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Formation processes and properties of conducting polymer composites

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Filled Polymers I Science and Technology

Part of the book series: Advances in Polymer Science ((POLYMER,volume 96))

Abstract

Conducting polymer composites (CPCM) have usually been considered from the point of view of their constituents and properties. However, processing conditions may influence the properties even more strongly. The present article is meant to redress the situation, relating processing conditions and the final properties of these materials. First, components, structure, and conductivity of CPCM are shortly reviewed, with the newly developed types of conducting fillers included. Then, redistribution of disperse filler particles during injection molding and resulting conductivity profiles are considered. The use of polymer blends may lead to the segregation of the filler, resulting in higher conductivity at lower concentrations. These phenomena are also considered. The next chapter deals with the influence of processing on conducting fibers, which are the most promising fillers but which easily break under extreme processing conditions. A novel technique for manufacturing CPCM — polymerization filling — and the properties of resulting composites are reviewed. Finally, existing and future applications of conducting polymer composites are considered.

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7 References

  1. Norman RH (1970) Conductive rubbers and plastics, Appl. Sci. Pub., Essex, England

    Google Scholar 

  2. Sichel EK (1982) Carbon black — Polymer composites, Marcel Dekker, New York

    Google Scholar 

  3. Gul' VE, Shenfil LZ (1984) Conducting polymer composites, Moscow, Chemistry (in Russian)

    Google Scholar 

  4. Vasilenok YN (1981) Prevention of statistical charging of polymers, Leningrad, Chemistry (in Russian)

    Google Scholar 

  5. Gurland JC, Tanner DB (eds) (1978) Electrical Transport and Optical Properties of Inhomogeneous Media AIP, New York

    Google Scholar 

  6. Seymour RB (1984) Conductive polymers, Plenum, New York

    Google Scholar 

  7. Conducting Polymer Symp., Las Vegas, NV, Aug. 26–27, 1980, Plenum New York, 1981

    Google Scholar 

  8. Crossman RA (1985) Polym. Eng. Sci. 25: 507

    Google Scholar 

  9. Mair HJ, Roth S (eds) (1986) Elektrisch leitende Kunststoffe, Carl Hanser, Munchen

    Google Scholar 

  10. Shevchenko VG, Ponomarenko AT (1983) Advances in Chemistry, USSR, 52: 1336

    Google Scholar 

  11. Shevchenko VG, Ponomarenko AT, Enikolopyan NS (1985) Plaste und Kautschuk 32: 401

    Google Scholar 

  12. Ponomarenko AT, Shevchenko VG, Tchmutin IA, Ovchinnikov AA, Enikolopyan NS (1986) Conducting polymer composites, In: Sedlacek B (ed) Polymer composites, Walter de Gruyter, B., N.Y., 1986, p. 67.

    Google Scholar 

  13. Katz HS, Milewski JV (eds) (1978) Handbook of fillers and reinforcements for plastics, Van Nostrand Reinh., New York

    Google Scholar 

  14. Kiesche E: Plast. Techn., Nov 1985, p 77

    Google Scholar 

  15. Bigg DM, Stutz DE (1983) Polymer Comp. 4: 40

    Google Scholar 

  16. Tolokan RP, Nablo JC: Plast. Eng., Aug 1985, p 31

    Google Scholar 

  17. Levit RM (1986) Conducting Chemical Fibers, Moscow, Chemistry (in Russian)

    Google Scholar 

  18. Sheng P (1980) Phys. Rev. 21B: 2180

    Google Scholar 

  19. Malliaris A, Turner DT (1971) Journ. Appl. Phys. 42: 614

    Google Scholar 

  20. Broadbent SR, Hammersley JM (1957) Proc. Cambr. Soc. (1957) 53: 629

    Google Scholar 

  21. Shante VKS, Kirkpatrick S (1971) Adv. Phys. 20: 325

    Google Scholar 

  22. Kirkpatrick S (1973) Rev. Mod. Phys. 45: 574

    Google Scholar 

  23. Shklovsky BI, Efros AL (1975) Advances in Physical Sciences, USSR, 117: 401

    Google Scholar 

  24. Galashina NM, Shevchenko VG, Ponomarenko AT, Grigorov LN, Shklyarova EI, Djachkovsky FS, Enikolopyan NS (1985) In: Ovchinnikov AA (ed) Electronics of organic materials Moscow Science, p 43 (in Russian)

