Abstract
It is shown that the amphiphilic diblock copolymers poly(N-vinylpyrrolidone-2,2,3,3-tetrafluoropropyl methacrylate) can be prepared through the reaction of chain transfer to bis(pentafluorophenyl)germane during the polymerization of N-vinylpyrrolidone and the subsequent postpolymerization of isolated functional polymers in 2,2,3,3-tetrafluoropropyl methacrylate. The dilute-solution behavior and self-organizing ability of functional polymers based on poly(N-vinylpyrrolidone) containing end bis(pentafluorophenyl) groups and of amphiphilic diblock copolymers formed on their basis are studied via the methods of static and dynamic light scattering and viscometry. Surface properties at the interface of the films are estimated through the wetting technique.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
V. Percec, G. Johansson, and J. Zhou, J. Am. Chem. Soc. 118, 9855 (1996).
N. A. Hadjiantoniou and C. S. Patrickios, Polymer 48, 7041 (2007).
G. Erdodi and J. P. Kennedy, Prog. Polym. Sci. 31, 1 (2006).
C. Guerrero-Sanchez, D. Wouters, C. A. Fustin, et al., Macromolecules 38, 10185 (2005).
Modern Fluoropolymers, Ed. by J. Scheirs (Wiley, New York, 1997).
Block Copolymers in Nanoscience, Ed. by M. Lazzari, G. Liu, and S. Lecommandoux (Wiley-VCH, Weinheim, 2006).
A. Weissberger, E. Proskauer, J. Riddick, and E. Toops, Organic Solvents. Physical Properties and Methods of Purification (Wiley, New York, 1955; Inostrannaya Literatura, Moscow, 1958).
F. R. Mayo, J. Am. Chem. Soc. 65, 2324 (1943).
V. A. Balandina, D. B. Gurvich, M. S. Kleshcheva, et al., Analysis of Polymerization Plastics (Khimiya, Moscow, 1965) [in Russian].
O. G. Zakharova, Yu. V. Golyagina, and Yu. D. Semchikov, Zh. Prikl. Khim. (S.-Peterburg) 82, 649 (2009).
V. E. Eskin, Light Scattering from Polymer Solutions (Nauka, Leningrad, 1986) [in Russian].
V. P. Pugachevich, E. M. Beglyarov, and I. A. Lavygin, Surface Phenomena in Polymers (Khimiya, Moscow, 1982) [in Russian].
Yu. S. Lipatov, A. E. Nesterov, T. M. Gritsenko, and R. A. Veselovskii, Handbook of Polymer Chemistry (Naukova Dumka, Kiev, 1971) [in Russian].
E. B. Zhulina, M. Adam, I. LaRue, et al., Macromolecules 38, 5330 (2005).
V. N. Tsvetkov, V. E. Eskin, and S. Ya. Frenkel’, The Structure of Macromolecules in Solutions (Nauka, Moscow, 1964) [in Russian].
W. Burchard, Adv. Polym. Sci. 143, 113 (1999).
O. G. Zakharova, S. D. Zaitsev, Yu. Yu. Gushchina, et al., Polymer Science, Ser. B 47, 146 (2005) [Vysokomol. Soedin., Ser. B 47, 861 (2005)].
O. G. Zakharova, E. V. Tarasova, M. A. Simonova, et al., Polymer Science, Ser. A 51, 512 (2009) [Vysokomol. Soedin., Ser. A 51, 768 (2009)].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © O.G. Zamyshlyayeva, I.V. Deniskina, A.P. Filippov, Yu.D. Semchikov, 2011, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2011, Vol. 53, No. 8, pp. 1376–1383.
This work was supported by the Russian Foundation for Basic Research, project nos. 09-03-00662, 09-03-90744, 08-03-90707, and 08-03-00421.
Rights and permissions
About this article
Cite this article
Zamyshlyayeva, O.G., Deniskina, I.V., Filippov, A.P. et al. Synthesis and self-organization of amphiphilic poly(N-vinylpyrrolidone-2,2,3,3-tetrafluoropropyl methacrylate) diblock copolymers in solution and bulk. Polym. Sci. Ser. A 53, 691–697 (2011). https://doi.org/10.1134/S0965545X11080128
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0965545X11080128