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NaLn(IO3)4 Iodates (Ln = Pr, Tb): New Representatives of Nonlinear Optical Crystals with the NaY(IO3)4 Structure

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Abstract

Interaction of rare-earth oxides (Pr, Tb, Er) with periodic acid or sodium iodate under hydrothermal conditions in the presence of Na2HPO4⋅12H2O leads to formation of complex NaLn(IO3)4 iodates. The compounds of Pr and Tb are reported for the first time. Single-crystal studies reveal that they are isostructural to the previously reported analogs of other rare-earths and adopt the non-centrosymmetric space group Сс. Polycrystalline samples generate a strong SHG signal above that of the potassium dihydrogen phosphate reference standard. They also exhibit wide optical transparency areas and high thermal stability.

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ACKNOWLEDGMENTS

The authors thank T.B. Shatalova and A.F. Murtazoev for the help in conducting the experiments.

Funding

Tis work was financially supported by the Russian Foundation for Basic Research, grant no. 20-03-00702А.

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Authors and Affiliations

  1. Chemistry Department, Moscow State University, 119991, Moscow, Russia

    O. P. Grigorieva, S. Yu. Stefanovich, D. O. Charkin, V. A. Dolgikh & K. A. Lysenko

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  1. O. P. Grigorieva
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  2. S. Yu. Stefanovich
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  3. D. O. Charkin
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  4. V. A. Dolgikh
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  5. K. A. Lysenko
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Correspondence to O. P. Grigorieva.

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Grigorieva, O.P., Stefanovich, S.Y., Charkin, D.O. et al. NaLn(IO3)4 Iodates (Ln = Pr, Tb): New Representatives of Nonlinear Optical Crystals with the NaY(IO3)4 Structure. Russ. J. Inorg. Chem. 68, 1516–1522 (2023). https://doi.org/10.1134/S0036023623601976

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