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The application of differential scanning calorimetry (DSC) to the study of epoxy resin curing reactions

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Epoxy Resins and Composites I

Part of the book series: Advances in Polymer Science ((POLYMER,volume 72))

Abstract

This review is on the use of differential scanning calorimetry as a method of monitoring and investigating the kinetics of epoxy resin curing reactions. Some instrumental and experimental aspects are discussed, including methods of analysing the kinetic data. A brief survey is made of epoxy resin curing reactions and results of DSC studies are reviewed. These results are concerned with the use of carboxylic acid anhydrides, primary and secondary amines, dicyanodiamide, and imidazoles as curing agents.

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6 References

  1. Mackenzie, R. C.: Thermochim. Acta 28, 1 (1979)

    Google Scholar 

  2. Mackenzie, R. C.: Anal. Proc. 217 (1980)

    Google Scholar 

  3. Watson, E. S. O'Neill, M. J. Justin, J., Brenner, N.: Anal. Chem. 36, 1233 (1964)

    CAS  Google Scholar 

  4. O'Neill, M. J.: Anal. Chem. 36, 1238 (1964)

    Google Scholar 

  5. Boersma, S. L.: J. Amer. Ceramic Soc. 38, 281 (1955)

    CAS  Google Scholar 

  6. Lee, J. D., Levy, P. F.: North American Thermal Anal. Soc., Proc., 11th Conf. (1981)

    Google Scholar 

  7. Wendlandt, W. W., Gallagher, P. K.: Thermal Characterisation of Polymeric Materials (ed.) Turi, E. A., Chapter 1, New York N.Y., Academic Press (1981)

    Google Scholar 

  8. Mraw, S. C.: Rev. Sci. Instr. 53, 228 (1982)

    CAS  Google Scholar 

  9. Dallek, S., Kabacoff, L.: Thermochim. Acta 57, 99 (1982)

    CAS  Google Scholar 

  10. Hohne, G. W. H., Breuer, K. H., Eysel, W.: Thermochim. Acta 69, 145 (1983)

    Google Scholar 

  11. Richardson, M. J., Savill, N. G.: Polymer 16, 753 (1975)

    CAS  Google Scholar 

  12. Flynn, J. H.: Thermochim. Acta 8, 69 (1974)

    CAS  Google Scholar 

  13. Nielsen, L. E.: J. Macromol. Sci., Revs. Macromol. Chem. C3, 69 (1969)

    Google Scholar 

  14. Nielsen, L. E.: Mechanical Properties of Polymers and Composites, Vol. 1, New York, N.Y., Marcel Dekker (1974)

    Google Scholar 

  15. Chompff, A. J.: Polymer Networks (ed.) Chompff, A. J., Newman, S., p. 145, New York, N.Y., Plenum Press (1971)

    Google Scholar 

  16. Widmann, G.: Proc. 4th International Conference on Thermal Analysis (ed.) Buzas, I., Vol. 3, p. 359, Budapest, Akademiai Kiado (1975)

    Google Scholar 

  17. Barton, J. M.: Thermochim. Acta 71, 337 (1983)

    CAS  Google Scholar 

  18. Barrett, K. E. J.: J. Appl. Polym. Sci. 11, 1617 (1967)

    CAS  Google Scholar 

  19. Freeman, E. S., Carroll, B.: J. Phys. Chem. 62, 394 (1958)

    CAS  Google Scholar 

  20. Ellerstein, S. M.: Analytical Calorimetry (eds.) Porter, R. S., Johnson, J. O., p. 279, New York, N.Y., Plenum Press (1968)

    Google Scholar 

  21. Crane, L. W., Dynes, P. J., Kaelble, D. H.: J. Polym. Sci., Polym. Letters 11, 533 (1973)

    CAS  Google Scholar 

  22. Rogers, R. N., Smith, L. C.: Thermochim. Acta 1, 1 (1970)

    CAS  Google Scholar 

  23. Kissinger, H.: Anal. Chem. 21, 1702 (1957)

    Google Scholar 

  24. Doyle, C. D.: J. Appl. Polym. Sci. 6, 639 (1962)

    CAS  Google Scholar 

  25. Doyle, C. D.: Techniques and Methods of Polymer Evaluation (ed.) Slade, P. E., Jenkins, L. T., Vol. 1, Thermal Analysis Chapter 4, p. 173, New York, N.Y., Marcel Dekker (1966)

