Abstract
The paper presents the results of studies of the self-propagating high temperature synthesis (SHS) of boron nitride via chemical reduction of boron oxide with aluminum in a nitrogen medium. The phase composition of the powder reaction products depending on the nitrogen pressure during the synthesis was studied by X-ray diffraction. It was found that SHS in the B2O3–Al system gives the BN–Al2O3 powder material containing 20–28 wt % hexagonal boron nitride depending on the nitrogen pressure. Microstructure examination showed that the obtained powder materials contains separate hexagonal BN particles with <3 μm size. The differences in the density and morphology of BN and Al2O3 determine the possibility of BN isolation from the obtained powder mixture by the pneumatic powder separation methods.
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REFERENCES
S. N. Perevislov, Novye Ogneupory 6, 35 (2019). https://doi.org/10.1007/s11148-019-00355-5
B. Chen, Q. Bi, J. Yang, et al., Tribol. Int. 41, 1145 (2008). https://doi.org/10.1016/j.triboint.2008.02.014
M. Engler, C. Lesniak, R. Damasch, et al., Ceram. Forum Int. 84, E49 (2007).
J. Eichler and C. Lesniak, J. Eur. Ceram. Soc. 28, 1105 (2008). https://doi.org/10.1016/j.jeurceramsoc.2007.09.005
L. S. Sigl and K. Hunold, Iron Steelmaker 18, 31 (1991).
S. Rudolph, Aluminium Cast House Technology: Seventh Australian Asian Pacific Conference (John Wiley & Sons, 2013).
S. Santosh, K. Rajkumar, and A. Gnanavelbabu, Mater. Sci. Forum. Trans. Tech. Pub. 830–831, 87 (2015). https://doi.org/10.4028/www.scientific.net/MSF.830-831.87
D. Jia, L. Zhou, Z. Yang, et al., J. Am. Ceram. Soc. 94, 3552 (2011). https://doi.org/10.1111/j.1551-2916.2011.04540.x
K. Jia, X. Meng, and W. Wang, Processes 9, 871 (2021). https://doi.org/10.3390/pr9050871
J. Bao, Electron. Mater. Lett. 12, 1 (2016). https://doi.org/10.1007/s13391-015-5308-2
R. Kumar, S. Sahoo, E. Joanni, et al., Nano Res. 12, 2655 (2019). https://doi.org/10.1007/s12274-019-2467-8
T. Liu, Y. Li, J. He, et al., New J. Chem. Royal Soc. Chem. 43, 3280 (2019). https://doi.org/10.1039/C8NJ05299A
Y. Chao, B. Tang, J. Luo, et al., J. Colloid Interface Sci. 584, 154 (2021). https://doi.org/10.1016/j.jcis.2020.09.075
G. Zhao, A. Wang, W. He, et al., Adv. Mater. Interfaces 6, 1900062 (2019). https://doi.org/10.1002/admi.201900062
M. Yoosefian, N. Etminan, MoghaniM. Zeraati, et al., Superlattices Microstruct. 98, 325 (2016). https://doi.org/10.1016/j.spmi.2016.08.049
Y. He, D. Li, W. Gao, et al., Nanoscale 11, 21909 (2019). https://doi.org/10.1039/C9NR07153A
E. Chigo-Anota, A. Escobedo-Morales, H. Hermandez-Cocoletzi, et al., Phys. E: Low Dimens. Syst. Nanostruct. 74, 538 (2015). https://doi.org/10.1016/j.physe.2015.08.008
I. V. Sukhorukova, I. Y. Zhitnyak, A. M. Kovalskii, et al., ACS Appl. Mater. Interfaces 7, 17217 (2015). https://doi.org/10.1021/acsami.5b04101
J. Hu, M. Yue, P. Zhang, et al., Angew. Chem. Int. 59, 6715 (2020). https://doi.org/10.1002/anie.201914819
S. J. Yoon and A. Jha, J. Mater. Sci. 31, 2265 (1996). https://doi.org/10.1007/BF00356318
H. Tagawa and O. Itouji, Bull. Chem. Soc. Jpn. 35, 1536 (1962). https://doi.org/10.1246/bcsj.35.1536
S.-I. Hirano, T. Yogo, S. Asada, et al., J. Am. Ceram. Soc. 72, 66 (1989). https://doi.org/10.1111/j.1151-2916.1989.tb05955.x
G.-Q. Chen, X.-D. He, J.-C. Han, et al., J. Mater. Sci. Lett. 19, 81 (2000). https://doi.org/10.1023/A:1006772320587
R. Haubner, M. Wilhelm, R. Weissengacher, et al., Structure and Bonding (Springer Berlin Heidelberg, Berlin, Heidelberg, 2002). https://doi.org/10.1007/3-540-45623-6_1
O. Gafri, A. Grill, D. Itzhak, et al., Thin Solid Films 72, 523 (1980). https://doi.org/10.1016/0040-6090(80)90542-8
N. S. Evseev, A. E. Matveev, and P. Y. Nikitin, Russ. J. Inorg. Chem. 67, 1319 (2022). https://doi.org/10.1134/S0036023622080095
P. M. Bazhin, A. S. Konstantinov, A. P. Chizhikov, et al., Russ. J. Inorg. Chem. 67, 2040 (2022). https://doi.org/10.1134/S0036023622601696
D. R. Safaeva, Yu. V. Titova, and D. A. Maidan, Sovr. Mater. Tekh. Tekhnol. 5, 70 (2018).
D. R. Safaeva, Yu. V. Titova, and D. A. Maidan, Sovr. Mater. Tekh. Tekhnol. 5, 164 (2019).
I. P. Borovinskaya, T. I. Ignat’eva, V. I. Vershinnikov, et al., Inorg. Mater. 39, 588 (2003).
ACKNOWLEDGMENTS
The phase composition and microstructure of powder materials were studied using the equipment of the Tomsk Regional Center of Collective Use of the National Research Tomsk State University (grant no. 075-15-2021-693 of the Ministry of Science and Higher Education of the Russian Federation (no. 13.TsKP.21.0012)).
Funding
This study was supported by the Program of Development of the Tomsk State University (Prioritet-2030), project no. 2.4.4.22 ONG.
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Tkachev, D.A., Ziatdinov, M.H., Zhukov, I.A. et al. Synthesis of Boron Nitride by Reduction of Boron Oxide with Aluminum in Nitrogen. Russ. J. Inorg. Chem. 68, 1399–1405 (2023). https://doi.org/10.1134/S0036023623700328
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DOI: https://doi.org/10.1134/S0036023623700328