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Oxidation of 1-methyl-1H-imidazole-2-thiol with chlorine dioxide

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Abstract

Oxidation of 1-methyl-1H-imidazole-2-thiol with chlorine dioxide was performed for the first time, and the results were shown to depend on the oxidation conditions. Optimal conditions were found for the preparation of 1-methylimidazole-2-sulfonic acid, 2,2′-disulfanediylbis(1-methylimidazole) hydrochlorite, and 1-methyl-3-sulfo-3H-imidazolium chloride. A new salt, 4-methylanilinium 1-methyl-1H-imidazole-2-sulfonate, was isolated.

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Authors and Affiliations

  1. Institute of Chemistry, Komi Research Center, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 48, Syktyvkar, 167982, Russia

    O. M. Lezina, S. A. Rubtsova, D. V. Belykh & A. V. Kutchin

  2. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620041, Russia

    P. A. Slepukhin

Authors
  1. O. M. Lezina
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  2. S. A. Rubtsova
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  3. D. V. Belykh
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  4. P. A. Slepukhin
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  5. A. V. Kutchin
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Correspondence to O. M. Lezina.

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Dedicated to Full Member of the Russian Academy of Sciences G.A. Tolstikov on his 80th anniversary

Original Russian Text © O.M. Lezina, S.A. Rubtsova, D.V. Belykh, P.A. Slepukhin, A.V. Kutchin, 2013, published in Zhurnal Organicheskoi Khimii, 2013, Vol. 49, No. 1, pp. 117–123.

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Lezina, O.M., Rubtsova, S.A., Belykh, D.V. et al. Oxidation of 1-methyl-1H-imidazole-2-thiol with chlorine dioxide. Russ J Org Chem 49, 112–118 (2013). https://doi.org/10.1134/S1070428013010193

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  • DOI: https://doi.org/10.1134/S1070428013010193

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