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Synthesis and Optoelectronic Properties of a Pt(II) Complex with 2-Pyridin-2-Yl-1,3-Thiazole-4-Carboxylic Acid

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Abstract

A carboxyl functionalized Pt(II) complex PtC9H6N2O2SCl2 (I) has been synthesized by the coordination reaction of K2PtCl4 with 2-pyridin-2-yl-1,3-thiazole-4-carboxylic acid. The absorption property and photosensitizing performance of I has been studied. Through assembling the dye-sensitized solar cells (DSSCs) based on complex I, a weak solar-energy-to-electricity conversion is presented. Additionally, when complex I was solved in DMF solution, a novel complex PtC9H7N2O3SCl (II) could be obtained. The structure of II has been confirmed by the single-crystal X-ray diffraction (CIF file CCDC no. 1538911).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou, 571158, P.R. China

    X. P. Zhang, D. S. Zhang, W. Sun & Z. F. Shi

  2. Key Laboratory of Water Pollution Treatment & Resource Reuse of Hainan Province, Haikou, 571158, P.R. China

    X. P. Zhang, D. S. Zhang, W. Sun & Z. F. Shi

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  1. X. P. Zhang
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  2. D. S. Zhang
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  3. W. Sun
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  4. Z. F. Shi
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Correspondence to Z. F. Shi.

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Zhang, X.P., Zhang, D.S., Sun, W. et al. Synthesis and Optoelectronic Properties of a Pt(II) Complex with 2-Pyridin-2-Yl-1,3-Thiazole-4-Carboxylic Acid. Russ J Coord Chem 44, 15–20 (2018). https://doi.org/10.1134/S1070328418010098

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  • DOI: https://doi.org/10.1134/S1070328418010098

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