    Google Scholar 

  26. Horowitz, H. H., Metzger, G.: Anal. Chem. 35, 1464 (1963)

    CAS  Google Scholar 

  27. Coates, A. W., Redfern, J. P.: Nature 201, 68 (1964)

    Google Scholar 

  28. Ozawa, T.: Bull. Chem. Soc. Japan 38, 1881 (1965)

    CAS  Google Scholar 

  29. Ozawa, T.: J. Thermal Anal. 2, 301 (1970)

    CAS  Google Scholar 

  30. Ozawa, T.: J. Thermal. Anal. 7, 601 (1975)

    CAS  Google Scholar 

  31. Swarin, S. J., Wims, A. M.: Anal. Calorimetry 4, 155 (1976)

    Google Scholar 

  32. Draper, A. L.: Third Toronto Symposium on Thermal Analysis, Proceedings p. 63 (1970)

    Google Scholar 

  33. MacCallum, J. R., Tanner, J.: Nature 225, 1127 (1970)

    CAS  Google Scholar 

  34. Fevre, A. Murat, M., Comel, C.: J. Thermal Anal. 12, 193 (1977)

    Google Scholar 

  35. Prime, R. B.: Analytical Calorimetry 2, 201 (1970)

    Google Scholar 

  36. Prime, R. B.: Polym. Eng. Sci. 13, 365 (1973)

    CAS  Google Scholar 

  37. Barton, J. M., Shepherd, P. M.: Makromol. Chem. 176, 919 (1975)

    CAS  Google Scholar 

  38. Hill, R. A.: Nature 227, 703 (1970)

    CAS  Google Scholar 

  39. Simmons, E. L., Wendlandt, W. W.: Thermochim. Acta 3, 498 (1972)

    CAS  Google Scholar 

  40. Gyulai, G., Greenhow, E. J.: Thermochim. Acta: 5, 481 (1973)

    CAS  Google Scholar 

  41. Sestak, J., Kratochvil, J.: J. Thermal Anal. 5, 429 (1973)

    Google Scholar 

  42. Tanaka, Y., Mika, T. F.: Epoxide curing reactions, in: Epoxy Resins (ed.) May, C. A., Tanaka, Y., Chapter 3, New York, N.Y., Marcel Dekker 1973

    Google Scholar 

  43. Mika, T. F.: Curing agents and modifiers, in: Epoxy Resins, (

    Google Scholar 

  44. Fisch, W., Hofmann, W.: J. Polym. Sci. 12, 497 (1954)

    CAS  Google Scholar 

  45. Fisch, W., Hofmann, W.: Makromol. Chem. 44–46, 8 (1961)

    Google Scholar 

  46. Tanaka, Y., Kakiuchi, H.: J. Appl. Polym. Sci. 7, 1063 (1963)

    CAS  Google Scholar 

  47. Tanaka, Y., Kakiuchi, H.: J. Polym. Sci., Part A, 2, 3405 (1964)

    CAS  Google Scholar 

  48. Tanaka, Y., Kakiuchi, H.: J. Macromol. Chem. 1, 307 (1966)

    CAS  Google Scholar 

  49. Luston, J., Manasek, Z.: J. Macromol. Sci., Chem. A, 12, 983 (1978)

    Google Scholar 

  50. Luston, J., Manasek, Z., Kulichova, M.: J. Macromol. Sci., Chem. A, 12, 995 (1978)

    Google Scholar 

  51. Matejka, L., Lovy, J., Pokorny, S., Bouchal, K., Dusek, K.: J. Polym. Sci., Polym. Chem. Ed. 21, 2873 (1983)

    CAS  Google Scholar 

  52. Stevens, G. C.: J. Appl. Polym. Sci. 26, 4259 (1981)

    CAS  Google Scholar 

  53. Stevens, G. C.: J. Appl. Polym. Sci. 26, 4279 (1981)

    CAS  Google Scholar 

  54. Antoon, M. K., Koenig, J. L.: J. Polym. Sci., Polym. Chem. Ed. 19, 549, (1981)

    CAS  Google Scholar 

  55. Schechter, L., Wynstra, J., Kurkjy, R. P.: Ind. Eng. Chem. 48, 94 (1956)

    Google Scholar 

  56. Enikolopiyan, N. S.: Pure and Appl. Chem. 48, 317 (1976)

    CAS  Google Scholar 

  57. Smith, I. T.: Polymer 2, 95 (1961)

    CAS  Google Scholar 

  58. King, J. J., Bell, J. P.: in: Epoxy Resin Chemistry (ed.) Bauer R. S., ACS Symposium Series, No. 114, Chapter 16, Amer. Chem. Soc. (1979)

    Google Scholar 

  59. Saunders, T. F., Levy, M. F., Serefino, J. F.: J. Polym. Sci. A-1, 5, 1609 (1967)

    CAS  Google Scholar 

  60. Sacher, E.: Polymer 14, 91 (1973)

    CAS  Google Scholar 

  61. Schneider, N. S., Sprouse, J. F., Hagnauer, G. L., Gillham, J. K.: Polym. Eng. Sci. 19, 304 (1979)

    CAS  Google Scholar 

  62. Son, P., Weber, C. D.: J. Appl. Polym. Sci. 17, 1305 (1973)

    CAS  Google Scholar 

  63. LaLiberte, B. R., Bornstein, J., Sacher, R. E.: Ind. Eng. Chem. Prod. Res. Dev. 22, 261 (1983)

    CAS  Google Scholar 

  64. Farkas, A., Strohm, P. F.: J. Appl. Polym. Sci. 12, 159 (1968)

    CAS  Google Scholar 

  65. Fava, R. A.: Polymer 9, 137 (1968)

    CAS  Google Scholar 

  66. Peyser, P., Bascom, W. D.: Analytical Calorimetry 3, 537 (1974)

    CAS  Google Scholar 

  67. Peyser, P., Bascom, W. D.: J. Appl. Polym. Sci. 21, 2359 (1977)

    CAS  Google Scholar 

  68. Mohler, H., Schwab, M.: Kunststoffe 71, 245 (1981)

    Google Scholar 

  69. Malavasic, T., Moze, A., Vizovisek, I., Lapanje, S.: Angew. Makromol. Chemie 44, 89 (1975)

    CAS  Google Scholar 

  70. Stevens, G. C., Richardson, M. J.: Polymer 24, 851 (1983)

    CAS  Google Scholar 

  71. Duswalt, A. A.: Thermochim. Acta 8, 57 (1974)

    CAS  Google Scholar 

  72. Abolafia, O. R.: SPE Ann. Tech. Conf., Proc. 15, 610 (1969)

    CAS  Google Scholar 

  73. Prime, R. B.: Analytical Calorimetry 2, 201 (1970)

    Google Scholar 

  74. Acitelli, M. A., Prime, R. B., Sacher, E.: Polymer 12, 335 (1971)

    CAS  Google Scholar 

  75. Prime, R. B., Sacher, E.: Polymer 13, 455 (1972)

    CAS  Google Scholar 

  76. Prime, R. B.: Polym. Eng. Sci. 13, 365 (1973)

    CAS  Google Scholar 

  77. Barton, J. M.: Makromol. Chem. 171, 247 (1973)

    CAS  Google Scholar 

  78. Barton, J. M.: J. Macromol. Sci.-Chem. A8, 25 (1974)

    Google Scholar 

  79. Cizmecioglu, M., Gupta, A.: SAMPE Qtly. April, 16 (1982)

    Google Scholar 

  80. Levy, N.: Analysis of an epoxy resin curing reaction by differential scanning calorimetry, in: Computer Applications in Applied Polymer Science, p. 313, ACS Symp. Ser. 197, Washington D.C., Amer. Chem. Soc. 1975

