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Fe-M-B (M = IVa TO VIa Metal) Nanocrystalline Soft Magnetic Materials

A Review of Alloy Development

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Properties and Applications of Nanocrystalline Alloys from Amorphous Precursors

Part of the book series: NATO Science Series ((NAII,volume 184))

Abstract

A novel approach employed in the development of soft magnetic materials is to reduce the structural correlation length (grain size) below the ferromagnetic correlation length (∼ domain wall width). This approach has successfully been applied to the development of Fe-rich Fe-M-B (M = IVa to VIa metal) nano-crystalline soft magnetic alloys, commercially known as NANOPERM. In this paper, research on these nanocrystalline soft magnetic alloys is reviewed and the principles underlying alloy design are summarized. Some prospects for further alloy development in the Fe-M-B system are also discussed.

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References

  1. Herzer, G. (1997) Nanocrystalline soft magnetic alloys, in Handbook of Magnetic Materials, K.H.J. Buschow (ed.), Vol. 10, Elsevier Science, pp. 415–462.

    Google Scholar 

  2. Yoshizawa, Y., Oguma, S. and Yamauchi, K. (1988) New Fe-based soft magnetic alloys composed ofultrafine grain structure, J. Appl. Phys. 64, 6044–6046.

    Google Scholar 

  3. Suzuki, K., Kataoka, N., Inoue, A., Makino, A. and Masumoto, T. (1990) High saturation magnetization and soft magnetic properties of bcc Fe-Zr-B alloys with ultrafine grain structure, Mater. Trans. JIM 31, 743–746.

    Google Scholar 

  4. Suzuki, K., Makino, A., Inoue, A. and Masumoto, T. (1991) Soft magnetic properties of nanocrystalline bcc Fe-Zr-B and Fe-M-B-Cu (M = transition metal) alloys with high saturation magnetization, J. Appl. Phys. 70, 6232–6237.

    Google Scholar 

  5. Alben, R., Becker, J.J. and Chi, M.C. (1978) Random anisotropy in amorphous magnets, J. Appl. Phys 49, 1653–1658.

    Google Scholar 

  6. Hasegawa, R. (1991) Amorphous magnetic materials — a history, J. Magn. Magn. Mater. 100, 1–12.

    Google Scholar 

  7. Hoffmann, H. (1973) Static wall coercive force in ferromagnetic thin films, IEEE Trans. Magn. 9, 17–21.

    Google Scholar 

  8. Herzer, G. (1989) Grain structure and magnetism of nanocrystalline ferromagnets, IEEE Trans. Magn. 25, 3327–3329.

    Google Scholar 

  9. Kataoka, N., Suzuki, K., Inoue, A. and Masumoto, T. (1991) Magnetic properties of ironbase bcc alloys produced by mechanical alloying, J. Mater. Sci. 26, 4621–4625.

    Google Scholar 

  10. Kataoka, N., Hosokawa, M., Inoue, A. and Masumoto, T. (1989) Magnetic properties of Fe-based binary crystalline alloys produced by vapor quenching, Jpn. J. Appl. Phys. 28, L462–L464.

    Google Scholar 

  11. Suzuki, K., Makino, A., Inoue, A. and Masumoto, T. (1994) Formation of nanocrystalline structure by crystallization of amorphous Fe-M-B (M = IVa to VIa group metal) alloys, Sci. Rep. RITU A39, 133–140.

    Google Scholar 

  12. Hono, K. (1999) Atom probe microanalysis and nanoscale microstructures in metallic materials, Acta mater. 47, 3127–3145.

    Google Scholar 

  13. Kronmüller, H., Frank, W. and Hörner, A. (1991) Diffusion and structural-relaxation mechanisms in metallic glasses, Mater. Sci. Eng. A133, 410–414.

    Google Scholar 

  14. Suzuki, K., Sahajwalla, V., Cadogan, J.M., Inoue, A. and Masumoto, T. (1996) The role of the M element in nanocrystalline Fe-M-B (M = Zr, Hf and Nb) soft magnetic alloys, Mater. Sci. Forum 225–227, 665–670.

    Google Scholar 

  15. Suzuki, K., Makino, A., Inoue, A. and Masumoto, T. (1993) Soft magnetic properties of Fe-Hf-B ternary alloys with nanoscale bcc structure, J. Jpn. Inst. Metals 57, 964–971.

    Google Scholar 

  16. Yoshizawa, Y. and Yamauchi, K (1989) Fe based soft magnetic alloys composed of ultrafine grain structure, J. Jpn. Inst. Metals 53, 241–248.

    Google Scholar 

  17. Zhang, Y., Hono, K., Inoue, A. and Sakurai, T. (1996) APFIM studies of nanocrystalline microstructural evolution in Fe-Zr-B(-Cu) amorphous alloys, Mater. Sci. Eng. A217–218, 407–413.

    Google Scholar 

  18. Yoshizawa, Y. and Yamauchi, K. (1989) Magnetic properties of Fe-M-Cu-Nb-Si-B (M = Co, Ni) alloys, Abstracts of the 104th Spring Meeting of the Japan Institute of Metals, The Japan Institute of Metals, Sendai, p. 97.

    Google Scholar 

  19. Kimura, H., Murakami, Y., Suzuki, K., Inoue, A. and Masumoto, T. (1991) Formation of nanocrystalline non-equilibrium phase by controlling crystallization of an amorphous phase, The 2nd Reports on the Cooperative Research Programs of the Laboratory for Advanced Materials, Institute for Materials Research, Tohoku University, Sendai, 155–157.

