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Solvatochromism and Nonlinear Optical Properties of Donor-acceptor π-Conjugated Molecules

  • Chapter
Non-Linear Optical Properties of Matter

Part of the book series: Challenges and Advances in Computational Chemistry and Physics ((COCH,volume 1))

Abstract

We review the theoretical approaches based on the perturbation theory, namely few-states approximations. These approaches are extensively used in the description of the solvent effects on nonlinear response of molecular systems. The connection between the nonlinear optical response and solvatochromic behavior of the donor-acceptor π-conjugated molecules is considered. The general relations between molecular (hyper)polarizabilities and two-photon absorption for the positively and negatively solvatochromic compounds are presented

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Authors and Affiliations

  1. Institute of Physical and Theoretical Chemistry, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

    Wojciech Bartkowiak

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  1. Wojciech Bartkowiak
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  1. National Hellenic Research Foundation, Greece

    Manthos G. Papadopoulos

  2. Nicolaus Copernicus University, Poland

    Andrzej J. Sadlej

  3. Jackson State University, USA

    Jerzy Leszczynski

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Bartkowiak, W. (2006). Solvatochromism and Nonlinear Optical Properties of Donor-acceptor π-Conjugated Molecules. In: Papadopoulos, M.G., Sadlej, A.J., Leszczynski, J. (eds) Non-Linear Optical Properties of Matter. Challenges and Advances in Computational Chemistry and Physics, vol 1. Springer, Dordrecht. https://doi.org/10.1007/1-4020-4850-5_9

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