    Google Scholar 

  81. Cizmecioglu, M., Hong, S. D., Moacanin, J., Gupta, A.: ACS Polymer Preprints 22, (2), 224 (1981)

    CAS  Google Scholar 

  82. Severini, F., Gallo, R., Marullo, R.: J. Thermal Anal. 25, 515 (1982)

    CAS  Google Scholar 

  83. Horie, K., Hiura, H., Sawada, M., Mita, I., Kambe, H.: J. Polym. Sci., Part A-1 8, 1357 (1970)

    CAS  Google Scholar 

  84. Klute, C. H., Viehmann, W.: J. Appl. Polym. Sci. 5, 86 (1961)

    Google Scholar 

  85. Kamal., M. R., Sourour, S., Ryan, M.: SPE 31st Ann. Tech. Conf., Proc. 187 (1973)

    Google Scholar 

  86. Sourour, S., Kamal., M. R.: Thermochim. Acta 14, 41 (1976)

    CAS  Google Scholar 

  87. Ryan, M. E., Dutta, A.: Polymer 20, 203 (1979)

    CAS  Google Scholar 

  88. Flammersheim, H., Horhold, H., Bellstedt, K., Klee, J.: Makromol. Chem. 184, 113 (1983)

    CAS  Google Scholar 

  89. Barton, J. M.: Unpublished work

    Google Scholar 

  90. Lunak, S., Dusek, K.: J. Polym. Sci., Polym. Symp. No. 53, 45 (1975)

    Google Scholar 

  91. Lunak, S., Vladyka, J., Dusek, K.: Polymer 19, 931 (1978)

    CAS  Google Scholar 

  92. Dobas, I., Eichler, J.: Coll. Czech. Chem. Commun. 38, 2602 (1973)

    CAS  Google Scholar 

  93. Dobas, I., Eichler, J.: Coll. Czech. Chem. Commun. 38, 3279 (1973)

    CAS  Google Scholar 

  94. Dobas, I., Eichler, J., Klaban, J.: Coll. Czech. Chem. Commun. 40, 2989 (1975)

    CAS  Google Scholar 

  95. Johncock, P., Tudgey, G. F.: Brit. Polym. J. 15, 14 (1983)

    CAS  Google Scholar 

  96. Johncock, P., Porecha, L., Tudgey, G. F.: J. Polym. Sci., Polym. Chem. Ed. 23, 291 (1985)

    CAS  Google Scholar 

  97. Mones, E. T., Morgan, R. J.: ACS Polymer Preprints 22, 249 (1981)

    CAS  Google Scholar 

  98. Hagnauer, G. L., Pearce, P. J., LaLiberte, B. R., Roylance, M. E.: ACS Div. Org. Coat. Plast. Chem., Preprints 47, 429 (1982)

    Google Scholar 

  99. Gupta, A., Cizmecioglu, D., Coulter, R., Liang, R. H., Yavrouian, A., Tsay, F. D., Moacanin, J.: J. Appl. Polym. Sci. 28, 1011 (1983)

    Google Scholar 

  100. Apicella, A., Nicolais, L., Iannone, M., Passerini, P.: J. Appl. Polym. Sci. 29, 2083 (1984)

    CAS  Google Scholar 

  101. Mijovic, J., Kim, J., Slaby, J.: J. Appl. Polym. Sci. 20, 1449 (1984)

    Google Scholar 

  102. Morgan, R. J., Happe, J. A., Mones, E. T.: Paper presented at the 28th Nat. SAMPE Symposium, Annaheim, Calif., April (1983)

    Google Scholar 

  103. Zukas, W. X.: Ph. D Dissertation, Chem. Eng. Dept., Univ. of Mass., USA (1983)

    Google Scholar 

  104. Zukas, W. X., Schneider, N. S., MacKnight, W. J.: Paper presented at Fall Meeting, ACS, Washington DC (1983)

    Google Scholar 

  105. Lee, W. I., Loos, A. C., Springer, G. S.: J. Comp. Mat. 16, 510 (1982)

    CAS  Google Scholar 

  106. Gordon, M., Simpson, W.: Polymer 2, 303 (1961)

    Google Scholar 

  107. Barton, J. M.: Polymer 21, 603 (1980)

    CAS  Google Scholar 

  108. Olcese, T., Spelta, O., Vargiu, S.: J. Polym. Sci., Polym. Symp. No. 53, 113 (1975)

    CAS  Google Scholar 

  109. Miller, R. L., Oebser, M. A.: Thermochim. Acta 36, 121 (1980)

    CAS  Google Scholar 

  110. Barton, J. M.: Brit. Polym. J. 11, 115 (1979)

    CAS  Google Scholar 

  111. Barton, J. M.: Unpublished work

    Google Scholar 

  112. Barton, J. M.: Thermochim. Acta 71, 337 (1983)

    CAS  Google Scholar 

  113. Grentzer, T. H., Holsworth, R. M., Provder, T., Kline, S.: ACS Polymer Preprints 22, (1), 318 (1981)

    CAS  Google Scholar 

  114. Walkup, C. M., Morgan, R. J., Hoheisel, T. H.: ACS Polymer Preprints 25, (1), 187 (1984)

    CAS  Google Scholar 

  115. Riccardi, C. C., Adabbo, H. E., Williams, R. J. J.: J. Appl. Polym. Sci. 29, 2841 (1984)

    Google Scholar 

  116. Foun, C. C., Moroni, A., Pearce, E. M., Mijovic, J.: Polym. Mater. Sci. Eng. 51, 411 (1984)

    CAS  Google Scholar 

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Barton, J.M. (1985). The application of differential scanning calorimetry (DSC) to the study of epoxy resin curing reactions. In: Epoxy Resins and Composites I. Advances in Polymer Science, vol 72. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-15546-5_5

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