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Coating of PANI/SnO2, PANI/ZnO Polymeric Nanocomposite on 304 L Stainless Steel by Galvanostatic Method and Investigation of Corrosion Behavior

  • NANOSCALE AND NANOSTRUCTURED MATERIALS AND COATINGS
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Abstract—In this study, Polyaniline (PANI) and Polianiline/nano metal oxide (SnO2, ZnO (0.1, 0.3 and 0.5 wt %)) are coated on the surface of the steel electrode by galvanostatic method. PANI, PANI/SnO2 and PANI/ZnO coatings were obtained at constant current 50 mA and 1200 s. Characterization of galvanostatically obtained coatings was carried out by FT-IR spectroscopy, XRD and SEM. The effectiveness of PANI, PANI/SnO2 and PANI/ZnO nanocomposite coating in preventing steel corrosion was investigated in 3% NaCl solution using the potentiodynamic polarization technique and electrochemical impedance spectroscopy. The experimental results indicate that as the amount of nanometal oxide (SnO2, ZnO) in the polymer matrix increases, the steel corrosion is reduced.

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REFERENCES

  1. Kapakam, V., Kamaraj, K., Sathiyanarayanan, S., Venkatachari, G., and Ramu, S., Electrochim. Acta, 2011, vol. 56, p. 2165.

    Article  Google Scholar 

  2. Sathiyanarayanan, S., Karpakam, V., Kamaraj, K., Muthukirishnan, S., and Venkatachari, G., Surf. Coat. Technol., 2010, vol. 204, nos. 9–10, p. 1426.

    Article  CAS  Google Scholar 

  3. Ali Fathima Sabirneeza, A. and Subhashini, S., J. Appl. Polym. Sci., 2012, vol. 127, no. 4, p. 3084.

    Article  Google Scholar 

  4. Shabani-Nooshabani, M., Allahyary, E., and Jafari, Y., J. Nanostruct., 2018, vol. 8, no. 2, p. 131.

    Google Scholar 

  5. Deberry, D.W., J. Electrochem. Soc., 1985, vol. 132, p. 1022.

    Article  CAS  Google Scholar 

  6. Dominis, A.J., Spinks, G.M., and Wallace, G.G., Prog. Org. Coat., 2003, vol. 48, p. 43.

    Article  CAS  Google Scholar 

  7. Spinks, G.M., Dominis, A.J., Wallace, G.G., and Tallman, D.E., J. Solid State Electrochem., 2002, vol. 6, no. 2, p. 85.

    Article  CAS  Google Scholar 

  8. Kalendová, A., Veselý, D., and Stejskal, J., Prog. Org. Coat., 2008, vol. 62, no. 1, p. 105.

    Article  Google Scholar 

  9. Riaz, U., Nwaoha, C., and Ashraf, S.M., Prog. Org. Coat., 2014, vol. 77, no. 4, p. 743.

    Article  CAS  Google Scholar 

  10. Popovic, M.M. and Grgur, B.N., Synth. Met., 2004, vol. 143, p. 191.

    Article  CAS  Google Scholar 

  11. Schauer, T., Joos, A., Dulog, L., and Eisenbach, C.D., Prog. Org. Coat., 1998, vol. 33, no. 1, p. 20.

    Article  CAS  Google Scholar 

  12. Lu, W.K., Elsenbaumer, R.L., and Wessling, B., Synth. Met., 1995, vol. 71, p. 2163.

    Article  CAS  Google Scholar 

  13. Ozyilmaz, A.T., Kardas, G., Erbil, M., and Yazici, B., Appl. Surf. Sci., 2005, vol. 242, p. 97.

    Article  Google Scholar 

  14. Pagotto, J.F., Recio, F.J., Motheo, A.D.J., and Herrasti, P., Surf. Coat. Technol., 2016, vol. 289, p. 23.

    Article  CAS  Google Scholar 

  15. Wang, Y., Lim, S., Luo, J.L., and Xu, Z.H., Wear, 2006, vol. 260, p. 976.

    Article  CAS  Google Scholar 

  16. Shi, S., Zhang, Z., and Yu, L., Synth. Met., 2017, vol. 233, p. 94.

    Article  CAS  Google Scholar 

  17. Lei, Y., Qiu, Z., Tan, N., Du, H., Li, D., Liu, J., Liu, T., Zhang, W., and Chang, X., Prog. Org. Coat., 2019, vol. 139, p. 105430. https://doi.org/10.1016/j.porgcoat.2019.105430