    Google Scholar 

  25. Sazhin BI (ed) (1970) Electrical properties of polymers, Leningrad Chemistry (in Russian)

    Google Scholar 

  26. Sheer GE, Turner DT (1971) In: Gould RF (ed) Multicomponent polymer systems, ACS, Wash.

    Google Scholar 

  27. Yun-ichi Y, Osamu M, Yuzo K (1978) Rev Elec. Commun Lab. 26: 616

    Google Scholar 

  28. USA patent No. 382942 (1983)

    Google Scholar 

  29. Tikhomirov AF, Pugachev AK, Olshevsky OI, Sazhin BI (1988) Plastic Materials, USSR No. 5, p 13

    Google Scholar 

  30. Bhattacharya R (1982) Polym.-Plast. Technol. Eng. 19: 21

    Google Scholar 

  31. Davenport DE (1981) In: Conduct. Polym. Proc. Symp., Las Vegas, 1980, Plenum, New York, p 39

    Google Scholar 

  32. Bazarova FF, Kolosova NS (1975) Cements in production of radioelectronic equipment, Moscow, Energy (in Russian)

    Google Scholar 

  33. Klason C, Kubat J (1975) Journ. Appl. Polym Sci. 24: 831

    Google Scholar 

  34. Fox L (1978) RCA Review 39: 119

    Google Scholar 

  35. Skutnik Bolesh J (1984) Rubber Chem. Technol. 57: 403

    Google Scholar 

  36. Torner RV (1972) Basic processes of polymer processing (Theory and calculations methods), M., Chemistry (in Russian)

    Google Scholar 

  37. Gauthier F, Goldsmith HL, Mason SG (1971) Rheol. Acta 10: 344

    Google Scholar 

  38. Gauthier F, Goldsmith HL, Mason SG (1971) Trans. Soc. Rheol., 15: 297

    Google Scholar 

  39. Brunn P (1980) Journ. Non-Newt. Fluid Mech. 7: 271

    Google Scholar 

  40. Emerman SH (1987) Polym. Eng. Sci. 27: 1105

    Google Scholar 

  41. Kubat J, Szalanczi A (1974) Polym. Eng. Sci. 14: 873

    Google Scholar 

  42. Hegler RP, Mennig G (1985) Polym. Eng. Sci. 25: 395

    Google Scholar 

  43. Bayer RK et al. (1988) Journ. Mater. Sci. 23: 475

    Google Scholar 

  44. Bayer RK, Eliah AE, Seferis JC (1984) Polym. Eng. Rev. 4: 201

    Google Scholar 

  45. Pavlii VG, Zaikin AE, Kuznetsov EV (1984) Proceedings of XII All-Union Conference on Organic Semiconductors, Moscow, Patent publishers, pp 117–118 (in Russian)

    Google Scholar 

  46. Pavlii VG, Zaikin AE, Kuznetsov EV (1986) Higher School Bulletin, USSR, Chemistry and Chemical Technology, 29: 84

    Google Scholar 

  47. Kim VS, Skachkov VV (1980) Dispersion and mixing in the processes of manufacture and processing of plastic materials, Moscow, Chemistry, p 240 (in Russian)

    Google Scholar 

  48. Bachellor GK (1969) Introduction to fluid dynamics, Wiley N.Y.

    Google Scholar 

  49. Enikolopov NS (1980) Nature, USSR 8: 62

    Google Scholar 

  50. Dyachkovsky FS, Novokshonova LA (1984) Advances in Chemistry, USSR, 53: 200

    Google Scholar 

  51. Baulin AA, Krasnoshchekov AM, Deyanova AS, Vasilenok YI (1982) Applied Chemistry Journal, USSR 55: 2534

    Google Scholar 

  52. Aivazyan FN, Matkovsky PE, Ponomarenko AT, Pavlii VG, Shamsullin IF, Kolesnikov YN, Enikolopyan NS (1983) In: Complex metalloorganic catalysts of elefin polymerization, Chernogolovka, p 73 (in Russian)

    Google Scholar 

  53. Enikolopyan NS, Galashina NM, Shevchenko VG, Ponomarenko AT et al. (1984) USSR Certificate of Authorship No. 1240761

    Google Scholar 

  54. Nedorezova PM, Shevchenko VG, Grinev VG, Galashina NM, Tsvetkova VN, Ponomarenko AT, Dyachkovsky FS, Levintovich PY, Katasonov AS, Enikolopyan NS (1985) Collection of Reports at II All-Union Conference “Highly Filled Complex Polymer Materials in the Economy”, I., vol 1, pp 20–25 (in Russian)

    Google Scholar 

  55. Levintovich PY, Shevchenko VG, Kotosonov AS, Nedorezova PM, Ponomarenko AT (1984) Proceedings of XIII All-Union Conference on Organic Semiconductors, Moscow, Patent, p 96 (in Russian)

