Skip to main content

Natural vibrational Raman optical activity

  • Conference paper
  • First Online:
Structural Chemistry

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 123))

Abstract

This article reviews all the published work concerned with the study of vibrational optical activity in chiral molecules from measurements of a small difference in the intensity of Raman scattering in right and left circularly polarized incident light. The history and basic theory are described briefly, followed by an account of the instrumentation and the precautions that must be observed in order to suppress spurious signals. The various theories that have been proposed in order to relate stereochemical features to the observations are then outlined, this being followed by a survey of all reported Raman optical activity spectra.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

8 References

  1. Barron, L. D., Buckingham, A. D.: Ann. Rev. Phys. Chem. 26, 381 (1975)

    Article  Google Scholar 

  2. Barron, L. D.: Raman optical activity, in: Advances in Infrared and Raman Spectroscopy, Vol. 4 (eds. Clark, R. J. H., Hester, R. E.) p. 271, London, Heyden 1978

    Google Scholar 

  3. Barron, L. D.: Raman optical activity, in: Optical Activity and Chiral Discrimination (ed. Mason, S. F.) p. 219, Dordrecht, Reidel 1979

    Google Scholar 

  4. Barron, L. D.: Acc. Chem. Res. 13, 90 (1980)

    Article  Google Scholar 

  5. Barron, L. D.: Molecular Light Scattering and Optical Activity, Cambridge, Cambridge Univ. Press 1982

    Google Scholar 

  6. Nafie, L. A., Diem, M.: Acc. Chem. Res. 12, 296 (1979)

    Article  Google Scholar 

  7. Nafie, L. A.: Infrared and Raman vibrational optical activity, in: Vibrational Spectra and Structure, Vol. 10 (ed. Durig, J. R.) p. 153, Amsterdam, Elsevier 1981

    Google Scholar 

  8. Polavarapu, P. L.: Recent advances in model calculation of vibrational optical activity, in: Vibrational Spectra and Structure, Vol. 13 (ed. Durig, J. R.), Amsterdam, Elsevier (in the press)

    Google Scholar 

  9. Gans, R.: Z. Phys. 17, 353 (1923)

    Article  Google Scholar 

  10. de Malleman, R.: Compt. Rend. 181, 371 (1925)

    Google Scholar 

  11. Bhagavantam, S., Venkateswaran, S.: Nature 125, 237 (1930)

    Google Scholar 

  12. Kastler, A.: Compt. Rend. 191, 565 (1930)

    Google Scholar 

  13. Perrin, F.: J. Chem. Phys. 10, 415 (1942)

    Article  Google Scholar 

  14. Atkins, P. W., Barron, L. D.: Mol. Phys. 16, 453 (1969)

    Google Scholar 

  15. Barron, L. D., Buckingham, A. D.: ibid. 20, 1111 (1971)

    Google Scholar 

  16. Bosnich, B., Moskovits, M., Ozin, G. A.: J. Am. Chem. Soc., 94, 4750 (1972)

    Article  Google Scholar 

  17. Diem, M., Fry, J. L., Burow, D. F.: ibid. 95, 253 (1973)

    Article  Google Scholar 

  18. Barron, L. D., Bogaard, M. P., Buckingham, A. D.: ibid. 95, 603 (1973)

    Article  Google Scholar 

  19. Barron, L. D., Bogaard, M. P., Buckingham, A. D.: Nature 241, 113 (1973)

    Google Scholar 

  20. Barron, L. D., Buckingham, A. D.: J. Chem. Soc., Chem. Commun. 1974, 152

    Google Scholar 

  21. Hug, W., Kint, S., Bailey, G. F., Scherer, J. R.: J. Am. Chem. Soc. 97, 5589 (1975)

    Article  Google Scholar 

  22. Diem, M., Diem, M. J., Hudgens, B. A., Fry, J. L., Burow, D. F.: J. Chem. Soc., Chem. Commun. 1976, 1028

    Google Scholar 

  23. Boucher, H., Brocki, T. R., Moskovits, M., Bosnich, B.: J. Am. Chem. Soc. 99, 6870 (1977)

    Article  Google Scholar 

  24. Waki, H., Higuchi, S., Tanaka, S., Sakayanag, N.: J. Spectrosc. Soc. Japan 26, 272 (1977)

    Google Scholar 

  25. Barron, L. D., Vrbancich, J.: Magnetic Raman optical activity, in: Advances in Infrared and Raman Spectroscopy, (eds. Clark, R. J. H., Hester, R. E.) London, Heyden, in the press