    Google Scholar 

  20. Suzuki, K., Makino, A., Inoue, A. and Masumoto, T. (1994) Soft magnetic properties of nanocrystalline Fe-Co-Zr-B alloys, J. Magn. Soc. Jpn. 18, 800–804.

    Google Scholar 

  21. Ślawska-Waniewska, A. and Lachowicz, H.K. (2003) Magnetostriction in soft magnetic nanocrystalline materials, Scripta Mater. 48, 889–894.

    Google Scholar 

  22. Miglierini, M. and Greneche, J.M. (1997) Mössbauer spectrometry of Fe(Cu)MB-type nanocrystalline alloys: II. The topography of hyperfine interactions in Fe(Cu)ZrB alloys, J. Phys,: Condens. Matter 9, 2312–2347.

    Google Scholar 

  23. Ito, S., Aso, K., Makino, Y. and Ueda, S. (1980) Magnetostriction and magnetization of iron-based amorphous alloys, Appl. Phys. Lett. 37, 665–666.

    Google Scholar 

  24. Willard, M.A., Laughlin, D.E., McHenry, M.E., Thoma, D., Sickafus, K., Cross, J.O. and Harris, V.G. (1998) Structure and magnetic properties of (Fe0.5Co0.5)88Zr7B4Cu1 nanocrystalline alloys, J. Appl. Phys. 84, 6773–6777.

    Google Scholar 

  25. Skorvanek, I., Svec, P., Marcin, J., Kovac, J., Krenicky, T. and Deanko, M. (2003) Nanocrystalline Cu-free HITPERM alloys with improved soft magnetic properties, Phys. Stat. Sol. A196, 217–220.

    Google Scholar 

  26. Kataoka, N., Matsunaga, T., Inoue, A. and Masumoto, T. (1989) Soft magnetic properties of bcc Fe-Au-X-Si-B (X = early transition metal) alloys with fine grain structure, Mater. Trans. JIM, 30, 947–950.

    Google Scholar 

  27. Sawa, T and Takahashi, Y. (1990) Magnetic properties of FeCu(3d transition metals)SiB alloys with fine grain structure, J. Appl. Phys. 67, 5565–5567.

    Google Scholar 

  28. Yoshizawa, Y. and Yamauchi, K (1991) Magnetic properties of Fe-Cu-M-Si-B (M = Cr, V, Mo, Nb, Ta, W) alloys, Mater. Sci. Eng. A133, 176–179.

    Google Scholar 

  29. Fujii, Y, Fujita, H., Seki, A. and Tomida, T. (1991) Magnetic properties of fine crystalline Fe-P-C-Cu-X alloys, J. Appl. Phys. 70, 6241–6243.

    Google Scholar 

  30. Yoshizawa, Y., Bizen, Y., Yamauchi, K. and Sugihara, H. (1992) Improvement of magnetic properties in Fe-based nanocrystalline alloys by addition of Si, Ge, C, Ga, P, Al elements and their applications, Trans. IEE Jpn. A112, 553–558.

    Google Scholar 

  31. Watanabe, H., Saito, H. and Takahashi, M. (1993) Soft magnetic properties and structures of nanocrystalline Fe-Al-Si-Nb-B alloy ribbons, J. Magn. Soc. Jpn. 17, 191–196.

    Google Scholar 

  32. Chou, T., Igarashi, M. and Narumiya, Y. (1993) Soft magnetic properties of microcrystalline Fe-Al-Si-Ni-Zr-B alloys, J. Magn. Soc. Jpn. 17, 197–200.

    Google Scholar 

  33. Tomida, T. (1994) Crystallization of Fe-Si-B-Ga-Nb amorphous alloy, Mater. Sci. Eng. A179–180, 521–525.

    Google Scholar 

  34. Kopcewicz, M. and Idzikowski, B. (2003) Nanocrystalline Fe81−xNixZr7B12 (x = 10−40) alloys investigated by Mössbauer spectroscopy, in Material Research in Atomic Scale by Mössbauer Spectroscopy, M. Mashlan et al. (eds.) Kluwer Academic Publishers, pp. 147–158.

    Google Scholar 

  35. Hayashi, K., Hayakawa, M., Ishikawa, W., Ochiai, Y., Matsuda, H., Iwasaki, Y. and Aso, K. (1987) New crystalline soft magnetic alloy with high saturation magnetization, J. Appl. Phys., 61, 3514–3519.

    Google Scholar 

  36. Suzuki, K. and Cadogan, J.M. (1998) Random magnetocrystalline anisotropy in two-phase nanocrystalline systems, Phys. Rev. B58, 2730–2739.

    Google Scholar 

  37. Suzuki, K., Herzer, G. and Cadogan, J.M. (1998) The effect of coherent uniaxial anisotropies on the grain size dependence of coercivity in nanocrystalline soft magnetic alloys, J. Magn. Magn. Mater. 177–181, 949–950.

    Google Scholar 

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Suzuki, K. (2005). Fe-M-B (M = IVa TO VIa Metal) Nanocrystalline Soft Magnetic Materials. In: Idzikowski, B., Švec, P., Miglierini, M. (eds) Properties and Applications of Nanocrystalline Alloys from Amorphous Precursors. NATO Science Series, vol 184. Springer, Dordrecht. https://doi.org/10.1007/1-4020-2965-9_1

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