Abstract
Co3O4/C composites with microsphere structure were prepared by heat treatment of Co-based metal-organic framework (MOF). The structure and composition of Co3O4/C material were studied by X‑ray diffraction (XRD), scanning electron microscopy (SEM), and other test methods. In the voltage range of 0.01–3.0 V and the current density of 0.05 A g–1, the initial capacity of Co3O4/C calcined at 600°C is 1554.25 mA h g–1. After 60 times of charging and discharging at different current densities, Co3O4/C-600 has excellent rate performance and maintains a specific capacity of 1042 mA h g–1 at a current density of 0.05 A g–1. The good rate performance of Co3O4/C-600 is due to the structure which is dispersed on the carbon substrate and the excellent specific surface area. Therefore, Co3O4/C composite is considered as promising anode material for lithium batteries.
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ACKNOWLEDGMENTS
This work was supported by National International Technology Cooperation Plan (grant no. 2014DFR50570).
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Guan, R., Dong, G., Li, Z. et al. MOF-Derived Co3O4/C Microspheres As High-Performance Anode Materials for Lithium-Ion Batteries. Russ. J. Phys. Chem. 96 (Suppl 1), S175–S182 (2022). https://doi.org/10.1134/S0036024422140114
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DOI: https://doi.org/10.1134/S0036024422140114