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2+1 Rhenium Tricarbonyl Complexes with N,N′-Bidentate Ligands and Ethyl Isocyanoacetate: Synthesis, Structure, and Properties

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Abstract

2+1 tricarbonyl complexes [Re(CO)3(N^N)CNCH2COOEt]X, where N^N = 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen) and X = Cl– or ClO4–, were prepared and isolated by two procedures. The intermediate tricarbonyl complexes [Re(CO)3(N^N)X] (where X = Cl– or ClO4–) were also isolated. The composition and molecular structure of these complexes were determined by single crystal X-ray diffraction analysis. The complexes have fac-tricarbonyl structure with bidentate coordination of bipy and phen. The complexes were characterized by PL, IR, UV-Vis, and 1H NMR spectroscopy and by elemental analysis.

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Funding

The study was financially supported by the Russian Foundation for Basic Research (project no. 19-33-90040\19).

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Authors and Affiliations

  1. Khlopin Radium Institute, 194021, St. Petersburg, Russia

    M. Yu. Tyupina & G. V. Sidorenko

  2. St. Petersburg State University, 199034, St. Petersburg, Russia

    M. Yu. Tyupina, A. E. Miroslavov, V. V. Gurzhiy & A. P. Sakhonenkova

  3. St. Petersburg State Pediatric Medical University, 194100, St. Petersburg, Russia

    M. Yu. Tyupina

Authors
  1. M. Yu. Tyupina
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  2. A. E. Miroslavov
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  3. G. V. Sidorenko
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  4. V. V. Gurzhiy
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  5. A. P. Sakhonenkova
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Correspondence to M. Yu. Tyupina.

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Tyupina, M.Y., Miroslavov, A.E., Sidorenko, G.V. et al. 2+1 Rhenium Tricarbonyl Complexes with N,N′-Bidentate Ligands and Ethyl Isocyanoacetate: Synthesis, Structure, and Properties. Russ J Gen Chem 92, 69–78 (2022). https://doi.org/10.1134/S1070363222010108

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  • DOI: https://doi.org/10.1134/S1070363222010108

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