Abstract
The desorption of rhenium from an A172 anion exchanger with an ammonia solution has been studied. A172 and A170 anion exchangers have been investigated with infrared spectroscopy. The difference in their structures has been revealed so that A172 can be assigned to a medium basic anion exchanger type. The reason for the low desorption of rhenium from the A172 anion exchanger has been determined.
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References
Ionity v tsvetnoi metallurgii (Ion Exchangers in Non-Ferrous Metallurgy), Lebedev, K.B., Ed., Moscow: Metallurgiya, 1975.
Abisheva, Z.S. and Zagorodnyaya, A.N., Contribution from the Institute of Metallurgy and Enrichment to the organization of the production of rhenium and osmium-187 compounds in Kazakhstan, Vestn. Mosk. Inst. Tonkoi Khim. Tekhnol., 2013, vol. 8, no. 3, pp. 34–48.
Zagorodnyaya, A.N., Abisheva, Z.S., Ponomareva, E.I., and Bobrova, V.V., Integrated sorption–solvent extraction–electrodialysis technology for the production of ammonium perrhenate from uranium-containing solutions, Tsvetn. Met., 2010, no. 8, pp. 59–62.
Volkov, V.P., Meshcheryakov, N.M., Nikitin, N.V., and Mikhailenko, M.A., Industrial experience of sorption recovery of rhenium from circulating solutions used in the in situ leaching of uranium, Tsvetn. Met., 2012, no. 7, pp. 64–66.
Blokhin, A.A., Amosov, A.A., Murashkin, Yu.V., Evdoshenko, S.A., Mikhailenko, M.A., and Nikitin, N.V., Sorption of rhenium(VII) on gel and macroporous anion exchangers of different basicities from solutions of mineral acids and their ammonium salts, Russ. J. Appl. Chem., 2005, vol. 78, no. 9, pp. 1411–1415.
Blokhin, A.A., Amosov, A.A., and Murashkin, Yu.V., Assessing the possibility of sorption recovery of rhenium from washing sulfuric acid used in wet purification in copper and nickel production, Tsvetn. Met., 2006, no. 8, pp. 94–98.
Abisheva, Z.S., Zagorodnyaya, A.N., Bekturganov, N.S., Ospanov, E.A., and Ospanov, N.A., Rhenium sorption on A170 anion exchanger from industrial solutions of washing sulfuric acid of the Balkhash copper-smelting plant, Tsvetn. Met., 2012, no. 7, pp. 57–61.
Sung-Ho, Joo., Young-Uk, Kim., and Jin-Gu, Kang., Recovery of rhenium and molybdenum from molybdenite roasting dust leaching solution by ion exchange resins, Mater. Trans., 2012, vol. 53, no. 11, pp. 2034–2037.
Abisheva, Z.S., Zagorodnyaya, A.N., Sadykanova, S.E., Bobrova, V.V., and Sharipova, A.S., Sorption technology of rhenium recovery from uranium-containing solutions with the use of weakly basic anion exchangers, Kompleks. Ispol. Miner. Syr’ya, 2011, no. 3, pp. 8–16.
Sadykanova, S.E., Zagor odnyaya, A.N., Abisheva, Z.S., and Sharipova, A.S., Rhenium desorption with aqueous ammonia from A170 weakly basic anion exchanger, Kompleks. Ispol. Miner. Syr’ya, 2013, no. 3, pp. 9–14.
Mal’tseva, E.E., Blokhin, A.A., and Murashkin, Yu.V., Kinetics of rhenium sorption from weakly basic macroporous and gel anion exchangers Purolite A170 and Purolite A 172 from sulfuric acid solutions, Russ. J. Appl. Chem., 2012, vol. 85, no. 7, pp. 1029–1033.
Blokhin, A.A., Mal’tseva, E.E, Murashkin, Yu.V., and Mikhailenko, M.A., RF Patent 2427535, 2011.
GOST (State Standard) 10897–64: Ionites. Methods of Preparation to Testing, 1964.
Zagorodnyaya, A.N., Abisheva, Z.S., Bobrova, V.V., Sharipova, A.S., and Sydykanova, S.E., Assessing the applicability of A172 anion exchanger to selective recovery of rhenium from uranium-containing solutions, Kompleks. Ispol. Miner. Syr’ya, 2012, no. 2, pp. 35–45.
Zakhar’yan, S.V. and Gedgagov, E.I., Anion exchange separation of rhenium and selenium in ammonium perrhenate production systems, Khim. Tekhnol., 2012, no. 7, pp. 420–428.
Kazitsyna, L.A. and Kupletskaya, N.B., Primenenie UF-, IK-i YaMR-spektroskopii v organicheskoi khimii (Application of UV,IR, and NMR spectroscopy in Organic Chemistry), Moscow: Vysshaya Shkola, 1971.
Ionoobmennye materialy dlya protsessov gidrometallurgii, ochistki stochnykh vod i vodopodgotovki: Spravochnik (Ion-exchange Materials for Hydrometallurgy, Wastewater Treatment and Water Conditioning: A Handbook), Moscow: VNIIKhT, 1983.
Sil’verstein, R., Bassler, G., and Morril, T., Spectrometric Identification of Organic Compounds, New York: Wiley, 1991.
Laskorin, B.N., Fedorova, L.A., and Stupin, N.P., Structural distribution of functional groups in polystyrene-based anion exchangers, Zh. Fiz. Khim., 1973, vol. 47, no. 4, pp. 964–966.
Kiseleva, E.I., Chmutov, K.V., Khasanova, V.M., and Markova, Z.A., Radiation stability of AN-25 and AN-25A anion exchangers, Zh. Fiz. Khim., 1971, vol. 45, no. 4, pp. 897–907.
Stupin, N.P., Kharina, T.P., and Baskakov, A.N., Structuring in the copolymerization of 3-methyl-5-vinylpyridine and p-divinylbenzene, Plast. Massy, 1981, no. 7, p. 57.
Dechant, J., Danz, R., Kimmer, W., and Schmolke, R., Ultrarotspektroskopische Untersuchungen an Polymeren, Berlin: Akademie, 1972.
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Original Russian Text © A.N. Zagorodnyaya, Z.S. Abisheva, L.U. Amanzholova, S.E. Sadykanova, A.S. Sharipova, 2015, published in Khimicheskaya Tekhnologiya, 2015, Vol. 16, No. 12, pp. 739–745.
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Zagorodnyaya, A.N., Abisheva, Z.S., Amanzholova, L.U. et al. Desorption of rhenium from weakly basic anion exchangers. Theor Found Chem Eng 50, 872–877 (2016). https://doi.org/10.1134/S0040579516050262
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DOI: https://doi.org/10.1134/S0040579516050262