Skip to main content
SpringerLink
Log in

Using a Stationary Phase Based on Porous Graphitized Carbon for the Determination of 1,1-Dimethylhydrazine Transformation Products by Liquid Chromatography–Mass Spectrometry

  • ARTICLES
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

An approach to the simultaneous determination of five products of the transformation of rocket fuel on the basis of 1,1-dimethylhydrazine (1-methyl-1H-1,2,4-triazole, N-nitrosodimethylamine, N,N-dimethylformamide, and formaldehyde and acetaldehyde dimethylhydrazones) is proposed based on a combination HPLC on porous graphitized carbon (Hypercarb) with mass spectrometry and tandem mass spectrometry detection. The limits of detection are 0.6–7 µg/L. It was found that the stationary phase based on porous graphitized carbon ensures the effective chromatographic retention and separation of nitrogen-containing products 1,1-dimethylhydrazine transformation products by a mixed mechanism, including both hydrophobic and induction interactions with the analytes. The absence of matrix effects in the analysis of natural waters and a methanol extract from peat bog soil was shown.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Rodin, I.A., Moskvin, D.N., Smolenkov, A.D., and Shpigun, O.A., Russ. J. Phys. Chem. A, 2008, vol. 82, no. 6, p. 911.

    Article  CAS  Google Scholar 

  2. Ul’yanovskii, N.V., Kosyakov, D.S., Pikovskoi, I.I., and Khabarov, Yu.G., Chemosphere, 2017, vol. 174, p. 66.

    Article  Google Scholar 

  3. Kenessov, B., Alimzhanova, M., Sailaukhanuly, Y., Baimatova, N., Abilev, M., Batyrbekova, S., Carlsen, L., Tulegenov, A., and Nauryzbayev, M., Sci. Total Environ., 2012, vol. 427-428, p. 78.

    Article  CAS  Google Scholar 

  4. Bakaikina, N.V., Kenessov, B.N., Ul’yanovskii, N.V., and Kosyakov, D.S., Talanta, 2018, vol. 184, p. 332.

    Article  CAS  Google Scholar 

  5. Rodin, I.A., Anan’eva, I.A., Smolenkov, A.D., and Shpigun, O.A., J. Anal. Chem. 2010, vol. 65, no. 13, p. 1405.

    Article  CAS  Google Scholar 

  6. Kosyakov, D.S., Ul’yanovskii, N.V., Bogolitsyn, K.G., and Shpigun, O.A., Int. J. Environ. Anal. Chem., 2014, vol. 94, no. 12, p. 1254.

    Article  CAS  Google Scholar 

  7. Smirnov, R.S., Rodin, I.A., Smolenkov, A.D., and Shpigun, O.A., J. Anal. Chem., 2010, vol. 65, no. 12, p. 1266.

    Article  CAS  Google Scholar 

  8. Kosyakov, D.S., Ul’yanovskii, N.V., Pokryshkin, S.A., Lakhmanov, D.E., and Shpigun, O.A., Int. J. Environ. Anal. Chem., 2015, vol. 95, no. 14, p. 1321.

    Article  CAS  Google Scholar 

  9. Bakaikina, N.V., Kenessov, B., Ul’yanovskii, N.V., Kosyakov, D.S., Pokryshkin, S.A., Derbissalin, M., and Zhubatov, Z.K., Chromatographia, 2017, vol. 80, no. 6, p. 931.

    Article  CAS  Google Scholar 

  10. Zhubatov, Z.K., Kenessov, B., Bakaikina, N.V., Bimaganbetova, A.O., Akynbayev, N., and Bakhytkyzy, I., Chromatographia, 2016, vol. 79, nos. 7–8, p. 491.

    Article  CAS  Google Scholar 

  11. Ul’yanovskii, N.V., Kosyakov, D.S., Pikovskoi, I.I., Shavrina, I.S., and Shpigun, O.A., Chromatographia, 2018, vol. 81, no. 6, p. 891.

    Article  Google Scholar 

  12. Ripollés, C., Pitarch, E., Sancho, J.V., López, F.J., and Hernández, F., Anal. Chim. Acta, 2011, vol. 702, no. 1, p. 62.

    Article  Google Scholar 

  13. Plumlee, M.H., López-Mesasa, M., Heidlberger, A., Ishida, K.P., and Reinhard, M., Water Res., 2008, vol. 42, nos. 1–2, p. 347.

