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Mechanism of Thermal Decomposition of d-metals Nitrates Hydrates

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Abstract

A series of six nitrates(V) hydrates of 4d-metals as well as mercury and cadmium thermal decomposition was examined by DTA, TG and EGA techniques. It was found that thermal decomposition of d-metals nitrate(V) hydrates proceeds in three stages: partial dehydration, oxo-nitrates and hydroxide nitrates formation and metal oxides formation. General chemical equations for all decomposition stages were proposed. It was found that dehydration of hydrated salts is accompanied by partial decomposition of nitrate(V) groups.

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References

  1. J. Mu and D. D. Perlmutter, Thermochim. Acta, 56 (1982) 253.

    Article  CAS  Google Scholar 

  2. B. V. L'vov and A. V. Novichikhin, Spectrochim. Acta Part B, 50 (1995) 1427.

    Article  Google Scholar 

  3. J. G. Jackson, R. W. Fonsca and J. A. Holcombe, Spectrochim. Acta Part B, 50 (1995) 1449.

    Article  Google Scholar 

  4. A. Małecki, A. Małecka, R. Gajerski, B. Prochowska-Klisch and A. Podgórecka, J. Thermal Anal., 34 (1988) 203.

    Article  Google Scholar 

  5. A. Małecki, R. Gajerski, S. Łabuś and B. Prochowska-Klisch, J. Thermal Anal., 39 (1993) 545.

    Google Scholar 

  6. R. Gajerski, S. Łabuś, A. Małecki and K. T. Wojciechowski, Proc. of 7th Conf. on Calorimetry and Thermal Analysis CETTA '97, Poland, ed. University of Łódż, 1997, p. 309.

  7. K. T. Wojciechowski, R. Gajerski, S. Łabuś and A. Małecki, Proc. of 7th Conf. on Calorimetry and Thermal Analysis CETTA '97, Poland, ed. University of Łódż, 1997, p. 80.

  8. K. T. Wojciechowski, R. Gajerski, S. Łabuś and A. Małecki, Proc. of 7th Conf. on Calorimetry and Thermal Analysis CETTA '97, Poland, ed. University of Łódź, 1997, p. 79.

  9. A. F. Wells, Structural inorganic chemistry, Polish ed., WNT Warszawa 1993.

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Authors and Affiliations

  1. Faculty of Materials Science and Ceramics, University of Mining and Metallurgy, Al. Mickiewicza 30, 30–059, Cracow, Poland

    A. Małecki, R. Gajerski, S. Łabuś, B. Prochowska-Klisch & K. T. Wojciechowski

Authors
  1. A. Małecki
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  2. R. Gajerski
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  3. S. Łabuś
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  4. B. Prochowska-Klisch
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  5. K. T. Wojciechowski
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Małecki, A., Gajerski, R., Łabuś, S. et al. Mechanism of Thermal Decomposition of d-metals Nitrates Hydrates. Journal of Thermal Analysis and Calorimetry 60, 17–23 (2000). https://doi.org/10.1023/A:1010155931266

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  • DOI: https://doi.org/10.1023/A:1010155931266

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