Abstract
Crystallization in block copolymers has a profound effect on their structure. This review article focusses on the morphology of semicrystalline block copolymers, and those containing two crystallizable blocks. The effect of crystallization on mechanical properties is briefly considered. The extent of chain folding upon crystallization is discussed, as is the orientation of crystal stems with respect to the microstructure. The effect of selective solvent on solution crystallization is also highlighted. Recent work on crystallization kinetics is summarized and finally the theories for crystallization in block copolymers are outlined.
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References
Hamley IW (1998) The physics of block copolymers. Oxford University Press, Oxford
Mohajer Y, Wilkes GL, Wang IC, McGrath JE (1982) Polymer 23:1523
Hirata E, Ijitsu T, Soen T, Hashimoto T, Kawai H (1975) Polymer 16:249
Séguéla R, Prud’homme J (1989) Polymer 30:1446
Cohen RE, Cheng P-L, Douzinas K, Kofinas P, Berney CV (1990) Macromolecules 23:324
Veith CA, Cohen RE, Argon AS (1991) Polymer 32:1545
Khandpur AK, Macosko CW, Bates FS (1995) J Polym Sci Polym Phys Ed 33:247
Vonk CG (1973) J Appl Cryst 6:81
Hamley IW, Fairclough JPA, Bates FS, Ryan AJ (1998) Polymer 39:1429
Balta-Calleja FJ, Vonk CG (1989) X-ray scattering of synthetic polymers. Elsevier, London
Ryan AJ, Hamley IW, Bras W, Bates FS (1995) Macromolecules 28:3860
Nojima S, Kato K, Yamamoto S, Ashida T (1992) Macromolecules 25:2237
Nojima S, Nakano H, Takahashi Y, Ashida T (1994) Polymer 35:3479
Quiram DJ, Register RA, Marchand GR (1997) Macromolecules 30:4551
Quiram DJ, Register RA, Marchand GR, Ryan AJ (1997) Macromolecules 30:8338
Quiram DJ, Register RA, Marchand GR, Adamson DH (1998) Macromolecules 31:4891
Hamley IW, Fairclough JPA, Terrill NJ, Ryan AJ, Lipic PM, Bates FS, Towns-Andrews E (1996) Macromolecules 29:8835
Hamley IW, Fairclough JPA, Ryan AJ, Bates FS, Towns-Andrews E (1996) Polymer 37:4425
Ryan AJ, Fairclough JPA, Hamley IW, Mai S-M, Booth C (1997) Macromolecules 30:1723
Whitmore MD, Noolandi J (1988) Macromolecules 21:1482
Douzinas KC, Cohen RE, Halasa AF (1991) Macromolecules 24:4457
Rangarajan P, Register RA, Fetters LJ (1993) Macromolecules 26:4640
Unger R, Beyer D, Donth E (1991) Polymer 32:3305
DiMarzio EA, Guttman CM, Hoffman JD (1980) Macromolecules 13:1194
Nojima S, Yamamoto S, Ashida T (1995) Polym J 27:673
Ashman PC, Booth C (1975) Polymer 16:889
Ashman PC, Booth C, Cooper DR, Price C (1975) Polymer 16:897
Booth C, Pickles CJ (1973) J Polym Sci Polym Phys Ed 11:259
Flory PJ (1949) J Chem Phys 17:223
Flory PJ, Vrij S (1963) J Am Chem Soc 85:3548
Viras F, Luo Y-Z, Viras K, Mobbs RH, King TA, Booth C (1988) Makromol Chem 189:459
Al Kafaji JKH, Booth C (1981) Makromol Chem 182:3671
Booth C, Domszy RC, Leung Y-K (1979) Makromol Chem 180:2765
Cooper DR, Leung Y-K, Heatley F, Booth C (1978) Polymer 19:309
Domszy RC, Mobbs RH, Leung Y-K, Heatley F, Booth C (1979) Polymer 20:1204
Domszy RC, Mobbs RH, Leung Y-K, Heatley F, Booth C (1979) Polymer 21:588
Yang Y-W, Tanodekaew S, Mai S-M, Booth C, Ryan AJ, Bras W, Viras K (1995) Macromolecules 28:6029
Mai S-M, Fairclough JPA, Viras K, Gorry PA, Hamley IW, Ryan AJ, Booth C (1997) Macromolecules 30:8392
Honeker CC, Thomas EL (1996) Chem Mater 8:1702
Douzinas KC, Cohen RE (1992) Macromolecules 25:5030
Cohen RE, Bellare A, Drzewinski MA (1994) Macromolecules 27:2321
Kofinas P, Cohen RE (1994) Macromolecules 27:3002
Nojima S, Ono M, Ashida T (1992) Polym J 24:1271
Skoulios AE, Tsouladze G, Franta E (1963) J Polym Sci C 4:507
Gervais M, Gallot B (1973) Makromol Chem 171:157
Gervais M, Gallot B (1973) Makromol Chem 174:193
Lotz B, Kovacs B (1966) Koll-Z u Z Polym 209:97
Lotz B, Kovacs AJ, Bassett GA, Keller A (1966) Koll-Z u Z Polym 209:115
Gervais M, Gallot B (1977) Makromol Chem 178:1577
Lin EK, Gast AP (1996) Macromolecules 29:4432
Richter D, Schneiders D, Monkenbusch M, Willner L, Fetters LJ, Huang JS, Lin M, Mortensen K, Farago B (1997) Macromolecules 30:1053
Ramzi A, Prager M, Richter D, Efstratiadis V, Hadjichristidis N, Young RN, Allgaier JB (1997) Macromolecules 30:7171
Avrami M (1939) J Chem Phys 7:1103
Gedde UW (1995) Polymer physics. Chapman and Hall, London
Rangarajan P, Register RA, Adamson DH, Fetters LJ, Bras W, Naylor S, Ryan AJ (1995) Macromolecules 28:1422
Rangarajan P, Register RA, Fetters LJ, Bras W, Naylor S, Ryan AJ (1995) Macromolecules 28:4932
Nojima S, Nakano H, Ashida T (1993) Polymer 34:4168
Hamley IW, Pople JA, Ameri M, Attwood D, Booth C, Ryan AJ (1998) Macromol Chem Phys 199:1753
Hamley IW, Pople JA, Ameri M, Attwood D, Booth C (1998) Coll Surf A 145:185
Lovinger AJ, Han BJ, Padden FJ, Mirau PA (1993) J Polym Sci Polym Phys Ed 31:115
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Hamley, I.W. (1999). Crystallization in Block Copolymers. In: Interfaces Crystallization Viscoelasticity. Advances in Polymer Science, vol 148. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-48836-7_2
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DOI: https://doi.org/10.1007/3-540-48836-7_2
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