Magnesium belongs to alkaline earth metals, which occupy the second main group of the periodic table of elements. It was discovered in the eighteenth century and named after the ancient Greek district of Magnesia in Thessaly (Table 1.1). This silvery-white metal is the eighth most abundant element, comprising 2.7% of earth's crust. Due to high reactivity, magnesium is not found in elemental form in nature but only in chemical complexes, widely distributed in rock structures, seawater and lake brines.
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References
Shukun M et al (2005) Uplift China’s Pidgeon magnesium reduction processing level and develop recycling economy – China magnesium report. In: 62nd Annual World Magnesium Conference, Berlin, Germany, IMA, pp 13–25
Watson K et al (2000) The Magnola demonstration plant: A valuable investment in technology development and improvement. In HI Kaplan (ed) Magnesium Technology 2000, TMS, Nashville, TN, 27–30
Schoukens A, Curr T, and Abdellatif M (2007) Thermal production of magnesium. MINTEK, Pyrometallurgy Division, Randburg, South Africa, personal communication
Krishnan A, Lu X, and Pal UB (2005) Solid oxide membrane (SOM) for cost effective and environmentally sound production of magnesium directly from magnesium oxide. In NR Neelaleggham HI Kaplan, and BR Powell (eds) Magnesium Technology 2005, TMS, Warrendale, PA, pp 7–15
Brooks G et al (2006) The carbothermic route to magnesium. Journal of Metals 57(5):51
Kramer DA (1998) Magnesium recycling in the United States in 1998. In Flow studies for recycling metal commodities in the United States, US Geological Survey, Reston, VA, USA
Shang S et al (2001) Innovative vacuum distillation for magnesium recycling. In J Hryn (ed) Magnesium Technology 2001, TMS, Warrendale, PA, USA, pp 55–60
Kimura K, Nishii K, Kawarada M (2003) Recycling magnesium alloy housings for notebook computers. Fujitsu Scientific Technical Journal 38(1): 102–111
Hanko G, Macher G (2003) Technologies for efficient Mg-scrap recycling. In HI Kaplan (ed) Magnesium Technology 2003, TMS, Warrendale, PA, USA, pp 29–32
Busk RS, Phillips CW (1945) Transactions AIME 161:266
Holdeman GE (1942) US Patent 2,304,093,8 Dec 1942
Cao P, Qian M, StJohn DH (2004) Grain coarsening of magnesium alloys by beryllium. Scripta Materialia 51:647–651
Green W et al (1993) Method for producing high purity magnesium alloys. US Patent 5,248,477,28 Sept 28 1993
Dieter GE (1976) Mechanical Metallurgy. McGraw-Hill, New York
Caceres CH et al (2005) Section thickness, macrohardness and yield strength in high pressure die cast magnesium alloy AZ91. Materials Science and Engineering A 402:269–277
Somekawa H, Mukai T (2005) Effect of grain refinement on fracture toughness in extruded pure magnesium. Scripta Materialia 53:1059–1064
Emley EF (1966) Principles of magnesium technology. Pergamon Press, Oxford
Shaw C, Jones H (1997) The contribution of different alloying additions to hardening in rapidly solidified magnesium alloys. Materials Science and Engineering A 226–228:856–860
Blake AH, Caceres CH (2005) Solid solution effects on the tensile behaviour of concentrated Mg-Zn alloys. In NR Neelaleggham (ed) Magnesium Technology 2005, TMS, Warrendale, PA, pp 403–407
Nie JF (2003) Effects of precipitate shape and orientation on dispersion strengthening in magnesium alloys. Scripta Materialia 48:1009–1015
Caceres CH et al (2002) Effects of solidification and aging on the microstructure and mechanical properties of AZ91 alloy. Materials Science and Engineering A 325:344–355
Weiss D, Robison ST (2005) Magnesium driving to permanent mold. Modern Casting 95(9):26–29
Loughanne T et al (2005) The effect of grain refinement on the castability of magnesium permanent mould castings. In NR Neelaleggham (ed) Magnesium Technology 2005, TMS, Warrendale, PA, pp 309–314
Tukeda T et al (2003) Magnesium alloy excellent fluidity and materials thereof. US Patent 6,582,533 B2, 24 June 2003
Nakamura K et al (2004) High strength magnesium based alloy and Mg based casting alloy and article made of the alloy. US Patent 6,755,922 B2, 29 June 2004
Sweder TA et al (2006) AM-lite and AM-HP2 new magnesium alloys offer new opportunities. In SAE 2006 Congress, Detroit, USA, SAE, paper 06M–459
Klement W, Wilens R.H, Duwez P (1960) Nature 187:869
Inoue A (1995) Japan Institute of Materials (JIM) 36 (7):866–875
Kim G, Inoue A, Matsumoto T (1991) Increase of mechanical strength of Mg85Zn12Ce3 amorphous alloy by dispersion of ultrafine hcp particles. Materials Transactions JIM 32:875–878
