Abstract
Di-n-butyltin dihalides (Bu2SnY2, Y=Cl, I, OMe) behaved as neutral carriers for anion-selective electrodes. A variety of selectivity patterns have been obtained by using Bu2SnY2 which differ in the electronegative substituents Y on the Sn atom. However, all electrodes containing Bu2SnY2 provided the highest degree of selectivity for the SCN- ion. The interaction of Bu2SnY2 with the SCN- ion was studied in the organic solution by means of 13C NMR spectroscopy. In the case of the addition of NaSCN, a significant increase of the value of 1J(119Sn–13Ca) was observed in the 2.0 M CDCl3 solution of Bu2SnCl2.
Similar content being viewed by others
References
M. Nanjo, T. J. Rohm, and G. G. Guilbault, Anal. Chim. Acta, 1975, 77, 19.
S. A. Glazier and M. A. Arnold, Anal. Chem., 1988, 60, 2540.
S. A. Glazier and M. A. Arnold, Anal. Lett., 1989, 22, 1075.
S. A. Glazier and M. A. Arnold, Anal. Chem., 1991, 63, 754.
K. Fluri, J. Koudelka, and W. Simon, Helv. Chim. Acta, 1992, 75, 1012.
S. Koizumi, T. Imato, and N. Ishibashi, Bunseki Kagaku, 1993, 42, 191.
N. A. Chaniotakis, K. Jurkschat, and A. Rühlemann, Anal. Chim. Acta, 1993, 282, 345.
J. K. Tsagatakis, N. A. Chaniotakis, and K. Jurkschat, Helv. Chim. Acta, 1994, 77, 2191.
D. Liu, W. C. Chen, G. L. Shen, and R. Q. Yu, Analyst, 1996, 121, 1495.
S. Koizumi, T. Imato, and N. Ishibashi, Fresenius J. Anal. Chem., 1997, 357, 37.
S. Koizumi, T. Imato, and N. Ishibashi, J. Membrane Sci., 1997, 132, 149.
D. Liu, W. C. Chen, R. H. Yang, G. L. Shen, and R. Q. Yu, Anal. Chim. Acta, 1997, 338, 209.
Z. Q. Li, X. P. Song, G. L. Shen, and R. Q. Yu, Anal. Lett., 1998, 31, 1473.
U. Wuthier, H. V. Pham, R. Znd, D. Welti, R. J. J. Funck, A. Bezegh, D. Ammann, E. Pretsch, and W. Simon, Anal. Chem., 1984, 56, 535.
U. Wuthier, H. V. Pham, E. Pretsch, D. Ammann, A. K. Beck, D. Seebach, and W. Simon, Helv. Chim. Acta, 1985, 68, 1822.
U. Oesch, D. Ammann, H. V. Pham, U. Wuthier, R. Zünd, and W. Simon, J. Chem. Soc. Faraday Trans. 1, 1986, 82, 1179.
U. Wuthier, H. V. Pham, B. Rusterholz, and W. Simon, Helv. Chim. Acta, 1986, 69, 1435.
H. V. Pham, E. Pretsch, K. Fluri, A. Bezegh, and W. Simon, Helv. Chim. Acta, 1990, 73, 1894.
H. J. James, G. P. Carmack, and H. Freiser, Anal. Chem., 1972, 44, 853.
S. Back and J. Sandblom, Anal. Chem., 1973, 45, 1680.
A. Jyo, M. Torikai, and N. Ishibashi, Bull. Chem. Soc. Jpn., 1974, 47, 2862.
N. Yoshida and N. Ishibashi, Chem. Lett., 1974, 493.
D. Wegmann, H. Weiss, D. Ammann, W. E. Morf, E. Pretsch, K. Sugahara, and W. Simon, Mikrochim. Acta, 1984 III, 1.
M. Nádvorník, J. Holecek, K. Handlír, and A. Lycka, J. Organomet. Chem., 1984, 275, 43.
J. Holecek, M. Nádvorník, K. Handlír, and A. Lycka, J. Organomet. Chem., 1986, 315, 299.
J. P. Kerherve and A. Queromes, Fr. Demande, p 8; Chem. Abstr., 1986, 105, 119526C.
D. L. Alleston and A. G. Davies, J. Chem. Soc., 1962, 2050.
J. W. Nicholson, J. A. Douek, and A. J. Crowe, J. Organomet. Chem., 1981, 219, 309.
J. Holecek, K. Handlír, M. Nádvorník, and A. Lycka, J. Organomet. Chem., 1983, 241, 147.
A. Lycka, J. Holecek, M. Nádvorník, and K. Handlír, J. Organomet. Chem., 1985, 280, 323.
U. Edlund, M. Arshadi, and D. Johnels, J. Organomet. Chem., 1993, 456, 57.
T. Kawakami, T. Sugimoto, I. Shibata, A. Baba, H. Matsuda, and N. Sonoda, J. Org. Chem., 1995, 60, 2677.
T. Kawakami, I. Shibata, and A. Baba, J. Org. Chem., 1996, 61, 82.
T. M. Kawakami, H. Matsuda, I. Shibata, M. Miyatake, T. Suwa, and A. Baba, Bull. Chem. Soc. Jpn., 1999, 72, 465: Mitsubishi Chemical Industries Co., Ltd., Chem. Abstr., 1980, 93, 204853k.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Moriuchi-Kawakami, T., Aoto, H., Takeda, N. et al. Anion Selectivities of Dibutyltin Dihalides as Neutral Carriers for Ion-Selective Electrodes. ANAL. SCI. 16, 303–306 (2000). https://doi.org/10.2116/analsci.16.303
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.2116/analsci.16.303