Abstract
Water-soluble carbon quantum dot (CQD) nanoparticles were synthesized using a one-step hydrothermal method, with sucrose and urea selected as carbon precursors. The synthesized CQDs were characterized through SEM, TEM, X-ray diffraction, UV-Vis spectrum, FTIR, and fluorescence spectra analyses. HR-TEM results revealed the microstructure of CQDs as spherical-shaped particles, while XRD plots indicated their amorphous nature. XPS analysis confirmed the successful synthesis of N-doped CQDs. Moreover, this study introduced the reinforcing effect of CQD nanoparticles for the Al composites. The incorporation of CQD particles led to improved hardness properties of the Al–Zn–Mg–Cu composites by using Vickers tester. Additionally, SEM results suggested that CQD particles contributed to a grain fining effect, thereby reducing grain boundary separation.
REFERENCES
Dinç, S., Kara, M., and Yavuz, E., Carbon Dots in Agricultural Systems, Elsevier, 2022, p. 69.
Kaur, R., Singh, J., Kathuria, D., and Matharu, A.S., Sust. Chem. Pharm., 2022, vol. 29, p. 100813. https://doi.org/10.1016/j.scp.2022.100813
Kir, Ş., Dehri, İ., Önal, Y., Esen, R., and Başar, C.A., Surf. Interfaces, 2022, vol. 29, p. 101679. https://doi.org/10.1016/j.surfin.2021.101679
Rohde, L.E., Clausell, N, Pinto Ribeiro, J., Goldraich, L., Netto, R., Dec, G.W., DiSalvo, T.G., and Polanczyk, C.A., Int. J. Cardiol., 2005, vol. 102, p. 71. https://doi.org/10.1016/j.ijcard.2004.04.006
Şen, F.B., Beğiç, N., Bener, M., and Apak, R., Spectrochim. Acta (A), 2022, vol. 271, p. 120884. https://doi.org/10.1016/j.saa.2022.120884
Radnia, F., Mohajeri, N., and Zarghami, N., Talanta, 2020, vol. 209, p. 120547. https://doi.org/10.1016/j.talanta.2019.120547
Polatoğlu, B. and Bozkurt, E., Res. Chem. Intermed., 2021, vol. 47, p. 1865. https://doi.org/10.1007/s11164-021-04404-y
Eskalen, H., Uruş, S., Kavgacı, M., Kalmış, H.V., and Tahta, B., Biomass Conv. Bioref., 2023, p. 1. https://doi.org/10.1007/s13399-023-04048-5
Başkaya, S.K., Tahta, B., Uruş, S., Eskalen, H., Çeşme, M., and Özğan, Ş., Biomass Conv. Bioref., 2022, p. 1. https://doi.org/10.1007/s13399-022-03017-8
Dorbani, T., Bouleklab, M.C., Settar, A., Chetehouna, K., Naoui, Y., Revo, S., and Hamamda, S., J. Mater. Res. Technol., 2022, vol. 19, p. 1484. https://doi.org/10.1016/j.jmrt.2022.05.111
Tiwari, J.K., Mandal, A., Sathish, N., Agrawal, A.K., and Srivastava, A.K., Addit. Manuf., 2020, vol. 33, p. 101095. https://doi.org/10.1016/j.addma.2020.101095
Wang, F., Liu, H., Liu, Z., Guo, Z., and Sun, F., Sci. Rep., 2022, vol. 12, p. 9561. https://doi.org/10.1038/s41598-022-13793-y
Deng, C., Ma, Y., Zhang, P., Zhang, X., and Wang, D., Mater. Lett., 2008, vol. 62, p. 2301. https://doi.org/10.1016/j.matlet.2007.11.086
Abdullahi, U., Maleque, M.A., and Ali, M.Y., Mater. Today Proc., 2021, vol. 46, p. 6097. https://doi.org/10.1016/j.matpr.2020.03.333
