Life Cycle Gap Analysis for Product Circularity and Sustainability—a Case Study with Three Different Products

This paper aims to demonstrate the applicability and benefits of life cycle gap analyses for systematically integrating circular economy considerations into life cycle assessment. It presents life cycle gap analyses for three entirely different products (rechargeable batteries, T-shirts, plastic bottles), compares the applications and results, and draws conclusions on the usefulness of the method. The case studies reveal life cycle gaps of 54% (plastic bottles), 61% (rechargeable batteries), and 98% (T-shirts), indicating high potential for further circularity improvements in the current life cycle systems of different industries and product groups. At the same time, a potential weakness of the method is underlined. Even considering options to increase circularity, life cycle gaps of at least 45% still exist, raising the question of what measures are really needed in order to achieve product circularity and sustainability. The analysis demonstrates the general applicability of life cycle gap analyses and their contribution to the integration of circular decision-making and life cycle thinking.


Introduction
Sustainable development requires the closure of product material and energy cycles, and significant reductions in environmental impacts across the entire life cycle. (UN 2015) Quantitative approaches, such as life cycle assessment (LCA), allow the environmental impacts to be analyzed and assessed based on their material and energy cycles from cradle to grave, or from cradle to second life. Hence, such comprehensive LCA studies contain not only all the relevant information to assess products' life cycle impacts, but also to evaluate their circularity. In order to highlight this mindset, a life cycle gap analysis (LCGA; Dieterle et al. 2018) was developed as a specific technique to interpret LCA results with emphasis on circular economy (CE) principles, which aim at closing products' material loops and thereby minimizing resource inputs, waste, emissions, and energy leakages (Geissdoerfer et al. 2017). This paper aims to demonstrate the applicability and benefits of the LCGA method for systematically integrating CE considerations into LCA.
The basic idea of LCGA is to identify a product's life cycle gap (LCG) which results from the difference between the environmental impacts of the product's initial manufacturing and its environmental credits after recycling. In contrast to the common assessment and interpretation of LCA studies, environmental credits in the end-of-life (EoL) phase are uncoupled from environmental impacts for recycling and compared to initial impacts of the manufacturing phase. In this way, circular economy thinking is given its own stage within life cycle assessment interpretation. Figure 1 illustrates the iterative procedure of the LCGA, following the six defined steps of the methodology .
To exemplify and validate the applicability of the LCGA methodology, this study assesses three different types of products. Based on their respective EU product environmental footprint (PEF) pilot LCA studies, it examines a rechargeable nickel-metal hydride (Ni-MH) battery, a T-shirt, and a one-way polyethylene terephthalate (PET) bottle. The three products' LCGA implementation and results are compared and discussed with regard to applicability, benefits, and limitations of the method in general.

LCGA Application
LCGA was applied to a rechargeable Ni-MH battery, a T-shirt, and a one-way PET bottle. These common products were selected to represent a large range of products with different complexities, raw materials, and applications. Data for the status quo of these products have been derived from PEF pilot studies (EC 2018a, b; EC 2019). The publicly available studies provide a huge level of detail and transparency, are based on the work of LCA experts from the respective industries, and follow comprehensive LCA guidelines. The functional unit (FU) of the different products is defined as follows: • Ni-MH battery-"1 kWh of the total energy provided over the service life by the battery system" (EC 2018a); • One-way PET bottle 1.5 l-"to provide 100 ml of water" (EC 2018b); • T-shirt-"to wear a clean T-shirt until it becomes dirty 52 times" (EC 2019).
The whole life cycle of the three products is taken into account and divided into the phases of raw material acquisition, production of the main product, use phase (including product distribution), and EoL. While the product environmental footprint pilot studies feature a range of environmental impact categories, this paper focuses on climate change (global warming potential-GWP 100) only, expressed in grams of carbon dioxide equivalent (gCO 2 eq). Climate change is of highest concern and the best known and most robust environmental impact category, and is used as a proxy for all environmental impacts here. In principle, the LCGA method is capable of including several different environmental impact categories while using single-score indicators, such as Eco-Points (see, for example, Ahbe et al. (2018); Sala et al. (2018); Zampori and Pant (2019)).
Step 1: LCA Results of the Three Representative Products. According to the first step of the methodology (see Fig. 1), Table 1 summarizes the LCA results of the three representative products derived from product environmental footprint pilot studies (EC 2018a, b;EC 2019).
