002, Pharmaceuticals, hormones, and other organic wastewater contaminants in U.S. streams, 1999-2000: A national reconnaissance. Env. Sci. Technol. 36: 1202-1211.
Leu, C., Singer, H., Stamm, C., Müller, S.R., and Schwarzenbach, R.P., 2004, Variability of herbicide losses from 13 fields to surface water within a small catchment after a controlled herbicide application. Environ. Sci. Technol. 38: 3835-3841.
Makarov, A., Denisov, E., Kholomeev, A., Balschun, W., Lange, O., Strupat, K., and Horning, S., 2006, Performance evaluation of a hybrid linear ion trap/orbitrap mass spectrometer. Anal. Chem. 78: 2113-2120.
McArdell, C.S., Alder, A.C., Göbel, A., Löffler, D., Suter, M.J.F., and Ternes, T.A., 2007, Analytical Methods. In Human Pharmaceuticals, Hormones and Fragrances: The challenge of micropollutants in urban water management edited by Ternes, T.A., Joss, A. ISBN: 1843390930. Published by IWA Publishing, London, UK.
Miao, X.-S., Yang, J.-J., and Metcalfe, C.D., 2005, Carbamazepine and its metabolites in wastewater and in biosolids in a municipal wastewater treatment plant. Environ. Sci. Technol. 39: 469-7475.
Muir, D.C.G., and Howard, P.H., 2006, Are there other persistent organic pollutants? A challenge for environmental chemists. Environ. Sci. Technol. 40: 7157-7166.
Öllers, S., Singer, H.P., Fässler, P., and Müller, S.R., 2001, Simultaneous quantification of neutral and acidic pharmaceuticals and pesticides at the low-ng/ l level in surface and waste water J. Chromatogr. A 911: 225-234.
Ort, C., McArdell, C.S., and Giger, W., 2007, Benzotriazole and Tolyltriazole as Aquatic Contaminants: Tracers for Municipal Wastewater Infiltration into Groundwater. In preparation
Reemtsma, T., Weiss, S., Müeller, J., Petrovic, M., Gonzalez, S., Barcelo, D., Ventura, F., and Knepper, T.P., 2006, Polar pollutants entry into the water cycle by municipal wastewater: A european perspective. Environ. Sci. Technol. 40: 5451-5458.
Richardson, S.D., Ternes, T.A., 2005, Water Analysis: Emerging contaminants and current issues. Anal. Chem. 77: 3807-3838.
Sacher, F., Lange, F.G., Brauch, H.-J., and Blankenhorn, I., 2001. Pharmaceuticals in groundwaters. Analytical methods and results of a monitoring program in Baden-Württemberg, Germany. J. Chromatrogr. A 938: 199-210.
Schluep, M., Thomann, M., Häner, A., and Gälli, R., 2006, Organische Mikroverunreinigungen und Nährstoffhaushalt. Eine Standortbestimmung für die Siedlungswasserwirtschaft. UmwetlWissen Nr. 0614. Bundesamt für Umwelt, Bern.
Schwaiger, J., Ferling, H., Mallow, U., Wiontermayer, H., and Negele, R.D., 2004, Toxic effects of the non-steroidal anti-inflammatory drug diclofenac. Part I: Histopathological alterations and bioaccumulation in rainbow trout. Aquatic Toxicol. 68: 141-150.
Stamm Ch., Siber, R., Chèvre, N., Fenner, K., and Singer, H., 2006, Monitoring von Pestizidbelastungen in Oberflächengewässern, GWA Gas, Wasser, Abwasser 8: 629-636.
Stoob, K., Singer, H.P., Stettler, S., Hartmann, N., Mueller, S.R., and Stamm C.H., 2006, Exhaustive extraction of sulfonamide antibiotics from aged agricultural soils using pressurized liquid extraction J. Chromatgr. A 1128: 1-9.
Ternes, T.A., 1998, Occurrence of drugs in German sewage treatment plants and rivers. Wat. Res. 32: 3245-3260.
Ternes, T.A., Joss, A., and Siegrist, H., 2004, Scrutinizing Pharmaceuticals and personal care products in Wastewater Treatment. Environ. Sci. Technol. 38: 392A-399A.
Ternes, T.A., and Joss, A., 2007, Human Pharmaceuticals, Hormones and Fragrances: The challenge of micropollutants in urban water management edited by. ISBN: 1843390930. Published by IWA Publishing, London, UK
TGD, 1996, Technical guidance document in support of commission directive 93/67/EEC on risk assessment for new notified substances and commission regulation, EC, No 1488/94 on risk assessment of existing substances, Part II, Brussels, ISBN 92-827-8012-0.
Thurman, E.M., Ferrer, I., Zweigenbaum, J.A., GarcÃa-Reyes, J.F., Woodman, M., and Fernández-Alba, A.R., 2005, Discovering metabolites of post-harvest fungicides in citrus with liquid chromatography/time-of-flight mass spectrometry and ion trap tandem mass spectrometry. J. Chromatogr. A 1082: 71-80.
Triebskorn, R., Casper H., Heyd, A., Eikemper, R., Köhler, H.R., and Schwaiger, J., 2004, Toxic effects of the non-steroidal anti-inflammatory drug diclofenac. Part II: Cytological effects in liver, kidney, gills and intestine of rainbow trout (Oncorhynchus mykiss). Aquatic Toxicol. 68: 151-168.
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Hollender, J., Singer, H., McArdell, C.S. (2008). Polar Organic Micropollutants In The Water Cycle. In: Hlavinek, P., Bonacci, O., Marsalek, J., Mahrikova, I. (eds) Dangerous Pollutants (Xenobiotics) in Urban Water Cycle. NATO Science for Peace and Security Series. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-6795-2_11
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