    Article  CAS  Google Scholar 

  18. Mobin, M., Aslam, J., and Alam, R., J. Adhes. Sci. Technol., 2017, vol. 31, no. 7, p. 749.

    Article  CAS  Google Scholar 

  19. Zor, S. and Ilmieva, N., Polym. Compos., 2018, vol. 39, no. 4, p. E2415.

    Article  CAS  Google Scholar 

  20. Olad, A. and Rashidzadeh, A., Prog. Org. Coat., 2008, vol. 62, p. 293.

    Article  CAS  Google Scholar 

  21. Mostafaei, A. and Zolriasatein, A., Prog. Nat. Sci.: Mater. Int., 2012, vol. 22, no. 4, p. 273.

    Article  Google Scholar 

  22. Moholkar, A.V., Kim, J.H., and Patıl, V.B., Sens. Transducers J., 2011, vol. 134, no. 11, p. 120.

    Google Scholar 

  23. Olad, A. and Nosrati, R., Res. Chem. Intermed., 2012, vol. 38, p. 323.

    Article  CAS  Google Scholar 

  24. Patil, S.S., Harpale, K.V., Koiry, S.P., Patil, K.R., Aswal, D.K., and More, M.A., J. Appl. Polym. Sci., 2014, vol. 132, no. 5, p. 41401. https://doi.org/10.1002/AP.41401

    Article  Google Scholar 

  25. Pawar, P., Gaikwad, A.B., and Patil, P.P., Electrochim. Acta, 2007, vol. 52, p. 5958.

    Article  CAS  Google Scholar 

  26. Grgur, B.N., Živković, P., and Gvozdenović, M.M., Prog. Org. Coat., 2006, vol. 56, p. 240.

    Article  CAS  Google Scholar 

  27. Torres, V.V., Rayol, V.A., Magalhȃes, M., Viana, G.M., Aguiar, L.C.S., Machado, S.P., Orofino, H., and D’elia, E., Corros. Sci., 2014, vol. 79, p. 108.

    Article  CAS  Google Scholar 

  28. Ateş, S., Baran Aydın, E., and Yazıcı, B., J. Adhes. Sci. Technol., 2021, vol. 35, no. 4, p. 419.

    Article  Google Scholar 

  29. Mansfeld, F., Corrosion, 1981, vol. 37, p. 301.

    Article  CAS  Google Scholar 

  30. Hsu, C.H. and Mansfeld, F., Corrosion, 2001, vol. 57, p. 747.

    Article  CAS  Google Scholar 

  31. Ahamad, I. and Quraishi, M.A., Corros. Sci., 2009, vol. 51, p. 2006.

    Article  CAS  Google Scholar 

  32. Sathianarayanan, S., Azim, S.S., and Venktachari, G., Electrochim. Acta, 2007, vol. 53, p. 2087.

    Article  Google Scholar 

  33. Sambyal, P., Ruhi, G., Bhandari, H., and Dhawan, S.K., Surf. Coat. Technol., 2015, vol. 272, p.129.

    Article  CAS  Google Scholar 

  34. Sathiyanarayanan, S., Karpakam, V., Kamaraj, K., Muthukrishnan, S., and Venkatachari, G., Surf. Coat. Technol., 2010, vol. 204, p. 1426.

    Article  CAS  Google Scholar 

  35. Mostafaei, A. and Nasirpouri, F., Prog. Org. Coat., 2014, vol. 77, p. 146.

    Article  CAS  Google Scholar 

  36. Patil, R.C. and Radhakrishnan, S., Prog. Org. Coat., 2006, vol. 57, p. 332.

    Article  CAS  Google Scholar 

  37. Olad, A. and Nosrati, R., Prog. Org. Coat., 2013, vol. 76, p. 113.

    Article  CAS  Google Scholar 

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Funding

This project was supported by Kocaeli University Scientific Research Projects Unit (BAP) (KOU-BAP project nos. 2016/065 and 2018/076). Thank you for supporting KOU BAP.

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Correspondence to Sibel Demirel.

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Demirel, S., Bozkurt, B. Coating of PANI/SnO2, PANI/ZnO Polymeric Nanocomposite on 304 L Stainless Steel by Galvanostatic Method and Investigation of Corrosion Behavior. Prot Met Phys Chem Surf 58, 53–64 (2022). https://doi.org/10.1134/S207020512201021X

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  • DOI: https://doi.org/10.1134/S207020512201021X

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