    Google Scholar 

  26. Buckingham, A. D.: Adv. Chem. Phys. 12, 107 (1967)

    Google Scholar 

  27. Long, D. A.: Raman Spectroscopy, New York, McGraw-Hill 1977

    Google Scholar 

  28. Andrews, D. L.: J. Chem. Phys. 72, 4141 (1980)

    Article  Google Scholar 

  29. Bjarnason, J. O., Andersen, H. C., Hudson, B. S.: ibid. 72, 4132 (1980)

    Article  Google Scholar 

  30. Oudar, J. L., Minot, C., Garetz, B. A.: ibid. 76, 2227 (1982)

    Article  Google Scholar 

  31. Barron, L. D.: Rayleigh and Raman scattering of polarized light, in: Molecular Spectroscopy, Vol. 4 (eds. Barrow, R. F., Long, D. A., Sheridan, J.) p. 96, London, The Chemical Society 1976

    Google Scholar 

  32. Buckingham, A. D., Longuet-Higgins, H. C.: Mol. Phys. 14, 63 (1968)

    Google Scholar 

  33. Polavarapu, P. L., Diem, M., Nafie, L. A.: J. Am. Chem. Soc. 102, 5449 (1980)

    Article  Google Scholar 

  34. Brocki, T., Moskovits, M., Bosnich, B.: ibid. 102, 495 (1980)

    Article  Google Scholar 

  35. Hug, W., Surbeck, H.: Chem. Phys. Letters 60, 186 (1979)

    Article  Google Scholar 

  36. Talmi, Y.: Optoelectronic image detectors in chemistry, in: Multichannel Image Detectors (ed. Talmi, Y.), A.C.S. Symposium series, Vol. 102, p. 3, Washington D.C., Americal Chemical Society 1979

    Google Scholar 

  37. Horlick, G.: Appl. Spectrosc. 30, 113 (1976)

    Google Scholar 

  38. Hug, W.: Instrumental and theoretical advances in Raman optical activity, in: Raman Spectroscopy (eds. Lascombe, J., Huong, P. V.) p. 3, Chichester, Wiley, 1982

    Google Scholar 

  39. Barron, L. D., Torrance, J. F.: Chem. Phys. Letters (in the press)

    Google Scholar 

  40. Barron, L. D., Buckingham, A. D.: U.K. Pat. No. 6454 (1971); U.S. Pat. No. 3817634 (1974)

    Google Scholar 

  41. Hug, W.: Appl. Spectrosc. 35, 115 (1981)

    Google Scholar 

  42. Barron, L. D., Vrbancich, J.: J. Raman Spectrosc. (in the press)

    Google Scholar 

  43. Barron, L. D., Buckingham, A. D.: J. Am. Chem. Soc. 96, 4769 (1974)

    Article  Google Scholar 

  44. Barron, L. D., Buckingham, A. D.: ibid. 101, 1979 (1979)

    Article  Google Scholar 

  45. Barron, L. D., Clark, B. P.: Mol. Phys. 46, 839 (1982)

    Google Scholar 

  46. Sverdlov, L. M., Kovner, M. A., Krainov, E. P.: Vibrational Spectra of Polyatomic Molecules, Jerusalem, Israel Program for Scientific Translations 1974

    Google Scholar 

  47. Gussoni, M.: Infrared and Raman intensities from electro-optical parameters, in: Advances in Infrared and Raman Spectroscopy, Vol. 6 (eds. Clark, R. J. H., Hester, R. E.) p. 61, London, Heyden, 1980

    Google Scholar 

  48. Placzek, G.: Rayleigh and Raman scattering, in: Handbuch der Radiologie, Vol. 6, Part 2, (ed. Marx, E.) p. 205, Leipzig, Akademische Verlagsgesellschaft 1934