With a share of more than 70%, the manufacturing phase (raw material acquistion and production) dominates the life cycle impacts of all products. The use phase has a share of between 15% (battery) and 29% (T-shirt). With a higher contribution of renewable energy sources to the overall energy Fig. 1 Iterative procedure of the LCGA according to Dieterle et al. (2018) mix in the future, in the long run, the importance of the use phase is likely to diminish further for all three products.
Results within EoL (sum of environmental impacts for recycling minus environmental credits for recovery of energy and materials) indicate positive effects of EoL treatment for the battery and the PET bottle and almost no effect for the T-shirt.
The Ni-MH battery obtains similar results (see Fig. 2b). In the EoL phase, a mechanical pre-treatment followed by a pyrometallurgical and hydrometallurgical recycling of the battery allows the recovery of certain elements and metals at high qualities and quantities. For steel, an effective recycling rate over 90%, and for nickel sulfate and cobalt sulfate a rate of over 50% compared to virgin material can be achieved (calculated from EC 2018a). Overall, though, a LCG of 61% remains and indicates a high potential for further improvement from a CE perspective.
The results for the T-shirt (see Fig. 2c) reveal the largest LCG of around 98% and indicate a significant potential for further improvement from a CE perspective. According to the state of the art (EC 2019), only 11% of the cotton fibres are recycled (downcycled) into wiping cloths and insulation  materials. At EoL, the main fraction of the T-shirt is incinerated (around 37%) or deposited (around 52%).
Step 3: Identify Measures to Increase Circularity (Minimize LCG of the Initial Product System). According to Step 3 of the methodology (see Fig. 1), different strategies to close products' material and energy cycles are identified in the literature and applied in this case study in order to reduce the existing LCG of the three representative products. For the one-way PET bottle, an increased content of recycled PET materials within manufacturing is considered. Strict decontamination requirements are placed on recycled PET for food and beverage applications, including reprocessing with virgin resin with blending (multi-layered products) and a risk of colouration. Hence, a typical recycling content to be incorporated into a new PET bottle is around 35% (Valentino 2017, according to Komly et al. 2012and Shen et al. 2011. Much higher recycling rates of up to > 90% are likely to be reached by chemical recycling of PET materials, i.e. depolymerisation via hydrolase into monomers with virgin quality (Tournier, et al. 2020).
For the Ni-MH battery, an improvement of the recycling and upgrading process within the EoL phase is considered. The status quo includes recycling of the steel fractions (arising from the housing) and the nickel and cobalt elements (arising from the negative and positive electrodes) after mechanical pre-treatment and pyrometallurgical treatment of the battery. The newly developed recycling process also includes the recovery of cerium oxide and lanthanum oxide from the slag after pyrometallurgical treatment, using an additional acid leaching process and an ionometallurgical process (Salles et al. 2018). Such findings are in line with other approaches for the recovery of critical raw materials and precious metals from low-concentrated streams in hydrometallurgical technologies (Perez et al. 2019).
For the T-shirt, an improvement of the recycling and upgrading process within the EoL phase is likewise considered. In contrast to the status quo, where the main fraction of the T-shirt is incinerated (around 37%) or deposited (around 52%) (EC 2019), an advanced mechanical recycling process with sorting, washing, and shredding is introduced in order to substitute 80% of virgin cotton fibres in bales. The remaining 20% of losses are still incinerated (Schmidt et al. 2016). This is in line with other studies, which also state a mass loss rate of nearly 20% of the cotton fibres after the process of breaking fabrics for yarn recycling (Liu et al. 2020). Figure 3 illustrates the consideration of the recycled content approach for the PET bottle, and the consideration of the avoided burden approach for the Ni-MH battery and the T-shirt, according to Nordelöf et al. (2019).
Step 4: Assessing the LCG of the New Product System. A LCG computation can be used to assess the effects of the CE improvement measures derived from Step 3.
For the new one-way PET bottle (see Fig. 4a), which is now based on 35% of recycled PET materials (bottle-tobottle), the increased content of recycled material allows the environmental impacts for the raw material acquisition of the PET bottle to be reduced by 14%, and the LCG to be reduced in turn by 9%, from the original 54% (6.3 gCO 2 eq) to 45% (5.2 gCO 2 eq): The environmental credits after recycling of the PET bottle in the second loop stay more or less constant and decrease only by about 0.5 gCO 2 eq (quality loss of 10% per recycling loop compared to virgin material).
