Abstract
Processes of hydrogen electrochemical intercalation into layered InSe and GaSe crystals and its deintercalation were investigated. It was ascertained that for concentrations x<2 hydrogen mainly enters in interlayer space and forms H2 molecules, where is the amount of introduced atoms per one formula unit of the crystal bulk. For 2<x<4 atomic hydrogen being built into interstices due to quantum-size effects for the gap and H2 molecules.
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ZHIRKO, Y.I., KOVALYUK, Z., PYRLJA, M., BOLEDZYUK, V. (2007). APPLICATION OF LAYERED InSe AND GaSe CRYSTALS AND POWDERS FOR SOLID STATE HYDROGEN STORAGE. In: Veziroglu, T.N., et al. Hydrogen Materials Science and Chemistry of Carbon Nanomaterials. NATO Security through Science Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-5514-0_43
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DOI: https://doi.org/10.1007/978-1-4020-5514-0_43
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