Abstract
This article reviews all the published work concerned with the study of vibrational optical activity in chiral molecules from measurements of a small difference in the intensity of Raman scattering in right and left circularly polarized incident light. The history and basic theory are described briefly, followed by an account of the instrumentation and the precautions that must be observed in order to suppress spurious signals. The various theories that have been proposed in order to relate stereochemical features to the observations are then outlined, this being followed by a survey of all reported Raman optical activity spectra.
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8 References
Barron, L. D., Buckingham, A. D.: Ann. Rev. Phys. Chem. 26, 381 (1975)
Barron, L. D.: Raman optical activity, in: Advances in Infrared and Raman Spectroscopy, Vol. 4 (eds. Clark, R. J. H., Hester, R. E.) p. 271, London, Heyden 1978
Barron, L. D.: Raman optical activity, in: Optical Activity and Chiral Discrimination (ed. Mason, S. F.) p. 219, Dordrecht, Reidel 1979
Barron, L. D.: Acc. Chem. Res. 13, 90 (1980)
Barron, L. D.: Molecular Light Scattering and Optical Activity, Cambridge, Cambridge Univ. Press 1982
Nafie, L. A., Diem, M.: Acc. Chem. Res. 12, 296 (1979)
Nafie, L. A.: Infrared and Raman vibrational optical activity, in: Vibrational Spectra and Structure, Vol. 10 (ed. Durig, J. R.) p. 153, Amsterdam, Elsevier 1981
Polavarapu, P. L.: Recent advances in model calculation of vibrational optical activity, in: Vibrational Spectra and Structure, Vol. 13 (ed. Durig, J. R.), Amsterdam, Elsevier (in the press)
Gans, R.: Z. Phys. 17, 353 (1923)
de Malleman, R.: Compt. Rend. 181, 371 (1925)
Bhagavantam, S., Venkateswaran, S.: Nature 125, 237 (1930)
Kastler, A.: Compt. Rend. 191, 565 (1930)
Perrin, F.: J. Chem. Phys. 10, 415 (1942)
Atkins, P. W., Barron, L. D.: Mol. Phys. 16, 453 (1969)
Barron, L. D., Buckingham, A. D.: ibid. 20, 1111 (1971)
Bosnich, B., Moskovits, M., Ozin, G. A.: J. Am. Chem. Soc., 94, 4750 (1972)
Diem, M., Fry, J. L., Burow, D. F.: ibid. 95, 253 (1973)
Barron, L. D., Bogaard, M. P., Buckingham, A. D.: ibid. 95, 603 (1973)
Barron, L. D., Bogaard, M. P., Buckingham, A. D.: Nature 241, 113 (1973)
Barron, L. D., Buckingham, A. D.: J. Chem. Soc., Chem. Commun. 1974, 152
Hug, W., Kint, S., Bailey, G. F., Scherer, J. R.: J. Am. Chem. Soc. 97, 5589 (1975)
Diem, M., Diem, M. J., Hudgens, B. A., Fry, J. L., Burow, D. F.: J. Chem. Soc., Chem. Commun. 1976, 1028
Boucher, H., Brocki, T. R., Moskovits, M., Bosnich, B.: J. Am. Chem. Soc. 99, 6870 (1977)
Waki, H., Higuchi, S., Tanaka, S., Sakayanag, N.: J. Spectrosc. Soc. Japan 26, 272 (1977)
Barron, L. D., Vrbancich, J.: Magnetic Raman optical activity, in: Advances in Infrared and Raman Spectroscopy, (eds. Clark, R. J. H., Hester, R. E.) London, Heyden, in the press
Buckingham, A. D.: Adv. Chem. Phys. 12, 107 (1967)
Long, D. A.: Raman Spectroscopy, New York, McGraw-Hill 1977
Andrews, D. L.: J. Chem. Phys. 72, 4141 (1980)
Bjarnason, J. O., Andersen, H. C., Hudson, B. S.: ibid. 72, 4132 (1980)
Oudar, J. L., Minot, C., Garetz, B. A.: ibid. 76, 2227 (1982)
Barron, L. D.: Rayleigh and Raman scattering of polarized light, in: Molecular Spectroscopy, Vol. 4 (eds. Barrow, R. F., Long, D. A., Sheridan, J.) p. 96, London, The Chemical Society 1976
Buckingham, A. D., Longuet-Higgins, H. C.: Mol. Phys. 14, 63 (1968)
Polavarapu, P. L., Diem, M., Nafie, L. A.: J. Am. Chem. Soc. 102, 5449 (1980)
Brocki, T., Moskovits, M., Bosnich, B.: ibid. 102, 495 (1980)
Hug, W., Surbeck, H.: Chem. Phys. Letters 60, 186 (1979)
Talmi, Y.: Optoelectronic image detectors in chemistry, in: Multichannel Image Detectors (ed. Talmi, Y.), A.C.S. Symposium series, Vol. 102, p. 3, Washington D.C., Americal Chemical Society 1979