    Google Scholar 

  56. Galashina NM, Shevchenko VG, Ponomarenko AT, Nedorezova PM, Filippov PG, Grigorov LN, Dyachkovsky FS, Tsvetkova VN, Enikolopyan NS: Abstracts of IUPAC Macro-83, Bucharest, Romania, Spt. 5–9, 1983, Sect. 6–7, p 121

    Google Scholar 

  57. Chirkov IM, Matkovsky PE, Dyachkovsky FS (1976) Polymerization with Complex Metallorganic Catalysts, M., Chemistry, p 414 (in Russian)

    Google Scholar 

  58. Galashina NM, Nedorezova PM, Tsvetkova VN, Dyachkovsky FS, Enikolopyan NS (1984) USSR Academy of Sciences Proceedings, 278: 620

    Google Scholar 

  59. Sazhin BI (ed) (1977) Electrical properties of polymers, Moscow, Chemistry (in Russian)

    Google Scholar 

  60. Ubbelode AR, Lewis FA (1960) Graphite and its crystal compounds, Oxford Univ. Press

    Google Scholar 

  61. Nedorezova PM, Galashina NM, Tsvetkova VN, Grinev VG, Shevchenko VG, Ponomarenko AT, Tovmasyan YM, Kolbanov IV, Dyachkovsky FS, Enikolopyan NS: Abstracts of IUPAC Macro-87, Merseburg, June 30-July 4, 1987, p 102

    Google Scholar 

  62. Grigorov LN, Shklyarova, Dorofeeva TV, Galashina NM, Enikolopyan NS (1984) USSR Academy of Sciences Proceedings 278: 911

    Google Scholar 

  63. Grigorov LN, Galashina NM, Enikolopyan NS (1984) USSR Academy of Sciencies Proceedings, 274: 840

    Google Scholar 

  64. Moshkin AA, Losoto AP, Berezhnoy AI, Krasninov AS (1979) Nonferrous Metallurgy, USSR, 21: 34

    Google Scholar 

  65. Losoto AP, Moshkin AA, Akutin MS, Berezhnoy AI, Udalova VI, Petrova VF (1981) Plastic Materials, USSR, 3: 29

    Google Scholar 

  66. Losoto AP, Akutin MS, Petrova VF, Moshkin AA, Udalova VI, Pegasov VV, Konysheva AV (1978) Nonferrous Metallurgy, USSR, 17: 52

    Google Scholar 

  67. Bledzki A, Stankowska D (1984) Kunststoffe 74: 89

    Google Scholar 

  68. Mobius KH (1988) Kunststoffe 78: 345

    Google Scholar 

  69. Regan J (1982) Polym.-Plast. Techn. Eng. 18: 47

    Google Scholar 

  70. Vance EF (1980) IEEE Trans. on Electromagn. Comp. EMC-22, 4: 319

    Google Scholar 

  71. Toensmeier PA (1987) Modern Plast. Int. 2: 47

    Google Scholar 

  72. Stephens KA (1987) Plast. Eng. 2: 33

    Google Scholar 

  73. Carpenter R (1986) Appliance Manufact. 8: 20

    Google Scholar 

  74. Yoshitake M (1985) Japan Plast. Age 23: 21

    Google Scholar 

  75. Inkpen SL, Melcher JR (1985) Polym. Eng. Sci. 25: 289

    Google Scholar 

  76. Bekishev RF, Daneker VA (1979) Electrotechnical Industry, USSR, Electrotechnical Materials series 5: 8

    Google Scholar 

  77. USSR Certificate of Autorship No. 997153, Inventions Bulletin, 1983, No. 6

    Google Scholar 

  78. Pristupa AI, Shevchenko VG, Ponomarenko AT, Chmutin IA, Ovchinnikov AA, Enikolopyan NS (1986) Proceedings of 8th Conf. Polymerphysik-86, Leipzig, Kurzfassung Vorträge und Poster, p 98

    Google Scholar 

  79. Pristupa AI, Petrov NK, Shevchenko VG, Ponomarenko AT, Enikolopyan NS (1986) Proceedings of 8th Conf. — Polymerphysik — 86, Leipzig, Kurzfassung Vorträge und Poster, pp 199–200

    Google Scholar 

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© 1990 Springer-Verlag

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Ponomarenko, A.T., Shevchenko, V.G., Enikolopyan, N.S. (1990). Formation processes and properties of conducting polymer composites. In: Enikolopyan, N.S. (eds) Filled Polymers I Science and Technology. Advances in Polymer Science, vol 96. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-52791-5_4

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  • DOI: https://doi.org/10.1007/3-540-52791-5_4

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