Skip to main content
SpringerLink
Log in

Coordinatively saturated gadolinium compounds for design of liquid organic scintillators

  • Physical Methods of Investigation
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Coordinatively saturated gadolinium compounds based on gadolinium 3,5,5-trimethylhexanoate Gd(TMHA)3 with additives of trioctylphosphine oxide and free 3,5,5-trimethylhexanoic acid were synthesized and studied to design Gd-containing scintillators for antineutrino detection. The obtained complexes were used for preparing 0.1% solutions of Gd in linear alkylbenzene and optical properties of the solutions were measured.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. F. A. Nezrick and F. Reines, Phys. Rev. 142, 852 (1966).

    Article  CAS  Google Scholar 

  2. Yu. Ya. Markov and O. G. Ryazhskaya, Prib. Tekh. Eksp., No. 4, 50 (1970).

    Google Scholar 

  3. L. B. Bezrukov, R. I. Enikeev, V. B. Korchagin, and O. G. Ryazhskaya, Prib. Tekh. Eksp., No. 3, 66 (1975).

    Google Scholar 

  4. J. S. Park, J. Lee, I. S. Yeo, et al., Nucl. Instrum. Methods Phys. Res., Sect. A 707, 45 (2013).

    Article  CAS  Google Scholar 

  5. C. Aberle, C. Buck, F. X. Hartman, and S. Schonert, Chem. Phys. Lett. 516, 257 (2011).

    Article  CAS  Google Scholar 

  6. C. Aberle, C. Buck, B. F. Gramblich, et al., arXiv: 1112.5941v2 [physics.ins-det] (2012).

  7. Y. Ding, Z. Zhang, J. Liu, et al., Nucl. Instrum. Methods Phys. Res., Sect. A 584, 238 (2008).

    Article  CAS  Google Scholar 

  8. M. Yeh, A. Garnov, and R. L. Hahn, Nucl. Instrum. Methods Phys. Res., Sect. A 578, 329 (2007).

    Article  CAS  Google Scholar 

  9. Yu. V. Klimov, V. I. Kopeikin, A. A. Labzov, et al., Yad. Fiz. 52, 1574 (1990).

    CAS  Google Scholar 

  10. Yu. V. Klimov, V. I. Kopeikin, L. A. Mikaelyan, et al., At. Energ. 76, 130 (1994).

    CAS  Google Scholar 

  11. V. I. Kopeikin, L. A. Mikaelyan, and V. V. Sinev, Yad. Fiz. 64, 914 (2001).

    Google Scholar 

  12. V. I. Kopeikin, L. A. Mikaelyan, and V. V. Sinev, Yad. Fiz. 67, 1916 (2004).

    Google Scholar 

  13. N. A. Danilov, Yu. S. Krylov, A. Yu. Tsivadze, et al., Radiokhimiya 51, 239 (2009).

    Google Scholar 

  14. I. R. Barabanov, L. B. Bezrukov, N. A. Danilov, et al., Preprint No. 1219/2009, IYaI RAN (Institute for Nuclear Research, Russian Academy of Sciences, 2009).

  15. G. Ya. Novikova, I. R. Barabanov, L. B. Bezrukov, et al., Zh. Neorg. Khim. 54, 1143 (2009).

    CAS  Google Scholar 

  16. T. N. Martynova, β-Diketonates of Rare Earth Elements (Synthesis, Structure, and New Approaches to Practical Application) (Irkutsk, 2010) [in Russian].

    Google Scholar 

  17. D. N. Suglobov, G. V. Sidorenko, and E. K. Legin, Volatile Organic Compounds and Complexes of f Elements (Energoatomizdat, Moscow, 1987) [in Russian].

    Google Scholar 

  18. Wen-Tong Chen, Zhi-Gang Luo, Zhong-Liang Yao, Acta Chim. Slov. 59, 949 (2012).

    Google Scholar 

  19. S. B. Meshkova, V. S. Matiichuk, and M. A. Potopnykh, Zh. Neorg. Khim. 56, 995 (2011).

    Google Scholar 

  20. S. I. Gutnikov, E. V. Karpova, M. A. Zakharov, and A. I. Boltalin, Zh. Neorg. Khim. 51, 503 (2006).

    Google Scholar 

  21. O. V. Kotova, S. V. Eliseeva, A. A. Volosnikov, et al., Koord. Khim. 32, 937 (2006).

    Article  Google Scholar 

  22. G. W. Pope, I. F. Steibach, and W. F. Wagner, J. Inorg. Nucl. Chem. 20, 304 (1961).

    Article  CAS  Google Scholar 

  23. P. A. Stabnikov, G. I. Zharkova, A. I. Smolentsev, et al., Zh. Strukt. Khim. 52, 577 (2011).

    Google Scholar 

  24. T. A. Zoan, N. P. Kuzmina, S. N. Frolovskaya, et al., J. Alloys Compd. 225, 396 (1995).

    Article  CAS  Google Scholar 

  25. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, (Interscience, New York, 1986).

    Google Scholar 

  26. I. R. Barabanov, L. B. Bezrukov, N. A. Danilov, et al., Zh. Prikl. Khim. 84, 385 (2011).

    Google Scholar 

  27. G. R. Willey, T. J. Woodman, and M. G. B. Drew, Polyhedron 16, 3385 (1997).

    Article  CAS  Google Scholar 

  28. D. V. Soldatov, K. Suvin’ska, Ya. Lipkovski, A. G. Ogienko, Zh. Strukt. Khim. 40, 964 (1999).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute for Nuclear Research, Russian Academy of Sciences, pr. 60-letiya Oktyabrya 7a, Moscow, 117312, Russia

    G. Ya. Novikova, N. I. Bakulina & V. P. Morgalyuk

Authors
  1. G. Ya. Novikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. I. Bakulina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. P. Morgalyuk
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © G.Ya. Novikova, N.I. Bakulina, V.P. Morgalyuk, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 3, pp. 389–396.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Novikova, G.Y., Bakulina, N.I. & Morgalyuk, V.P. Coordinatively saturated gadolinium compounds for design of liquid organic scintillators. Russ. J. Inorg. Chem. 59, 244–250 (2014). https://doi.org/10.1134/S0036023614030164

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023614030164

Keywords

Search

Navigation