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Novel Approaches in Spectroscopy of Interparticle Inter-Actions. Vibrational Line Profiles and Anomalous Non-Coincidence Effects

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Novel Approaches to the Structure and Dynamics of Liquids: Experiments, Theories and Simulations

Part of the book series: NATO Science Series ((NAII,volume 133))

Abstract

This chapter deals with the theories of vibrational line profiles and anomalous (negative) frequency non–coincidence effects in condensed media. First, a novel approach to the line profile analysis is described. It is based on a new, flexible time–correlation function (TCF), which has an analytical counterpart in the frequency domain. Using this function one can fit vibrational line profiles obtaining dynamical information at the same time. Numerous applications of this TCF are considered, including analyses of both line profiles and dynamics. Second, direct methods of estimation of repulsion contributions to frrequency shifts and non–coincidence effects are described, and model calculations enabling one to separate the contributions of repulsion and attraction forces resulting in frrequency non–coincidences are presented.

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Authors and Affiliations

  1. Institute for Sorption and Problems of Endoecology, Ukrainian National Academy of Sciences, Gen. Naumov St. 3, 03142, Kyiv - 142, Ukraine

    S. A. Kirillov

  2. Institute for Technological and Information Innovations, P.O. Box 263, 03134, Kyiv - 134, Ukraine

    S. A. Kirillov

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  1. Department of Chemistry, Physical Chemistry, University of Athens, Athens, Greece

    Jannis Samios (Chairman of the NATO-ASI) (Chairman of the NATO-ASI)

  2. Lomonosov Moscow State University, Moscow, Russia

    Vladimir A. Durov (Vice-Chairman of the NATO-ASI) (Vice-Chairman of the NATO-ASI)

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Kirillov, S.A. (2004). Novel Approaches in Spectroscopy of Interparticle Inter-Actions. Vibrational Line Profiles and Anomalous Non-Coincidence Effects. In: Samios, J., Durov, V.A. (eds) Novel Approaches to the Structure and Dynamics of Liquids: Experiments, Theories and Simulations. NATO Science Series, vol 133. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-2384-2_11

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