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CRYSTAL STRUCTURE OF SULFINAMIDES OF THE THIAZINE SERIES: FEATURES OF TRANSFERRING THE OPEN-CHAIN SUPRAMOLECULAR SYNTHON FROM THE RACEMIC TO HOMOCHIRAL ENVIRONMENT

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Abstract

The crystal structures of four representatives of sulfinamides of the thiazine series are comparatively analyzed for the occurrence of different supramolecular associates, inter- and intramolecular interactions. With a similar molecular geometry, different packing motifs occur in the crystals yielding different-type supramolecular associates due to classical N–H⋯O hydrogen bonds. The features of transferring the sulfinamide open-chain supramolecular synthon from racemic to homochiral environment consisting in the appearance of “secondary cross-linking” are studied.

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Funding

The work was supported by RSF grant 17-13-01209. The synthetic part of the work was supported by the State Competitiveness Program for the Kazan Federal University.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia

    D. P. Gerasimova & O. A. Lodochnikova

  2. Butlerov Institute of Chemistry, Kazan (Volga Region) Federal University, Kazan, Russia

    D. P. Gerasimova, V. V. Plemenkov & O. A. Lodochnikova

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  1. D. P. Gerasimova
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  2. V. V. Plemenkov
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  3. O. A. Lodochnikova
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Correspondence to D. P. Gerasimova.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 6, pp. 1043-1052.https://doi.org/10.26902/JSC_id74451

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Gerasimova, D.P., Plemenkov, V.V. & Lodochnikova, O.A. CRYSTAL STRUCTURE OF SULFINAMIDES OF THE THIAZINE SERIES: FEATURES OF TRANSFERRING THE OPEN-CHAIN SUPRAMOLECULAR SYNTHON FROM THE RACEMIC TO HOMOCHIRAL ENVIRONMENT. J Struct Chem 62, 974–983 (2021). https://doi.org/10.1134/S0022476621060172

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