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Synthesis and transformations of 1-(azidophenyl)-1H-tetrazoles

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Abstract

Diazotization of 1-(aminophenyl)-1H-tetrazoles and subsequent treatment of the diazonium salts with sodium azide gave 1-(azidophenyl)-1H-tetrazoles which were brought into cyclization with ethyl acetoacetate and cyanoacetanilide to obtain 1,2,3-triazole derivatives. Under these conditions, the tetrazole ring may undergo cleavage with formation of cyanamide group.

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Authors and Affiliations

  1. Ivan Franko Lviv National University, ul. Kirilla i Mefodiya 6, Lviv, 79005, Ukraine

    N. T. Pokhodylo, V. S. Matiichuk & N. D. Obushak

Authors
  1. N. T. Pokhodylo
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  2. V. S. Matiichuk
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  3. N. D. Obushak
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Correspondence to N. D. Obushak.

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Original Russian Text © N.T. Pokhodylo, V.S. Matiichuk, N.D. Obushak, 2010, published in Zhurnal Organicheskoi Khimii, 2010, Vol. 46, No. 4, pp. 565–568.

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Pokhodylo, N.T., Matiichuk, V.S. & Obushak, N.D. Synthesis and transformations of 1-(azidophenyl)-1H-tetrazoles. Russ J Org Chem 46, 556–560 (2010). https://doi.org/10.1134/S1070428010040196

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  • DOI: https://doi.org/10.1134/S1070428010040196

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