Amiya K, Inoue A (2000) Materials Transactions JIM 41:1460
Magde SV, Greer AL (2004) Effect of Ag addition on the glass-forming ability and thermal stability of Mg-Cu-Y alloys. Materials Science and Engineering A 375–377:759–762
Perez P et al (2002) Mechanical behaviour of amorphous Mg-23.5Ni ribbons. In VIII Congreso National de Propiedades Mecanicas en Solidos, Gandia
Xu YK et al (2005) Mg-based bulk metallic glass composites with plasticity and gigapaskals strength. Acta Materialia 53:1857–1866
Inoue A et al (1991) Materials Transactions JIM 32:609
Cullity BD (1978) Elements of X-ray Diffraction. Addison-Wesley, New York
Kelly EW, Hosford WF (1968) Trans.AIME 242:5
Staroselsky A, Anand L (2003) A constitutive model for hcp materials deforming by slip and twinning: Application to magnesium alloy AZ31B. International Journal of Plasticity 19(10):1843–1864
Gehrmann R, Frommert MM, Gottstein G (2005) Texture effect on plastic deformation of magnesium. Materials Science and Engineering A 395:338–349
Kaibyshev OA (2005) Superplasticity: Microstructural Refining and Superplastic Roll Forming. In ISTC, Science and Technology Series, vol 3. Futureplast, Arlington, USA
Kaibyshev OA, Salikhov RR (1981) Effect of superplastic deformation on the structure and properties of alloy MA21. Metal Science and Heat Treatment 23(3):188–192
Watanabe H et al (2002) Low temperature superplasticity of a fine-grained ZK60 magnesium alloy processed by equal-channel-angular extrusion. Scripta Materialia 46:851–856
Somekawa H et al (2003) Low temperature diffusion bonding in a superplastic AZ31 magnesium alloy. Scripta Materialia 48:1249–1254
Mabuchi M et al (1997) Low temperature superplasticity in an AZ91 magnesium alloy processed by ECAE. Scripta Materialia 36:681–686
Watanabe H et al (1999) Effect of temperature and grain size on the dominant diffusion process for superplastic flow in AZ61 magnesium alloy. Acta Materialia 47(14):3753–3758
Caceres CH et al (1999) The effect of Cu content on the level of microporosity in Al-Si-Cu-Mg casting alloys. Scripta Materialia 40(5):631–637
Ghosh AK (1977) Tensile instability and necking in materials with strain hardening and strain-rate hardening. Acta Metallurgica 25(12):1413–1424
Lee SG et al (2005) Variability in the tensile ductility of high pressure die cast AM50 Mg alloy. Scripta Materialia 53:851–856
Weiler JP et al (2005) Relationship between internal porosity and fracture strength of die cast magnesum alloy AM60B. Materials Science and Engineering A 395:315–322
Ericksen SC (1988) Magnesium’s high damping capacity for automotive noise and vibration attenuation. In 45 World Magnesium Congress, Tokyo, 1998, IMA, pp 54–58
Jensen JW (1964) Magnesium damping capacity—causes and effects. In Magnesium Association Convention, 1964, pp 1–11
EMI shielding, Hydro Magnesium Brochure, 2005
Rudajevova A, Stanek M, Lukac P (2003) Determination of thermal diffusivity and thermal conductivity of Mg-Al alloys. Materials Science and Engineering A 341:152–157
Doehler HH (1951) Die castings. McGraw Hill, New York
Sin LS, Dube D (2004) Influence of process parameters on fluidity of investment cast AZ91D magnesium alloy. Materials Science and Engineering A 386:34–42
Moore S (2002) Magnesium Molding—technique expands options. Modern Plastics, July 2002:33
Kono K (1999) Method and apparatus for manufacturing metallic parts by fine die casting. US Patent 5,983,976, 16 Nov 1999
Moore S (2002) Thixotropic molding broadens processor capabilities. Modern Plastics March 2002:24–30
Tausing G, Ricketts NJ, Peck SR (2001) Forging of magnesium using squeeze cast preform. In J Hryn (ed) Magnesium Technology 2001, TMS, Warrendale, PA, pp 235–242
Couling SL, Pashak JF, Sturkey L (1959) Transactions ASM 51:94–107
Barnett MR, Bave MD, Bettles CJ (2004) Deformation microstructures and textures of some cold rolled Mg alloys. Materials Science and Engineering A 386:205–211
Lochte L, Westengen H, Rodseth J (2005) An efficient route to magnesium alloy sheet: Twin roll casting and rolling. In NR Neelaleggham (ed) Magnesium Technology 2005, TMS, Warrendale, PA, pp 247–252
Bohlen J et al (2005) Microstructure and texture development during hydrostatic extrusion of magnesium alloy AZ31. Scripta Materialia 53:259–264
Celotto S (2000) TEM study of continuous precipitation in Mg-9Al-1Zn alloy. Acta Materialia 48(8):1775–1787
Zhang MX, Kelly PM (2002) Crystallography of Mg17Al12 precipitates in AZ91D alloy. Scripta Materialia 48:647–652
Ghali E, Kainer KU (2004) General and localized corrosion of magnesium alloys: A critical review. Journal of Materials Engineering and Performance 13:7–23
Lunder O et al (1989) Corrosion Science 45:741
Juzeliunas E et al (2005) Structure and initial corrosion resistance of sputter deposited nanocrystalline Mg-Al-Zr alloys. Materials Science and Engineering A 395:411–416
Song G, StJohn D (2002) The effect of zirconium grain refinement on the corrosion behaviour of magnesium-rare earth alloy MEZ. Journal of Light Metals 2:1–16
Dube D et al (2001) Characterization and performance of laser melted AZ91D and AM60B. Material Science and Engineering A 299:38–45
Song G, Atrens A, Dargusch M (1999) Influence of microstructure on the corrosion of die cast AZ91D. Corrosion Science 41:249–273
Mathieu S et al (2002) Corrosion behaviour of high pressure die cast and semisolid cast AZ91D alloys. Corrosion Science 44:2737–2756
Wang F, Li Y, Huo H 2004) Corrosion of AZ91D magnesium alloy with a chemical conversion coating and electroless nickel layer. Corrosion Science 46:1467–1477
Yang K, Xu L, Zhang E (2005) Formation by ion plating of Ti-coating on pure Mg for biomedical applications. Scripta Materialia 53:523–527
Timoshenko AV, Magurova YV (1995) The effect of a cathodic component on AC microplasma oxidation of aluminum alloys. Protection of Metals 31(4):377–380
Stevens KT, John CG, Walsh FC (2003) Surface finishing of aluminum and magnesium alloys using plasma electrolytic oxidation. In HI Kaplan (ed) Magnesium Technology 2003, TMS, Warrendale, PA, p 89
Timoshenko AV et al (1994) The effect of silicates in sodium hydroxide solution on the structure of oxide coatings deposited on a D16T alloy by microarc oxidation. Protection of Metals 30(2):149–153
Shrestha S et al (2002) Improved corrosion performance of AZ91D magnesium alloy coated with the Keronite process. In HI Kaplan (ed) Magnesium Technology 2002, TMS, Warrendale, PA
MEL (2005) Surface treatments for magnesium alloys in aerospace and defence. Magnesium Elektron, Swinton, England
Brown RE (2002) Developments in magnesium wrought products rolling, forging and sheet casting. In 59th Annual World Magnesium Conference, Montreal, 2002, pp 25–32
Nakatsugawa I, Tsukeda T, Kitamura K (2002) Latest developments in magnesium use for thixomolding in Asia. In 59th Annual World Magnesium Conference, Montreal, 2002, 11–14
Shukun M et al (2006) China magnesium industry development report for 2005. In 63rd World Magnesium Conference, Beijing, IMA, pp 3–23
Metals Handbook (1973) 8th ed. vol. 8. American Society for Metals, Metals Park, Ohio
Westengen H, Bakke P, Albright, D (2005) Advances in Magnesium Alloy Development. Die Casting Engineer 49(6):26–32
Nayeb-Hashemi AA, Clark JB (1988) Phase diagrams of binary magnesium alloys. ASM International, Metals Park, Ohio
Brooks CR (1982) Heat treatment, structure and properties of non-ferrous alloys. ASM International, Metals Park, Ohio
Mathis K, Trojanova Z, Lukac P (2002) Hardening and softening in deformed magnesium alloys. Materials Science and Engineering A 324:141–144
Pourbaix M (1974) Atlas of Electrochemical Equilibria. In Aqueous Solutions, National Association of Corrosion Engineers
Kato A et al (1994) Consolidation and mechanical properties of atomized Mg-based amorphous powder. Materials Science and Engineering A 179–180:112–117
Kato A et al (1994) Microstructure and mechanical properties of bulk Mg70Ca10Al20 alloys produced by extrusion of atomized amorphous powders. Materials Science and Engineering A 179–180:707–711
Friedrich H, Schumann S (2002) Strategies for overcoming technological barriers to the increased use of magnesium in cars. In Transactions of Institute of Mining and Metallurgy (section c: mineral processing and extractive metallurgy), The Institute of Materials, Minerals and Mining, pp. C65–C71
CRC Handbook of Chemistry and Physics (1996) New York
Smithels Metals Reference Book, 8-th edition (2004) Elsevier
Shewmon P, Diffusion in Solids (1989) TMS Warrendale
Horst HJ and Asby MF (1982) Deformation Mechanism Map, Pergamon Press
Cannon JF (1974) J. Phys. Chem. Ref. Data Vol. 3, pp 781–824
Magnesium and Magnesium Alloys (1999) edited by M. Avedesian and H. Baker, ASM International, Materials Park, OH
Metals Handbook (1990) Vol 2. ASM International, Materials Park, OH
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Czerwinski, F. (2008). Magnesium and Its Alloys. In: Magnesium Injection Molding. Springer, Boston, MA. https://doi.org/10.1007/978-0-387-72528-4_1
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