Skip to main content
SpringerLink
Log in

Reaction of N-methyl-N,N-bis(silatranylmethyl)amine with trichlorosilane

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

N,N-Bis(silatranylmethyl)methylamine reacts with trichlorosilane to form the amine hydrochloride and perchloropolysilane, the product of polymerization of dichlorosilylene. In the presence of 1,3-butadiene the main products of the reaction are the amine hydrochloride and 1,1-dichlorosilacyclopentene-3, the product of 1,4-addition of dichlorosilylene to 1,3-butadiene.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Lazareva, N.F., Vakul’skaya, T.I., Albanov, A.I., and Pestunovich, V.A., Appl. Organometal. Chem., 2006, vol. 20, no. 10, p. 696.

    Article  CAS  Google Scholar 

  2. Lazareva, N.F., Brodskaya, E.I., Belyaeva, V.V., and Voronkov, M.G., Russ. J. Gen. Chem., 2000, vol. 70, no. 10, p. 1547.

    CAS  Google Scholar 

  3. Lazareva, N.F., Vakul’skaya, T.I., and Lazarev, I.M., J. Phys. Org. Chem., 2009, vol. 22, no. 2, p. 144.

    Article  CAS  Google Scholar 

  4. Lazareva, N.F., Lazarev, I.M., and Dianova, N.G., Russ. Chem. Bull. Engl. Transl., 2008, no. 10, p. 2235.

  5. Benkeser, R.A., Acc. Chem. Res., 1971, vol. 4, no. 3, p. 94.

    Article  CAS  Google Scholar 

  6. Du Mont, W.-W., Muller, L P., Muller, L., Vollbrecht, S., and Zanin, A.J., J. Organomet. Chem., 1996, vol. 521, nos. 1–2, p. 417.

    Article  Google Scholar 

  7. Benkeser, R.A. and Gad, J.M., J. Am. Chem. Soc., 1970, vol. 92, no. 3, p. 720.

    Article  CAS  Google Scholar 

  8. Benkeser, R.A. and Snyder, D. C., J. Organomet. Chem., 1982, vol. 225, no. 1, p. 107.

    Article  CAS  Google Scholar 

  9. Benkeser, R.A., Foley, K.M., Grutzner, J.B., and Smith, W.E., J. Am. Chem. Soc., 1970, vol. 92, no. 3, p. 697.

    Article  CAS  Google Scholar 

  10. Karsch, H.H., Schluter, P.A., Bienlein, F., Herker, M., Witt, E., Sladek, A., and Heckel, M., Z. Anorg. Allg. Chem., 1998, vol. 624, no. 2, p. 295.

    Article  CAS  Google Scholar 

  11. Karsch, H.H., Bienlein, F., Sladek, A., Heckel, M., and Burgefi, K., J. Am. Chem. Soc., 1995, vol. 117, no. 18, p. 5160.

    Article  CAS  Google Scholar 

  12. Koe, J.R., Powell, D.R., Buffy, J.J., Hayase, S., and West, R., Angew. Chem. Int. Ed., 1998, vol. 37, no. 10, p. 1441.

    Article  CAS  Google Scholar 

  13. Hengge, E. and Kovar, D., Z. Anorg. Allg. Chem., 1979, vol. 458, no. 1, p. 163.

    Article  CAS  Google Scholar 

  14. Koe, J.R., Powell, D.R., Buffy, J.J., and West, R., Polyhedron, 1998, vol. 17, no. 10, p. 1791.

    Article  Google Scholar 

  15. Koe, J.R., Motonaga, M., Fujiki, M., and West, R., Macromolecules, 2001, vol. 34, no. 4, p. 706.

    Article  CAS  Google Scholar 

  16. Kang, S.-H., Han, J.S., Lee, M.E., Yoo, B.R., and Jung, I.N., Organometallics, 2003, vol. 22, no. 13, p. 2551.

    Article  CAS  Google Scholar 

  17. Damrauer, R., Simon, R., Laporterie, A., Manue, l G., Park, Y.T., and Weber, W.P., J. Organomet. Chem., 1990, vol. 391, no. 1, p. 7.

    Article  CAS  Google Scholar 

  18. Gordon, A.J. and Ford, R.A., The Chemist’s Companion. A Handbook of Practical Data, Techniques and References, New York: Wiley, 1972.

    Google Scholar 

  19. Lazareva, N.F., Brodskaya, E.I., Belyaeva, V.V., and Voronkov, M.G., Russ. J. Gen. Chem., 2001, vol. 71, no. 5, p. 815.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    N. F. Lazareva & I. M. Lazarev

Authors
  1. N. F. Lazareva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. M. Lazarev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. F. Lazareva.

Additional information

Original Russian Text © N.F. Lazareva, I.M. Lazarev, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 10, pp. 1653–1655.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lazareva, N.F., Lazarev, I.M. Reaction of N-methyl-N,N-bis(silatranylmethyl)amine with trichlorosilane. Russ J Gen Chem 81, 2106–2108 (2011). https://doi.org/10.1134/S1070363211100112

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363211100112

Keywords

Search

Navigation