    Article  CAS  Google Scholar 

  14. Smolenkov, A.D., Krechetov, P.P., Pirogov, A.V., Koroleva, T.V., Bendryshev, A.A., Shpigun, O.A., and Martynova, M.M., Int. J. Environ. Anal. Chem., 2005, vol. 85, no. 14, p. 1089.

    Article  CAS  Google Scholar 

  15. Smolenkov, A.D., Rodin, I.A., Smirnov, R.S., Tataurova, O.G., and Shpigun, O.A., Moscow Univ. Chem. Bull. (Engl. Transl.), 2012, vol. 67, no. 5, p. 229.)

  16. West, C., Elfakir, C., and Lafosse, M., J. Chromatogr. A, 2010, vol. 1217, no. 19, p. 3201.

    Article  CAS  Google Scholar 

  17. Knox, J.H. and Kaur, B., J. Chromatogr. A, 1986, vol. 352, p. 3.

    Article  CAS  Google Scholar 

  18. Polyakova, Y.L. and Row, K.H., Chromatographia, 2007, vol. 65, nos. 1–2, p. 59.

    Article  CAS  Google Scholar 

  19. Polyakova, Y.L. and Row, K.H., J. Liq. Chromatogr. Relat. Technol., 2005, vol. 28, no. 20, p. 3157.

    Article  CAS  Google Scholar 

  20. Ngongang, A.D., Duy, S.V., and Sauvé, S., Anal. Methods, 2015, vol. 7, no. 14, p. 5748.

    Article  CAS  Google Scholar 

  21. Class, J.B., Aston, J.G., and Oakwood, T.S., J. Am. Chem. Soc., 1953, vol. 75, no. 12, p. 2937.

    Article  CAS  Google Scholar 

  22. Catalán, J., Díaz, C., and García-Blanco, F., Org. Biomol. Chem., 2003, vol. 1, no. 3, p. 575.

    Article  Google Scholar 

  23. Bapiro, T.E., Richards, F.M., and Jodrell, D.I., Anal. Chem., 2016, vol. 88, no. 12, p. 6190.

    Article  CAS  Google Scholar 

  24. Lepont, C., Gunatillaka, A.D., and Poole, C.F., Analyst, 2001, vol. 126, p. 1318.

    Article  CAS  Google Scholar 

  25. Kalia, J. and Raines, R.T., Angew. Chem., Int. Ed. Engl., 2008, vol. 47, p. 7523.

    Article  CAS  Google Scholar 

  26. Zhang, S., J. Comput. Chem., 2012, vol. 33, no. 31, p. 2469.

    Article  CAS  Google Scholar 

  27. Ul’yanovskii, N.V., Kosyakov, D.S., Pokryshkin, S.A., and Bogolitsyn, K.G., J. Anal. Chem. 2015, vol. 70, no. 13, p. 1553.

    Article  Google Scholar 

  28. GOST (State Standard) R 52985-2008: Ecological Safety of Rocket-Space Technique. General Technical Requirement, Moscow: Standartinform, 2008.

  29. Zhubatov, Zh., Kenesov, B.N., Tovasarov, A.D., Kozlovskii, V.A., and Batyrbekova, S.E., Sistema ekologicheskogo normirovaniya raketno-kosmicheskoi deyatel’nosti kosmodroma Baikonur (The System of Environmental Regulation of Rocket and Space Activities of the Baikonur Cosmodrome), Nauryzbaev, M.K., Ed., Almaty, 2017.

    Google Scholar 

Download references

ACKNOWLEDGMENTS

This work was performed using instrumentation of the “Arktika” Core Facility Center of the Northern (Arctic) Federal University.

Funding

This work was supported by the Russian Science Foundation, project no. 17-13-01112.

Author information

Authors and Affiliations

  1. Core Facility Center “Arktika,” M.V. Lomonosov Northern (Arctic) Federal University, 163002, Arkhangelsk, Russia

    N. V. Ul’yanovskii, D. S. Kosyakov, M. S. Popov, I. I. Pikovskoi & O. Yu. Khoroshev

Authors
  1. N. V. Ul’yanovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. S. Kosyakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. S. Popov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. I. Pikovskoi
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. O. Yu. Khoroshev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. V. Ul’yanovskii.

Additional information

Translated by E. Rykova

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ul’yanovskii, N.V., Kosyakov, D.S., Popov, M.S. et al. Using a Stationary Phase Based on Porous Graphitized Carbon for the Determination of 1,1-Dimethylhydrazine Transformation Products by Liquid Chromatography–Mass Spectrometry. J Anal Chem 75, 510–518 (2020). https://doi.org/10.1134/S1061934820040140

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934820040140

Keywords:

Search

Navigation