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Resonance Excitation of Photoluminescence in Crystalline Uranyl Acetate Dihydrate

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Abstract

A method for rapid identification of uranyl compounds based on resonance fiber-optic photoluminescence (PL) excitation by ultraviolet-laser or LED radiation is proposed. This method was used to measure the PL spectra of an extremely small volume (10–9 cm3) of crystalline uranyl acetate dehydrate UO2(CH3COO)2 ∙ 2H2O with an exposure of 10–3 s. Semiconductor LEDs with wavelengths of 369, 385, 410, and 466 nm and a repetitively pulsed nitrogen laser with a lasing wavelength of 337 nm served as sources of excitation radiation. The operating range of a small-sized minispectrometer used in these experiments was 200–1000 nm.

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Authors and Affiliations

  1. Lebedev Physical Institute, Russian Academy of Sciences, Moscow, 119991, Russia

    V. S. Gorelik, A. A. Loboiko & S. O. Nechipurenko

  2. Bauman Moscow State Technical University, Moscow, 105005, Russia

    V. S. Gorelik & A. A. Loboiko

  3. Moscow Institute of Physics and Technology (State University), Dolgoprudnyi, 141707, Russia

    S. O. Nechipurenko

Authors
  1. V. S. Gorelik
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  2. A. A. Loboiko
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  3. S. O. Nechipurenko
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Correspondence to V. S. Gorelik.

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Original Russian Text © V.S. Gorelik, A.A. Loboiko, S.O. Nechipurenko, 2018, published in Optika i Spektroskopiya, 2018, Vol. 124, No. 2, pp. 226–231.

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Gorelik, V.S., Loboiko, A.A. & Nechipurenko, S.O. Resonance Excitation of Photoluminescence in Crystalline Uranyl Acetate Dihydrate. Opt. Spectrosc. 124, 221–226 (2018). https://doi.org/10.1134/S0030400X1802008X

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  • DOI: https://doi.org/10.1134/S0030400X1802008X

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