Skip to main content
SpringerLink
Log in

Coordination behavior of erbium chloride hydrate with diethylammonium diethyldithiocarbamate

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The complex of erbium chloride lower hydrate with diethylammonium diethyldithiocarbamate (D-DDC) has been synthesized conveniently in absolute alcohol and dry N2 atmosphere. The title complex was identified as Et2NH2[Er(S2CNEt2)4] by chemical and elemental analyses, the bonding characteristics of which was characterized by IR. The enthalpies of solution of erbium chloride hydrate and D-DDC in absolute alcohol at 298.15 K and the enthalpies change of liquid-phase reaction of formation for Et2NH2[Er(S2CNEt2)4] at different temperatures were determined by microcalorimetry. On the basis of experimental and calculated results, three thermodynamic parameters (the activation enthalpy, the activation entropy and the activation free energy), the rate constant and three kinetic parameters (the apparent activation energy, the pre-exponential constant and the reaction order) of liquid phase reaction of formation were obtained. The enthalpy change of the solid-phase title reaction at 298.15 K was calculated by a thermochemical cycle.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S. P. Mital, S. K. Sharma, R. V. Singh and J. P. Tandon, Curr. Sci., 50 (1981) 483.

    CAS  Google Scholar 

  2. T. H Ren, J. Xia and J. J. Zhang, Tribology, 18 (1998) 268.

    CAS  Google Scholar 

  3. J. A. Mceleverty, S. Gill, R. S. Z. Kowalski, N. A. Bailey, H. Adams, K, W. Lumbard and M. A. J. Murphy, Chem. Sox. Dalton Trans., (1982) 483.

  4. T. Jiang, W. G. Zhang and J. Y. Shen, Chin. Rare Earth, 21 (2000) 39.

    Google Scholar 

  5. N. Tang, H. L. Zhu and M. Y. Tian, Acta Chim. Sinica, 49 (1991) 42.

    CAS  Google Scholar 

  6. C. Y. Su, M. Y. Tan and N. Tang, J. Coord. Chem., 38 (1996) 207.

    CAS  Google Scholar 

  7. V. L. Varand and L. A. Glinskaya, J. Struct. Chem., 39 (1998) 244.

    Article  CAS  Google Scholar 

  8. V. L. Varand, L. A. Glinskaya, R. F. Klevtsova and S. V. Larinov, J. Struct. Chem., 41 (2000) 544.

    CAS  Google Scholar 

  9. C. Y. Su, N. Tang and M. Y. Tan, Polyhedron, 15 (1996) 233.

    Article  CAS  Google Scholar 

  10. N. Tang, X. M. Gan and W. G. Zhang, Chem. J. Chin Univ., 13 (1992) 141.

    CAS  Google Scholar 

  11. N. Tang, X. M. Gan and H. L. Zhu, Polyhedron, 9 (1990) 859.

    Article  CAS  Google Scholar 

  12. K. K. Dshiya and N. K. Kaushik, Indian J. Chem., 27 (1988) 449.

    Google Scholar 

  13. W. G. Zhang, N. Tang and W. S. Liu, Chin. J. Rare Earths, 20 (2002) 166.

    CAS  Google Scholar 

  14. X. H. Yin and M. Y. Tan, Chin. J. Rare Earths, 20 (2002) 240.

    CAS  Google Scholar 

  15. J. H. Wang, Y. Mu, S. B. Zhang and S. H. Feng, Chem. J. Chin. Univ., 21 (2000) 829.

    CAS  Google Scholar 

  16. Q. G. Li, L. J. Yie, J. N. Qu, Z. G. Liu, Y. Liu and S. S. Qu, Chin. J. Rare Earths, 20 (2002) 293.

    Google Scholar 

  17. T. Trindade, P. O'Brien and N. L. Piskett, Chem. Mater., 13 (2001) 3843.

    Article  CAS  Google Scholar 

  18. M. Krunks, J. Madarász, T. Leskelä, A. Mere, L. Niinistö and G. Pokol, J. Therm. Anal. Cal., 72 (2003) 497.

    Article  CAS  Google Scholar 

  19. M. Ji, M. Y. Liu, S. L. Gao and Q. Z. Shi, Instrum. Sci. Technol., 29 (2001) 53.

    Article  CAS  Google Scholar 

  20. S. L. Gao, Y. Fang, R. Z. Hu and S. P. Chen, J. Therm. Anal. Cal., 73 (2003) 887.

    Article  CAS  Google Scholar 

  21. V. K. Marthada, J. Res. NBS Standards, 85 (1980) 467.

    Google Scholar 

  22. S. L. Gao, Y. Fang, S. P. Chen, R. Z. Hu and Q. Z. Shi, Acta Chim. Sinica, 60 (2002) 2220.

    CAS  Google Scholar 

  23. K. Nakamoto, D. J. Huang and R. Q. Wang, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Chemical and Industrial Press, Beijing, China 1991, p. 276.

    Google Scholar 

  24. S. L. Gao, S. P. Chen, R. Z. Hu and Q. Z. Shi, Chin. J. Inorg. Chem., 18 (2002) 362.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University Xi'an, 710069, P.R. China

    F. Xuezhong, C. Sanping, R. Yixia, J. Baojuan, G. Shengli & S. Qizhen

  2. College of Chemistry and Molecular Engineering, State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University Beijing, 100871, P.R. China

    B. Jiang

Authors
  1. F. Xuezhong
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. C. Sanping
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. Jiang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. R. Yixia
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. J. Baojuan
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. G. Shengli
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. S. Qizhen
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Xuezhong, F., Sanping, C., Jiang, B. et al. Coordination behavior of erbium chloride hydrate with diethylammonium diethyldithiocarbamate. Journal of Thermal Analysis and Calorimetry 78, 273–282 (2004). https://doi.org/10.1023/B:JTAN.0000042174.45083.7f

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JTAN.0000042174.45083.7f

Search

Navigation