Abstract
The study relates to the problem of selecting a solvent for organic polymers during their chemical processing. Based on the method of Askadsky, simple schemes were proposed for calculating the solubility parameter of small molecules and polymeric materials using the structural elements of molecules. On the example of small molecules and polymers it was shown that the constructed methods are not inferior in accuracy to methods of Askadsky, Small, and Van Krevelen. The proposed schemes make it possible to calculate the solubility parameter and find acceptable solvents for a polymer material with a known value of the solubility parameter. The schemes were tested on specific examples and the possibility of their application for the selection of a solvent was demonstrated.
Similar content being viewed by others
REFERENCES
La Mantia, F., Vtorichnaya pererabotka polimerov (Recycling of Polymers), St Petersburg: Professiya, 2006.
Hildebrand, J.H., Prausnitz, J.M., and Scott, R.L., Regular and Related Solutions, New York: Van Nostrand, 1970.
Van Krevelen, D.W., Properties of Polymers. Their Correlation with Chemical Structure. Their Numerical Estimation and Prediction from Additive Group Contributions, Amsterdam: Elsevier, 1997.
Nesterov, A.E., Svoistva rastvorov i smesei polimerov. Spravochnik po fizicheskoi khimii polimerov. T. 1. (Properties of solutions and mixtures of polymers. Handbook of Physical Chemistry of Polymers, vol. 1.), Kiev: Naukova Dumka, 1984.
Askadskii, A.A. and Kondrashchenko, V.I., Komp’yuternoe materialovedenie polimerov (Computer Materials Science of Polymers), vol. 1, Atomno-molekulyarnyi uroven’ (Atomic-molecular level), Moscow: Nauch. Mir, 1999.
Hansen, C.M., Ind. Eng. Chem. Product Res. Develop., 1969, vol. 1, no. 8, pp. 2–11. https://doi.org/10.1021/i360029a002
Askadskii, A.A. and Matveev, Yu.I., Khimicheskoe stroenie i fizicheskie svoistva polimerov (Chemical Structure and Physical Properties of Polymers), Moscow: Khimiya, 1983.
Gyulmaliev, A.M., Golovin, G.S., and Gladun, T.G., Teoreticheskie osnovy khimii uglya (Theoretical Foundations of Coal Chemistry), Moscow: Izd MGGU, 2003.
Gyulmaliev, A.M., Popova, V.P., Romantsova, I.I., and Krichko, A.A., Fuel, 1992, vol. 71, no. 11, pp. 1329–1333. https://doi.org/10.1016/0016-2361(92)90062-S
Kadiev, Kh.M., Gyul’maliev, A.M., and Kubrin, N.A., Petrol. Chem., 2016, vol. 56, no. 9, pp. 807–813. https://doi.org/10.1134/S0965544116090073
Aleshina, A., Glazkova, S.V., Lugovskaya, L.A., Podoinikova, M.V., Fofanov, A.D., and Silina, E.V., Khimiya Past. Syr’ya, 2001, no. 1, pp. 5–36.
Funding
The study was carried out on the basis of the Institute of Petrochemical Synthesis of the Russian Academy of Sciences with a grant from the Russian Science Foundation (project no. 17-73-30046).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest requiring disclosure in this article.
Additional information
Translated from Zhurnal Prikladnoi Khimii, No. 1, pp. 55–63, January, 2021 https://doi.org/10.31857/S0044461821010084
Rights and permissions
About this article
Cite this article
Gyulmaliev, A.M., Zekel’, L.A., Dandaev, A.U. et al. A Simple Method for Estimating the Solubility Parameter of Small Molecules and Polymeric Materials. Russ J Appl Chem 94, 51–59 (2021). https://doi.org/10.1134/S1070427221010080
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427221010080