Abstract
A process for fabricating Al-doped β-Ga2O3 thin films of the (AlxGa1−x)2O3 composition by plasma-enhanced chemical vapor deposition has been studied for the first time. High-purity gallium metal, aluminum iodide (AlI3), and high-purity oxygen were used as precursors. Low-temperature plasma at a reduced pressure (0.01 torr) was the initiator of chemical transformations between the reactants. The plasma-enhanced deposition process was studied by optical emission spectroscopy in the range of 180–1100 nm. The obtained thin films of the (AlxGa1−x)2O3 system with the amount of the Al2O3 phase up to 20% were studied by various analytical methods.
Similar content being viewed by others
REFERENCES
Ahmadi, E. and Oshima, Y., J. Appl. Phys., 2019, vol. 126, no. 16, p. 160901.
Peelaers, H., Lyons, J.L., Varley, J.B., and van de Walle, C.G., APL Mater., 2019, vol. 7, no. 2, p. 022519.
Oshima, T., Kato, Y., Kawano, N., Kuramata, A., Yamakoshi, S., Fujita, S., Oishi, T., and Kasu, M., APEX, 2017, vol. 10, no. 3, p. 035701.
Zhang, Y., Neal, A., Xia, Z., Joishi, C., Johnson, J.M., Zheng, Y., Bajaj, S., Brenner, M., Dorsey, D., Chabak, K., Jessen, G., Hwang, J., Mou, S., Heremans, J.P., and Rajan, S., Appl. Phys. Lett., 2018, vol. 112, no. 17, p. 173502.
Olivier, J. and Poirier, R., Surf. Sci., 1981, vol. 105, p. 347.
Ishizawa, N., Miyata, T., Minato, I., Marumo, F., and Iwai, S., Acta Crystallogr., Sect B: Struct. Sci., 1980, vol. 36, p. 228.
Hill, V.G., Roy, R., and Osborn, E.F., J. Am. Ceram. Soc., 1952, vol. 35, p. 135.
Jaromin, A.L. and Edwards, D.D., J. Am. Ceram. Soc., 2005, vol. 88, p. 2573.
Kaun, S.W., Wu, F., and Speck, J.S., J. Vac. Sci. Technol., A, 2015, vol. 33, p. 041508.
Horie, R., Nishinaka, H., Tahara, D., and Yoshimoto, M., J. Alloys Compd., 2021, vol. 851, p. 156927.
Lee, H., Liu, J., and Lee, C., IEEE Photon. Technol. Lett., 2018, vol. 30, p. 549.
Wang, X., Chen, Z., Zhang, F., Saito, K., Tanaka, T., Nishio, M., and Guo, Q., AIP Adv., 2016, vol. 6, p. 015111.
Zhang, F., Saito, K., Tanaka, T., Nishio, M., Arita, M., and Guo, Q., Appl. Phys. Lett., 2014, vol. 105, p. 162107.
Anhar Uddin Bhuiyan, A.F.M., Feng, Z., Johnson, J.M., Huang, H.-L., Sarker, J., Zhu, M., Karim, M.R., Mazumder, B., Hwang, J., and Zhao, H., APL Mater., 2020, vol. 8, p. 031104.
Mochalov, L.A., Logunov, A.A., and Kudryashov, M.A., J. Phys.: Conf. Ser., 2021, vol. 1967, no. 1, p. 012037.
Mochalov, L., Logunov, A., Gogova, D., Letnianchik, A., and Vorotyntsev, V., Opt. Quantum Electron., 2020, vol. 52, p. 510.
Mochalov, L., Logunov, A., Kudryashov, M., Prokhorov, I., Sazanova, T., Yunin, P., Pryakhina, V., Vorotuntsev, I., Malyshev, V., Polyakov, A., and Pearton, S.J., J. Solid State Sci. Technol. 2021, vol. 10, p. 073002.
Logunov, A., Mochalov, L., Gogova, D., and Vorotyntsev, V., 2019 21st International Conference on Transparent Optical Networks (ICTON), Angers, France, pp. 1−4, https://doi.org/10.1109/ICTON.2019.8840331
Mochalov, L., Logunov, A., and Vorotyntsev, V., Sep. Purif. Technol., 2021, vol. 258, p. 118001.
Mochalov, L., Logunov, A., Kitnis, A., Gogova, D., and Vorotyntsev, V., Sep. Purif. Technol., 2020, vol. 238, p. 116446.
Funding
The study was supported by the Russian Science Foundation, project no. 22-13-00053 “Development of scientific foundations for the technology of obtaining chemoresistive materials for electronic nose systems based on complex nanostructured oxide matrices.”
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare no conflict of interest.
Additional information
Translated by S. Zatonsky
Rights and permissions
About this article
Cite this article
Mochalov, L.A., Kudryashov, M.A., Prokhorov, I.O. et al. A Study on the Process of Plasma-Enhanced Chemical Vapor Deposition of (AlxGa1 – x)2O3 Thin Films. High Energy Chem 57, 430–435 (2023). https://doi.org/10.1134/S0018143923050065
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0018143923050065