    Google Scholar 

  49. Wilson, E. B., Decius, J. C., Cross, P. C.: Molecular Vibrations, New York, McGraw-Hill 1955

    Google Scholar 

  50. Barron, L. D., Clark, B. P.: J. Raman Spectrosc. 13, 155 (1982)

    Article  Google Scholar 

  51. Applequist, J.: Acc. Chem. Res. 10, 79 (1977)

    Article  Google Scholar 

  52. Prasad, P. L., Burow, D. F.: J. Am. Chem. Soc. 101, 800 (1979)

    Article  Google Scholar 

  53. Prasad, P. L., Burow, D. F.: ibid. 101, 806 (1979)

    Article  Google Scholar 

  54. Prasad, P. L., Nafie, L. A.: J. Chem. Phys. 70, 5582 (1979)

    Article  Google Scholar 

  55. Prasad, P. L., Nafie, L. A., Burow, D. F.: J. Raman Spectrosc. 8, 255 (1979)

    Article  Google Scholar 

  56. Polavarapu, P. L., Nafie, L. A.: J. Chem. Phys. 73, 1567 (1980)

    Article  Google Scholar 

  57. Nafie, L. A., Polavarapu, P. L., Diem, M.: ibid. 73, 3530 (1980)

    Article  Google Scholar 

  58. Nafie, L. A., Freedman, T. B.: ibid. 75, 4847 (1981)

    Article  Google Scholar 

  59. Polavarapu, P. L.: ibid. 77, 2273 (1982)

    Article  Google Scholar 

  60. Freedman, T. B., Nafie, L. A.: ibid. 78, 27 (1983)

    Article  Google Scholar 

  61. Komornicki, A., McIver, J. W.: ibid. 70, 2014 (1979)

    Article  Google Scholar 

  62. Barron, L. D.: J. Chem. Soc. A. 1971, 2899

    Google Scholar 

  63. Stone, A. J.: Mol. Phys. 29, 1461 (1975)

    Google Scholar 

  64. Stone, A. J.: ibid. 33, 293 (1977)

    Google Scholar 

  65. Andrews, D. L., Thirunamachandran, T.: Proc. Roy. Soc. A358, 297 (1977)

    Google Scholar 

  66. Andrews, D. L., Thirunamachandran, T.: ibid. A358, 311 (1977)

    Google Scholar 

  67. Gohin, A., Moskovits, M.: J. Am. Chem. Soc. 10, 1660 (1981)

    Article  Google Scholar 

  68. Barron, L. D., Vrbancich, J.: Mol. Phys. 48, 833 (1983)

    Google Scholar 

  69. Barron, L. D., Torrance, J. F., Vrbancich, J.: J. Raman Spectrosc. 13, 171 (1982)

    Article  Google Scholar 

  70. Cuony, B., Hug, W.: Chem. Phys. Letters 84, 131 (1981)

    Article  Google Scholar 

  71. Barron, L. D., Clark, B. P.: J. Chem. Soc., Perkin Trans. II 1979, 1164

    Google Scholar 

  72. Barron, L. D., Clark, B. P.: ibid. 1979, 1171

    Google Scholar 

  73. Barron, L. D.: Nature 255, 458 (1975)

    Google Scholar 

  74. Barron, L. D.: J. Chem. Soc., Perkin Trans. II 1977, 1790

    Google Scholar 

  75. Su, C. N., Keiderling, T. A.: Chem. Phys. Letters 77, 494 (1981)

    Article  Google Scholar 

  76. Hug, W., Kamatari, A., Srinivasan, K., Hansen, H.-J., Sliwka, H.-R.: ibid. 76, 469 (1980)

    Article  Google Scholar 

  77. Barron, L. D., Clark, B. P.: J. Chem. Res. (S) 1979, 36

    Google Scholar 

  78. Barron, L. D.: J. Chem. Soc., Perkin Trans II 1977, 1074

    Google Scholar 

  79. Torrance, J. F.: Ph. D. Thesis, Glasgow Univ. 1983

    Google Scholar 

  80. Barron, L. D.: Tetrahedron 34, 607 (1978)

    Article  Google Scholar 

  81. Polavarapu, P. L., Diem, M., Nafie, L. A.: J. Am Chem. Soc. 102, 5449 (1980)

    Article  Google Scholar 

  82. Barron, L. D.: J. Chem. Soc., Chem. Commun. 1977, 305

    Google Scholar 

  83. Barron, L. D., Numan, H., Wynberg, H.: ibid. 1978, 259

    Google Scholar 

  84. Barron, L. D., Vrbancich, J.: Mol. Phys. 48, 833 (1983)

    Google Scholar 

  85. Barron, L. D., Vrbancich, J.: J. Chem. Soc., Chem. Commun. 1981, 771

    Google Scholar 

  86. Waki, H., Higuchi, S., Tanaka, S.: Chem. Letters 1981, 147

    Google Scholar 

  87. Higuchi, S., Tanaka, K., Tanaka, S.: ibid. 1982, 635

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 1984 Springer-Verlag

About this paper

Cite this paper

Barron, L.D., Vrbancich, J. (1984). Natural vibrational Raman optical activity. In: Structural Chemistry. Topics in Current Chemistry, vol 123. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-13099-3_4

Download citation

  • DOI: https://doi.org/10.1007/3-540-13099-3_4

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-13099-4

  • Online ISBN: 978-3-540-38824-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics