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Catalytic Addition of C – H Bonds to C – C Multiple Bonds

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Directed Metallation

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 24))

Abstract

During the last decade, catalytic functionalization of C–H bonds has become one of the most attractive research areas in modern organic synthesis. To date, many efficient catalytic reactions have been reported. In almost all of these reactions, heteroatom-directed C–H bond cleavage and/or C–C bond formation are quite important for attaining high regioselectivity and efficiency. In this chapter, several representative results concerning transition metal-catalyzed alkylation of C–H bonds with olefins, alkenylation with acetylenes, and carbonylation with olefins and carbon monoxides will be briefly reviewed.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama, 223-8522, Kanagawa, Japan

    Fumitoshi Kakiuchi

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  1. Fumitoshi Kakiuchi
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Naoto Chatani

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Kakiuchi, F. (2007). Catalytic Addition of C – H Bonds to C – C Multiple Bonds. In: Chatani, N. (eds) Directed Metallation. Topics in Organometallic Chemistry, vol 24. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3418_2007_064

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