Skip to main content
SpringerLink
Log in

A Coated Wire-type Lead(II) Ion-Selective Electrode Based on a Phosphorylated Calix[4]arene Derivative

  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

The preparation of a lead-selective electrode based on 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis-(diphenylphosphinoylmethoxy)calix[4]arene (1) as an ionophore is reported. The plasticized PVC membrane containing 30% PVC, 57% ortho-nitrophenyloctylether (NPOE), 4% sodium tetraphenylborate (NaTPB) and 9% ionophore 1 was directly coated on a graphite electrode. It exhibits a nearly Nernstian slope of 28.0 ± 0.2 mV decade-1 over a concentration range of 1 × 10-5 - 1 × 10-2 mol dm-3 with a detection limit of 1.4 × 10-6 mol dm-3. The response time of the electrode was found to be ca. 17 s. The potential of the sensor was independent of the pH variation in the range 3.5–5.0. The selectivity of the electrode performance towards lead ions over Th4*, La3+, Sm3+, Dy3+, Y3+, Ca2+, Sr2+, Cd2+, Mn2+, Zn2+, Ni2+, Co2+, NH4+ Ag+, Li+, Na+ and K+ ions was investigated. The prepared electrode was used successfully as an indicator electrode for a potentiometric titration of a lead solution using a standard solution of EDTA. The applicability of the sensor for Pb2+ measurements in various synthetic water samples spiked with lead nitrate was also checked.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. Marian (ed.), “Metals and Their Compounds in the Environment”, 1991, VCH, Weinheim.

    Google Scholar 

  2. Y. Umezawa (ed.), “Handbook of Ion-Selective Electrodes”, 1990, CRC Press, Boca Raton, FL.

    Google Scholar 

  3. Y. A. Zolotov (ed.), “Macrocyclic Compounds in Analytical Chemistry”, 1997, John Wiley, New York.

    Google Scholar 

  4. V. Böhmer, Angew. Chem., Int. Ed. Engl., 1995, 34, 1713

    Article  Google Scholar 

  5. C. Wieser-Jeunesse, D. Matt, M. R. Yaftian, M. Burgard, and J. M. Harrowfield, C. R. Acad. Sci. Paris, t. 1, Série II c, 1998, 479

    Google Scholar 

  6. I. S. Antipin, E. Kh. Kazakova, W. D. Habicher, and A. I. Konovalov, Russ. Chem. Rev., 1998, 67, 905

    Article  Google Scholar 

  7. R. Ludwig, Fresenius J. Anal. Chem., 2000, 367, 103.

    Article  CAS  Google Scholar 

  8. A. M. Cadogan, D. Diamond, M. R. Smyth, M. Deasy, M. A. McKervey, and S. J. Harris, Analyst, 1989, 114, 1551.

    Article  CAS  Google Scholar 

  9. E. Malinowska, Z. Brzózka, K. Kasiura, R. M. Egberink, and D. N. Reinhoudt, Anal. Chim. Acta, 1994, 298, 245.

    Article  CAS  Google Scholar 

  10. T. Gray, S. Makuta, D. Diamond, D. J. Marrs, M. A. McKervey, and P. O’Hagan, Anal. Proc. Commun., 1995, 32, 471.

    Article  Google Scholar 

  11. T. McKittrick, D. Diamond, D. J. Marrs, P. O’Hagan, and M. A. McKervey, Talanta, 1996, 43, 1145.

    Article  CAS  Google Scholar 

  12. K. Kimura, K. Tatsumi, S. Yajima, S. Miyake, H. Sakamoto, and M. Yokoyama, Chem. Lett., 1998, 833.

    Google Scholar 

  13. J. S. Kim, A. Ohki, R. Ueki, T. Ishizuka, T. Shimotashiro, and S. Maeda, Talanta, 1999, 48, 705.

    Article  CAS  Google Scholar 

  14. K. Mimura, S. Yajima, K. Tatsumi, M. Yokoyama, and M. Oue, Anal. Chem., 2000, 72, 5290.

    Article  Google Scholar 

  15. D. R. Lynarn, L. G. Plantanida, and J. F. Cole, “Environmental Lead”, 1975, Academic Press, New York.

    Google Scholar 

  16. X. Yang, N. Kumar, H. Chi, D. B. Hibbert, and P. W. Alexander, Electroanalysis, 1997, 9, 549.

    Article  CAS  Google Scholar 

  17. E. Linder, K. Toth, E. Pungor, F. Behm, P. Oggenfuss, D. H. Ammann, W. E. Morf, E. Pretsch, and W. Simon, Anal. Chem., 1984, 56, 1127

