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Synthesis and Structure of Triphenylbismuth Difluoride

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Abstract

The reaction of triphenylbismuth dichloride with sodium fluoride in acetone leads to formation of triphenylbismuth difluoride in 73% yield. The X-ray diffraction data show that the bismuth atom in the two symmetrically independent molecules of bismuth difluoride has a trigonal-bipyramidal coordination with equatorial fluorine atoms. The Bi-F and Bi-C distances are 2.53(1)-2.59(1) and 2.10(3)-2.22(2) Å, respectively, and the FBiF angle is 175.1(5)°.

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Authors and Affiliations

  1. Blagoveshchensk State Pedagogical University, Blagoveshchensk, Russia

    V. V. Sharutin, O. K. Sharutina, I. V. Egorova, T. K. Ivanenko & V. K. Bel'skii

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. I. V. Egorova
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  4. T. K. Ivanenko
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  5. V. K. Bel'skii
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Sharutin, V.V., Sharutina, O.K., Egorova, I.V. et al. Synthesis and Structure of Triphenylbismuth Difluoride. Russian Journal of General Chemistry 72, 44–45 (2002). https://doi.org/10.1023/A:1015328925333

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  • DOI: https://doi.org/10.1023/A:1015328925333

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