Skip to main content
SpringerLink
Log in

Separation of Pollutant Phenols by Micellar Electrokinetic Chromatography with Double-Chain Surfactants Having Two Sulfonate Groups

  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

The separation of eleven priority (EPA) phenols and eighteen chlorophenols via micellar electrokinetic chromatography (MEKC) is described. Disodium 5,12-bis(dodecyloxymethyl)-4,7,10,13-tetraoxa-1,16-hexadecanedisulfonate (DBTHX), disodium 5,13-bis(dodecyloxymethyl)-4,7,11,14-tetraoxa-1,17-heptadecanedisulfonate (DBTHP) and disodium 5,13-bis(dodecyloxymethyl)-4,7,11,14-tetraoxa-9,9-dimethyl-1,17-heptadecanedisulfonate (DBTDMHP) were used as the double-chain surfactants. The EPA phenols were baseline separated by MEKC with 7.5 mM DBTHP. The detection limits of the phenols for a signal-to-noise ratio of 3 were in the range 0.5×10-2 - 3.0×10-2 mM. The relative standard deviation (RSD) of the capacity factors and peak areas for the phenols over the range of 0.31 - 1.8 mM were 0.21 - 1.4% and 1.9 - 4.3%, respectively. The separations of eighteen chlorophenols together with phenol were also carried out by MEKC with these surfactants. These phenols except for 2,3,5- and 2,4,5-trichlorophenol could each be separated with 10 mM DBTHX.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K. D. Altria, “Capillary Electrophoresis Guidebook”, Humana, Totowa, 1996.

    Google Scholar 

  2. H. Shintani and J. Polonsky, “Handbook of Capillary Electrophoresis Applications”, Blackie Academic and Professional, London, 1997.

    Google Scholar 

  3. L. Renberg and K. Lindstrom, J. Chromatogr., 214, 327 (1981).

    Article  CAS  Google Scholar 

  4. K. Abrahamsson and T. E. Xie, J. Chromatogr., 279, 199 (1983).

    Article  CAS  Google Scholar 

  5. K. Abrahamsson and A. J. Ekdahl, J. Chromatogr., 643, 239 (1993).

    Article  CAS  Google Scholar 

  6. J. F. Cooper, J. Tourte, and P. Gros, Chromatographia, 38, 147 (1994).

    Article  CAS  Google Scholar 

  7. B. Gawdzik, J. Gawdzik and U. Czerwinska-Bil, J. Chromatogr., 509, 135 (1990).

    Article  CAS  Google Scholar 

  8. C. A. Thomson and D. J. Chesny, Anal. Chem., 64, 848 (1992).

    Article  CAS  Google Scholar 

  9. D. Puig and D. Barceó, Chromatographia, 40, 435 (1995).

    Article  CAS  Google Scholar 

  10. C. W. Klampfl and E. Spanos, J. Chromatogr. A, 715, 213 (1995).

    Article  CAS  Google Scholar 

  11. A. L. Crego and M. L. Marina, J. Liq. Chromatogr. Relat. Technol., 20, 1 (1997), and references cited therein.

    Article  CAS  Google Scholar 

  12. A. Zemann and D. Volgger, Anal. Chem., 69, 3243 (1997), and references cited therein.

    Article  CAS  Google Scholar 

  13. M. Tanaka, T. Ishida, T. Araki, A. Masuyama, Y. Nakatsuji, M. Okahara and S. Terabe, J. Chromatogr., 648, 469 (1993).

    Article  CAS  Google Scholar 

  14. H. Harino, M. Tanaka, T. Araki, Y. Yasaka, A. Masuyama, Y. Nakatsuji, I. Ikeda, K. Funazo and S. Terabe, J. Chromatogr. A, 715, 135 (1995).

    Article  CAS  Google Scholar 

  15. H. Harino, Y. Inoue, J. Yoshioka, S. Tsunoi, M. Eguchi, Y. Yasaka, K. Funazo and M. Tanaka, J. Chromatogr. A, 755, 1347 (1996).

    Article  Google Scholar 

  16. Y.-P. Zhu, A. Masuyama, T. Nagata and M. Okahara, J. Jpn. Oil. Chem. Soc. (Yukagaku), 40, 473 (1991).

    Article  CAS  Google Scholar 

  17. K. Otsuka, S. Terabe, and T. Ando, J. Chromatogr., 348, 39 (1985).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Osaka City Institute of Public Health and Environmental Sciences, Tennoji, Osaka, 543-0026, Japan

    Hiroya Harino

  2. Research Center for Environmental Preservation, Osaka University, Yamada-oka, Suita, Osaka, 565-0871, Japan

    Shinji Tsunoi, Junko Yoshioka, Takashi Araki & Minoru Tanaka

  3. Department of Applied Chemistry, Faculty of Engineering, Osaka University, Yamada-oka, Suita, Osaka, 565-0871, Japan

    Araki Masuyama, Yohji Nakatsuji & Isao Ikeda

Authors
  1. Hiroya Harino
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Shinji Tsunoi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Junko Yoshioka
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Takashi Araki
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Araki Masuyama
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Yohji Nakatsuji
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Isao Ikeda
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Minoru Tanaka
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Harino, H., Tsunoi, S., Yoshioka, J. et al. Separation of Pollutant Phenols by Micellar Electrokinetic Chromatography with Double-Chain Surfactants Having Two Sulfonate Groups. ANAL. SCI. 14, 719–724 (1998). https://doi.org/10.2116/analsci.14.719

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2116/analsci.14.719

Keywords

Search

Navigation