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MIL-100(Fe)/Diatomite Composite with Hierarchical Porous Structure for Sorption of Volatile Organic Compounds

  • PHYSICAL CHEMISTRY OF SURFACE PHENOMENA
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Abstract

The synthesis of a composite material with a hierarchical porous structure based on the metal-organic framework MIL-100 and a natural silica material diatomite is proposed in the present study. The structure of the synthesized materials was characterized by a complex of physical-chemical methods (low-temperature sorption of nitrogen, XRD, TG-DSC). The hierarchical porous structure of the composite was confirmed by the low-temperature nitrogen adsorption method. The presence of MIL-100(Fe) and diatomite phases (amorphous silica and quartz) was confirmed by XRD. The composite structure is stable up to 300°C (confirmed by TG-DSC). The sorption properties of the composite were evaluated in the removal of toluene vapor. The MIL-100(Fe)/diatomite composite exhibited the high adsorption capacity for toluene (183 mg/g).

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ACKNOWLEDGMENTS

To Mrs. Evgenia V. Romanova (TSU) for STA studies.

Funding

This work was funded by RFBR and Tomsk region (project number 19-43-700008).

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Authors and Affiliations

  1. Tomsk State University, 634050, Tomsk, Russia

    E. V. Evdokimova, P. A. Matskan & G. V. Mamontov

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  1. E. V. Evdokimova
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  2. P. A. Matskan
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  3. G. V. Mamontov
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Correspondence to E. V. Evdokimova.

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Evdokimova, E.V., Matskan, P.A. & Mamontov, G.V. MIL-100(Fe)/Diatomite Composite with Hierarchical Porous Structure for Sorption of Volatile Organic Compounds. Russ. J. Phys. Chem. 96, 171–178 (2022). https://doi.org/10.1134/S0036024422010083

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  • DOI: https://doi.org/10.1134/S0036024422010083

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