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Polyvinylidene Fluoride Copolymers with Grafted Polyethyl Methacrylate Chains: Synthesis and Thermal and Dielectric Properties

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Abstract

Polyvinylidene fluoride copolymers with grafted polyethyl methacrylate chains have been synthesized for the first time via photoinduced reversible deactivation radical polymerization. Binary and ternary copolymers of vinylidene fluoride with chlorotrifluoroethylene and trifluoroethylene were used as initial polymer chains for modification. The effect of the content of grafted chains on the thermal and dielectric properties of the copolymers has been studied. It has been shown that an increase in the content of grafted chains leads to a decrease in the degradation temperature, dielectric permittivity, and dielectric losses of the copolymers, but it significantly improves their film-forming properties due to a decrease in the degree of crystallinity.

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Funding

This work was supported by the Russian Science Foundation, project no. 19-73-30028.

The 1Н NMR study was carried out at the Shared-Use Polymer Research Center within the framework of the State Assignment from the Ministry of Science and Higher Education of Russia (subject FFSM-2021-0005).

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Authors and Affiliations

  1. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, 117393, Moscow, Russia

    E. A. Kleimyuk, A.I. Kosyakova, A. I. Buzin, V. G. Shevchenko, Yu. N. Luponosov & S. A. Ponomarenko

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  1. E. A. Kleimyuk
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  2. A.I. Kosyakova
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  3. A. I. Buzin
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  4. V. G. Shevchenko
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  5. Yu. N. Luponosov
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  6. S. A. Ponomarenko
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Corresponding author

Correspondence to Yu. N. Luponosov.

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Translated by S. Zatonsky

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Kleimyuk, E.A., Kosyakova, A., Buzin, A.I. et al. Polyvinylidene Fluoride Copolymers with Grafted Polyethyl Methacrylate Chains: Synthesis and Thermal and Dielectric Properties. Polym. Sci. Ser. C 64, 200–210 (2022). https://doi.org/10.1134/S1811238222700138

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  • DOI: https://doi.org/10.1134/S1811238222700138

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