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Production of intermetallic compound of FeTi by means of mechanical-chemical synthesis and its interaction with hydrogen

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Inorganic Materials: Applied Research Aims and scope

Abstract

A technique for producing the intermetallic compound FeTi by treatment of Ti-50 at % Fe powder mixtures in a high-energy ball planetary mill in argon atmosphere is demonstrated. The forming compound is in the nanocrystalline state with the size of coherent scattering areas (CSA) of 10–20 nm. A method of sample compaction from powder obtained by mechanical and chemical synthesis is proposed. It combines mechanical strength with initial phase composition and material microstructure. It is determined that, after high-temperature activation, the synthesized compound FeTi reversibly absorbs up to 0.6 wt % of hydrogen at room temperature.

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References

  1. Skakov, Yu.A., High-Energy Cold Plastic Deformation, Diffusion and Mechanical-Chemical Synthesis, MiTOM, 2004, no. 4, pp. 3–12.

  2. Skakov, Yu.A., Generation and Stability of Metastable Phases under Mechanochemical Synthesis, MiTOM, 2005, no. 7, pp. 45–54.

  3. Zadorozhnyi, V.Yu., Milovzorov, G.S., and Skakov, Yu.A., Generation of Metastable States in Fe-Ti and Ni-Ti Systems during Mechanochemical Synthesis, MiTOM, 2008, no. 8, pp. 46–52.

  4. Schlapbach, L. and Zuttel, A., Hydrogen-Storage Alloys from a Gas Reactor Point of View, Nature, 2001, vol. 414, pp. 353–358.

    Article  CAS  Google Scholar 

  5. Sandrock, G., A Panoramic Overview of Hydrogen Storage Alloys from a Gas Reaction Point of View, J. Alloys and Compounds, 1997, vols. 253–254, pp. 877–888.

    Google Scholar 

  6. Kolachev, B.A., Shalin, R.E., and Il’in, A.A., Splavy — nakopiteli vodoroda. Spravochnik (Alloys — Hydrogen Accumulators. Handbook), Moscow: Metallurgiya, 1995.

    Google Scholar 

  7. Zaluski, L., Zaluska, A., Strom-Oisen, J.O., Nanocrystalline Metal Hydrides, J. Alloys and Compounds, 1997, vols. 253–254, pp. 70–79.

    Article  Google Scholar 

  8. Novikova, A.A., Ogladze, O.V., Tarasov, B.P., Sveshnikov, S.V., and Likhushina, E.V., Generation of Surfeited Solid Solutions and Metastable Phases in the Fe-Ti System at Different Stages of Mechanical Alloying, Vestnik Moskovskogo Universiteta. Ser. 3. Fiz. Astron., 1998, no. 1, pp. 37–40.

  9. Yagodkin, Yu.D. and Dobatkin, S.V., Electron Microscopy and X-Ray Structural Analysis to Determine the Size of Structural Elements in Nanocrystal Materials (Review), Zavodskaya laboratoriya. Diagnostika materialov, 2007, vol. 73, no. 1, pp. 38–49.

    CAS  Google Scholar 

  10. Shelekhov, E.V. and Sviridova, T.A., Simulation of Balls Motion and Heating in Planetary-Type Mill. The Effect of Processing Modes onto Mechanical Activation Products of Ni and Nb Powders Mixture, Materialovedenie, 1999, no. 10, pp. 13–22.

  11. Pustov, L.Yu., Kaloshkin, S.D., Tcherdyntsev, V.V., et al., J. Metastable and Nanocrystalline Mater., 2000, vol. 10, p. 373.

    Article  Google Scholar 

  12. Shelehov, E.V., Tcherdyntsev, V.V., Pustov, L.Yu., et al., J. Metastable Nanocrystalline Mater., 2000, vol. 8, p. 603.

    Article  Google Scholar 

  13. Klyamkin, S.N., Burnasheva, V.V., and Semenenko, K.N., Features of Interaction in Hf2Fe-H2 System Being under Low Temperatures and High Pressures, Izv. Akad. Nauk, Ser. Khim., 1997, no. 1, pp. 33–36.

  14. Tikhomirov, A.V., Aksenov, A.A., Shelekhov, E.V., et al., Calculation and Measuring of Background Temperature of Mechanical Alloying in Planetary-Type Mill with Ball Loading and Quasicylindrical Milling Body, Izv. Vyssh. Uchebn. Zaved., Tsv. Metallurgiya, 2008, no. 3, pp. 52–57.

  15. Sun, L., Liu, H., Bradhurst, D.H., and Dou, S., Formation of FeTi Hydrogen Storage Alloys by Ball-Milling, J. Mater. Sci. Lett., 1998, vol. 17, pp. 1825–1830.

    Article  CAS  Google Scholar 

  16. Zadorozhnyi, V.Yu., Milovzorov, G.S., and Skakov, Yu.A., RF Patent no. 2007138675, 2007.

  17. Reilly, J.J. and Wiswall, R.H., Inorg. Chem., 1974, vol. 13, p. 218.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Moscow Institute of Steel and Alloys (MISA), Moscow, Russia

    V. Yu. Zadorozhnyy, S. N. Klyamkin, S. D. Kaloshkin & Yu. A. Skakov

  2. Moscow State University, Moscow, Russia

    V. Yu. Zadorozhnyy, S. N. Klyamkin, S. D. Kaloshkin & Yu. A. Skakov

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  1. V. Yu. Zadorozhnyy
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  2. S. N. Klyamkin
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  3. S. D. Kaloshkin
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  4. Yu. A. Skakov
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Original Russian Text © V.Yu. Zadorozhnyy, S.N. Klyamkin, S.D. Kaloshkin, Yu.A. Skakov, 2009, published in Materialovedenie, 2009, No. 6, pp. 41–45.

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Zadorozhnyy, V.Y., Klyamkin, S.N., Kaloshkin, S.D. et al. Production of intermetallic compound of FeTi by means of mechanical-chemical synthesis and its interaction with hydrogen. Inorg. Mater. Appl. Res. 1, 41–45 (2010). https://doi.org/10.1134/S2075113310010065

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  • DOI: https://doi.org/10.1134/S2075113310010065

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