Horlick, G.: Appl. Spectrosc. 30, 113 (1976)
Hug, W.: Instrumental and theoretical advances in Raman optical activity, in: Raman Spectroscopy (eds. Lascombe, J., Huong, P. V.) p. 3, Chichester, Wiley, 1982
Barron, L. D., Torrance, J. F.: Chem. Phys. Letters (in the press)
Barron, L. D., Buckingham, A. D.: U.K. Pat. No. 6454 (1971); U.S. Pat. No. 3817634 (1974)
Hug, W.: Appl. Spectrosc. 35, 115 (1981)
Barron, L. D., Vrbancich, J.: J. Raman Spectrosc. (in the press)
Barron, L. D., Buckingham, A. D.: J. Am. Chem. Soc. 96, 4769 (1974)
Barron, L. D., Buckingham, A. D.: ibid. 101, 1979 (1979)
Barron, L. D., Clark, B. P.: Mol. Phys. 46, 839 (1982)
Sverdlov, L. M., Kovner, M. A., Krainov, E. P.: Vibrational Spectra of Polyatomic Molecules, Jerusalem, Israel Program for Scientific Translations 1974
Gussoni, M.: Infrared and Raman intensities from electro-optical parameters, in: Advances in Infrared and Raman Spectroscopy, Vol. 6 (eds. Clark, R. J. H., Hester, R. E.) p. 61, London, Heyden, 1980
Placzek, G.: Rayleigh and Raman scattering, in: Handbuch der Radiologie, Vol. 6, Part 2, (ed. Marx, E.) p. 205, Leipzig, Akademische Verlagsgesellschaft 1934
Wilson, E. B., Decius, J. C., Cross, P. C.: Molecular Vibrations, New York, McGraw-Hill 1955
Barron, L. D., Clark, B. P.: J. Raman Spectrosc. 13, 155 (1982)
Applequist, J.: Acc. Chem. Res. 10, 79 (1977)
Prasad, P. L., Burow, D. F.: J. Am. Chem. Soc. 101, 800 (1979)
Prasad, P. L., Burow, D. F.: ibid. 101, 806 (1979)
Prasad, P. L., Nafie, L. A.: J. Chem. Phys. 70, 5582 (1979)
Prasad, P. L., Nafie, L. A., Burow, D. F.: J. Raman Spectrosc. 8, 255 (1979)
Polavarapu, P. L., Nafie, L. A.: J. Chem. Phys. 73, 1567 (1980)
Nafie, L. A., Polavarapu, P. L., Diem, M.: ibid. 73, 3530 (1980)
Nafie, L. A., Freedman, T. B.: ibid. 75, 4847 (1981)
Polavarapu, P. L.: ibid. 77, 2273 (1982)
Freedman, T. B., Nafie, L. A.: ibid. 78, 27 (1983)
Komornicki, A., McIver, J. W.: ibid. 70, 2014 (1979)
Barron, L. D.: J. Chem. Soc. A. 1971, 2899
Stone, A. J.: Mol. Phys. 29, 1461 (1975)
Stone, A. J.: ibid. 33, 293 (1977)
Andrews, D. L., Thirunamachandran, T.: Proc. Roy. Soc. A358, 297 (1977)
Andrews, D. L., Thirunamachandran, T.: ibid. A358, 311 (1977)
Gohin, A., Moskovits, M.: J. Am. Chem. Soc. 10, 1660 (1981)
Barron, L. D., Vrbancich, J.: Mol. Phys. 48, 833 (1983)
Barron, L. D., Torrance, J. F., Vrbancich, J.: J. Raman Spectrosc. 13, 171 (1982)
Cuony, B., Hug, W.: Chem. Phys. Letters 84, 131 (1981)
Barron, L. D., Clark, B. P.: J. Chem. Soc., Perkin Trans. II 1979, 1164
Barron, L. D., Clark, B. P.: ibid. 1979, 1171
Barron, L. D.: Nature 255, 458 (1975)
Barron, L. D.: J. Chem. Soc., Perkin Trans. II 1977, 1790
Su, C. N., Keiderling, T. A.: Chem. Phys. Letters 77, 494 (1981)
Hug, W., Kamatari, A., Srinivasan, K., Hansen, H.-J., Sliwka, H.-R.: ibid. 76, 469 (1980)
Barron, L. D., Clark, B. P.: J. Chem. Res. (S) 1979, 36
Barron, L. D.: J. Chem. Soc., Perkin Trans II 1977, 1074
Torrance, J. F.: Ph. D. Thesis, Glasgow Univ. 1983
Barron, L. D.: Tetrahedron 34, 607 (1978)
Polavarapu, P. L., Diem, M., Nafie, L. A.: J. Am Chem. Soc. 102, 5449 (1980)
Barron, L. D.: J. Chem. Soc., Chem. Commun. 1977, 305
Barron, L. D., Numan, H., Wynberg, H.: ibid. 1978, 259
Barron, L. D., Vrbancich, J.: Mol. Phys. 48, 833 (1983)
Barron, L. D., Vrbancich, J.: J. Chem. Soc., Chem. Commun. 1981, 771
Waki, H., Higuchi, S., Tanaka, S.: Chem. Letters 1981, 147
Higuchi, S., Tanaka, K., Tanaka, S.: ibid. 1982, 635
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Barron, L.D., Vrbancich, J. (1984). Natural vibrational Raman optical activity. In: Structural Chemistry. Topics in Current Chemistry, vol 123. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-13099-3_4
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DOI: https://doi.org/10.1007/3-540-13099-3_4
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