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Syntheses, Crystal Structures, and Properties of Two Dysprosium Coordination Compounds Based on Na2H2L Ligands

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Abstract

Two coordination compounds, Dy2(H2L)3(phen)2·2(phen) (I) and [Dy(L)(H2O)2·Hbipy]n (II) (Na2H2L is 4,5-dihydroxy-1,3-benzenedisulfonic acid disodium; phen is 1,10-phenanthroline; bipy is 2,2'-bipyridine), were hydrothermally synthesized. They have been characterized by single crystal X-ray diffraction and elemental analyses. In compound I, introduction of the auxiliary chelating ligand phen led to a new Dy phenol-sulfonate with dinuclear structure bridging by the three H2L2– ligands. The interconnection of the dinuclear compounds via the π–π stacking interactions between phen molecules resulted in a one dimensional chain structure. Compound II features a novel one-dimensional chain in which Dy atoms are bridged by the phenol-sulfonate ligands in pentadentate fashion. Dy atom is eight-coordinated by one sulfonate group bidentately, one phenol group unidentately and two phenol groups from one L4– ligand. Compounds I and II exhibit photoluminescence with emissions maximum at 408 and 438 nm, which can be attributed to the intraligand emission state, furthermore, they also display the characteristic emissions of Dy ions, correspond to 4F5/2–6H15/2, 4F5/2–6H13/2 and 4F5/2–6H11/2 transitions, respectively.

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Funding

This work was supported by the Scientific Research Fund Project of Liaoning Provincial Education Department no. LJKZ0371.

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Authors and Affiliations

  1. School of Petrochemical Engineering, Liaoning Petrochemical University, 113001, Fushun, China

    Pengpeng Yin, Lei Guan, Ying Wang, Xian Chen, Hongzhe Jin & Xuejia Xiong

  2. School of Innovation and Entrepreneurship, Liaoning Petrochemical University, 113001, Fushun, China

    Chunlei Xue & Yudi Yan

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  1. Pengpeng Yin
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  2. Chunlei Xue
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  3. Yudi Yan
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Correspondence to Ying Wang.

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Yin, P., Xue, C., Yan, Y. et al. Syntheses, Crystal Structures, and Properties of Two Dysprosium Coordination Compounds Based on Na2H2L Ligands. Russ. J. Inorg. Chem. 67, 456–463 (2022). https://doi.org/10.1134/S0036023622040222

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  • DOI: https://doi.org/10.1134/S0036023622040222

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