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Lanthanide Tris-2-(quinolyl-8-iminomethyl)phenolates: Synthesis and Structures

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Abstract

The reactions of sodium 2-(quinolyl-8-iminomethyl)phenolate with rare-earth element chlorides afford homoleptic mononuclear complexes [Ln{2-(8-quinolyl)N=CH–C6H4O}3] (Ln = La (I), Nd (II), Eu (III), and Tb (IV)) with the nonacoordinated rare-earth element ion. All synthesized complexes are similar in structure, and complexes II, III, and IV are isostructural (CIF files CCDC nos. 2124365 (I), 2124364 (II), 2124366 (III), and 2124367 (IV)). Compounds III and IV exhibit no luminescence, and characteristic luminescence in the near-IR range is observed for complex II.

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ACKNOWLEDGMENTS

XRD studies were carried out using the equipment purchased at the expense of facilities of the Development program of the Moscow State University.

Funding

This work was supported by the Russian Science Foundation, project no. 17-13-01357.

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Authors and Affiliations

  1. Moscow State Pedagogical University, Moscow, Russia

    K. I. Antipova

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

    L. N. Puntus & D. M. Roitershtein

  3. Kotelnikov Institute of Radio Engineering and Electronics, Russian Academy of Sciences (Fryazino Branch), Fryazino, Moscow oblast, Russia

    L. N. Puntus

  4. Moscow State University, Moscow, Russia

    K. A. Lysenko

  5. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia

    D. M. Roitershtein

  6. National Research University Higher School of Economics, Moscow, Russia

    D. M. Roitershtein

Authors
  1. K. I. Antipova
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  2. L. N. Puntus
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  3. K. A. Lysenko
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  4. D. M. Roitershtein
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Corresponding author

Correspondence to D. M. Roitershtein.

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The authors declare that they have no conflicts of interest.

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Translated by E. Yablonskaya

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Antipova, K.I., Puntus, L.N., Lysenko, K.A. et al. Lanthanide Tris-2-(quinolyl-8-iminomethyl)phenolates: Synthesis and Structures. Russ J Coord Chem 48, 379–384 (2022). https://doi.org/10.1134/S107032842206001X

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  • DOI: https://doi.org/10.1134/S107032842206001X

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