Palei, B.B., Dash, T., and Biswal, S.K., J. Mater. Sci., 2022, vol. 57, p. 8544. https://doi.org/10.1007/s10853-022-07043-9
Zhao, W., Bao, R., Yi, J., Tao, J., Guo, S., and Tan, S., Mater. Sci. Eng. (A), 2021, vol. 805, p. 140573. https://doi.org/10.1016/j.msea.2022.143222
Huang, X., Bao, R., and Yi, J.-h., J. Cent. South Univ., 2021, vol. 28, p. 1255. https://doi.org/10.1007/s11771-021-4693-y
Zhao, W.-m., Bao, R., and Yi, J.-h., J. Mater. Sci., 2021, vol. 56, p. 12753. https://doi.org/10.1007/s10853-021-06116-5
Eskalen, H., Çeşme, M., Kerli, S., and Özğan, Ş., J. Chem. Res., 2021, vol 45, p. 428. https://doi.org/10.1177/1747519820953823
Aslan, M. and Eskalen, H., Fuller. Nanotub. Carbon Nanostructures, 2021, vol. 29, p. 1026. https://doi.org/10.1080/1536383X.2021.1926452
Lin, H., Ding, L., Zhang, B., and Huang, J., R. Soc. Open Sci., 2018, vol. 5, p. 172149. https://doi.org/10.1098/rsos.172149
Eskalen, H., Appl. Phys. (A), 2020, vol. 126, p. 708. https://doi.org/10.1007/s00339-020-03906-7
Pandiyan, S., Arumugam, L., Srirengan, S.P., Pitchan, P., Sevugan, S., Kannan, K., Pitchan, G., Hegde, T.A., and Gandhirajan, V., ACS Omega, 2020, vol. 5, p. 30363. https://doi.org/10.1021/acsomega.0c03290
Swapna, M. and Sankararaman, S., Int. J. Mater. Sci., 2017, vol. 12, p. 541. https://doi.org/10.1088/2053-1591/aaa656
Xu, X., Chen, Z., Li, Q., Meng, D., Jiang, H., Zhou, Y., Feng, S., and Yang, Y., Microchem. J., 2021, vol. 160, p. 105708. https://doi.org/10.1016/j.microc.2020.105708
Azizi, Z., Alamdari, A., and Doroodmand, M.M., J. Therm. Anal. Calorim., 2018, vol. 133, p. 951. https://doi.org/10.1007/s10973-018-7293-9
Gedda, G., Lee, C.-Y., Lin, Y.-C., and Wu, H.-f., Sens. Actuators (B), 2016, vol. 224, p. 396. https://doi.org/10.1016/j.snb.2015.09.065
Ma, X., Li, S., Hessel, V., Lin, L., Meskers, S., and Gallucci, F., Chem. Eng. Sci., 2020, vol. 220, p. 115648. https://doi.org/10.1016/j.ces.2020.115648
Asgari, M., Khanahmad, H., Motaghi, H., Farzadniya, A., Mehrgardi, M.A., and Shokrani, P., Appl. Phys. (A), 2021, vol. 127, p. 1. https://doi.org/10.1007/s00339-020-04171-4
Garg, P., Gupta, P., Kumar, D., and Parkash, O., J. Mater. Environ. Sci., 2016, vol. 7, p. 1461. https://doi.org/10.1016/j.jmrt.2019.06.028
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This study was supported by the Scientific Research Projects Coordination Unit of Kahramanmaraş Sütçü İmam University and Gaziantep University (project no. 2023/2-22 A and MF. DT.20.06, respectively).
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Aslan, M., Eskalen, H. & Kavgaci, M. Carbon Quantum Dot (CQD) Nanoparticles Synthesized by Sucrose and Urea: Application as Reinforcement Effect on Al–Mg–Cu–Zn Composite. Russ J Gen Chem 93, 2152–2160 (2023). https://doi.org/10.1134/S1070363223080236
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DOI: https://doi.org/10.1134/S1070363223080236