    Article  Google Scholar 

  18. E. Malinowska, Analyst, 1990, 115, 1085.

    Article  CAS  Google Scholar 

  19. S. Kamata and K. Onoyama, Anal. Chem., 1991, 63, 1295

    Article  CAS  Google Scholar 

  20. S. Kamata and K. Onoyama, Chem. Lett., 1991, 653.

    Google Scholar 

  21. A. M. Y. Jabar, G. J. Moody, and J. D. R. Thomas, Analyst, 1988, 133, 1413.

    Google Scholar 

  22. S. R. Sheen and J. S. Shih, Analyst, 1992, 117, 1691

    Article  CAS  Google Scholar 

  23. S. K. Srivastava, V. K. Gupta, and S. Jain, Analyst, 1995, 120, 495.

    Article  CAS  Google Scholar 

  24. H. R. Pouetedal, A. Forghaniha, H. Sharghi, and M. Shamsipur, Anal. Lett., 1998, 31, 2591.

    Article  Google Scholar 

  25. E. Mailinowska, Z. Brózka, K. Kasiura, R. J. M. Egbernik, and D. N. Reinhoudt, Anal. Chim. Acta, 1994, 298, 253

    Article  Google Scholar 

  26. W. Wroblewski, Z. Brózka, R. G. Janssen, W. Verboom, and D. N. Reinhoudt, New J. Chem., 1996, 4, 419.

    Google Scholar 

  27. F. Cadogan, P. Kane, M. A. McKervey, and D. Diamond, Anal. Chem., 1999, 71, 5544.

    Article  CAS  Google Scholar 

  28. M. R. Yaftian, M. Burgard, D. Matt, C. B. Dieleman, and F. Rastegar, Solvent Extr. Ion Exch., 1997, 15, 975

    Article  CAS  Google Scholar 

  29. M. R. Yaftian, M. Burgard, C. B. Dieleman, and D. Matt, J. Membr. Sci., 1998, 144, 57

    Article  CAS  Google Scholar 

  30. M. R. Yaftian, R. Taheri, and D. Matt, Phosphorus, Sulfur Silicon Relat. Elem., 2003, 178, 1225.

    Article  CAS  Google Scholar 

  31. C. B. Dieleman, C. Loeber, D. Matt, A. De Cian, and J. Fischer, J. Chem. Soc., Dalton Trans., 1995, 3097.

    Google Scholar 

  32. M. Shamsipur, M. Yousefi, M. Hosseini, M. R. Ganjali, H. Sharghi, and H. Naeimi, Anal. Chem., 2001, 73, 2869.

    Article  CAS  Google Scholar 

  33. S. Kamata, A. Bhale, S. Fukunaga, and A. Murata, Anal. Chem., 1988, 60, 2464.

    Article  CAS  Google Scholar 

  34. See for example (a) S. Chung, W. Kim, S. B. Park, D. Y. Kim, and S. S. Lee, Talanta, 1997, 44, 1291

    Article  CAS  Google Scholar 

  35. M. Shamsipur, T. Poursaberi, S. Rouhani, K. Niknam, H. Sharghi, and M. R. Ganjali, Anal. Sci., 2001, 17, 1049.

    Article  CAS  Google Scholar 

  36. Y. Umezawa, K. Umezawa, and H. Sato, Pure Appl. Chem., 1995, 67, 507

    Article  Google Scholar 

  37. M. R. Ganjali, L. Naji, T. Poursaberi, M. Shamsipur, and S. Haghgoo, Anal. Chim. Acta, 2003, 475, 59.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Zanjan University, P. O. Box, 45195-313 Zanjan, Iran

    Mohammad Reza Yaftian, Saeed Rayati & Daryoush Emadi

  2. Laboratoire de Chimie Inorganique Moléculaire, Université Louis Pasteur, UMR 7513 CNRS, 1 Rue Blaise Pascal, F-67008 Strasbourg, France

    Dominique Matt

Authors
  1. Mohammad Reza Yaftian
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Saeed Rayati
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Daryoush Emadi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Dominique Matt
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Mohammad Reza Yaftian.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yaftian, M.R., Rayati, S., Emadi, D. et al. A Coated Wire-type Lead(II) Ion-Selective Electrode Based on a Phosphorylated Calix[4]arene Derivative. ANAL. SCI. 22, 1075–1078 (2006). https://doi.org/10.2116/analsci.22.1075

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2116/analsci.22.1075

Search

Navigation