For the Ni-MH battery (see Fig. 4b), the newly developed recycling solution for the additional recovery of cerium oxide and lanthanum oxide reduces the LCG by about 10%, from the original 61% (732 gCO 2 eq) to 51% (620 gCO 2 eq): (4) LCG NEW;bottle = 6.7gCO 2 eq + 3.3gCO 2 eq −4.8gCO 2 eq = 5.2gCO 2 eq Fig. 3 Illustration of the measures to increase the circularity of the PET bottle, Ni-MH battery, and T-shirt. Diagramme modified according to (Nordelöf et al. 2019) Finally, for the T-shirt with improved material recycling of cotton fibres, the LCG is reduced by about 26%, from 98% (4,300 gCO 2 eq) to 72% (3,175 gCO 2 eq). Figure 4 illustrates the LCG of both, the initial and the improved product systems.
Step 5 and Step 6: Assessing the LCA Results of the New Product System and Comparing with the Status Quo. After improvement of the LCG of each product system according to Step 3 (identification of potentials for improvement) and Step 4 (assessment of the new options for improvement), possible trade-offs for other life cycle stages have to be assessed (Step 5) and compared with the status quo (Step 6). Table 2 summarizes the LCA results of the new product (5) LCG NEW;battery = 1, 155gCO 2 eq + 55gCO 2 eq − 590gCO 2 eq = 620gCO 2 eq (6) LCG NEW;shirt = 1, 900gCO 2 eq + 2, 500gCO 2 eq − 1, 225gCO 2 eq = 3, 175gCO 2 eq system (X NEW ), including a comparison with the initial product system (X 0 ). Table 2 shows that in all three cases the overall life cycle impacts are lower for the new product systems. The defined restrictions within Step 6 were fulfilled (as indicated with a green tick), which means that the products' CE improvement ensures an effective contribution towards sustainable development (avoidance of negative trade-offs). In the case of the battery, the overall improvement is only marginal (3%) due to higher recycling efforts, which counteract the benefits of more recycled material to some extent. The LCA results of the CE improved PET bottle show a decrease of manufacturing impacts by about 14%, as 35% recycled PET material (bottle-to-bottle) is used. This leads to a small reduction in environmental credits at EoL by about 0.5 gCO 2 eq, as the quality factor of  Table 2 LCA results of the initial product system and the CE improved alternatives X 0 (gCO 2 eq) X NEW (gCO 2 eq) X 0 (gCO 2 eq) X NEW (gCO 2 eq) X 0 (gCO 2 eq) X NEW (gCO 2 eq) Raw material acquisition 8.3 6 .7 1,155 the recycled PET material (second loop) has to be reduced by about 10% compared to the first loop (virgin material). At EoL of the Ni-MH battery, the increase of environmental credits by about 23% overcompensates the additional environmental impacts for recycling of the slag. The same situation occurs for the T-shirt: environmental credits increase by factor 12 and overcompensate the additional environmental impacts of recycling the textile cotton fibres.

Discussion
Our research shows that total life cycle impacts do not only result from the manufacturing and use phases, but also from EoL and closing products' material and energy cycles. To address this issue, we applied the life cycle gap analysis within the interpretation phase of the LCA for three entirely different products and identified substantial gaps of at least 54%. Based on different findings and innovations for CE from literature, strategies to reduce these life cycle gaps were explored further: • For one-way PET bottles, an increased content of recycled PET materials within manufacturing reduces the LCG by 9%, from 54% (6.3 gCO 2 eq) to 45% (5.2 gCO 2 eq). • For Ni-MH batteries, an improvement of the slag recycling after mechanical pre-treatment and within pyrometallurgical treatment to recover cerium oxide and lanthanum oxide leads to LCG reductions of about 10%, from 61% (732 gCO 2 eq) to 51% (620 gCO 2 eq). • For T-shirts, advanced mechanical recycling (including sorting, washing, and shredding) is capable of substituting 80% of virgin cotton fibres in bales and leads to LCG reductions of 26%, from 98% (4,300 gCO 2 eq) to 72% (3,175 gCO 2 eq).
Moreover, in all three cases, negative trade-offs were avoided, as the total life cycle impacts were lower compared to the status quo (3% reduction of total impacts for Ni-MH batteries, 9% for PET bottles, and 17% for T-shirts). The contribution towards circular economy and sustainability is therefore positive.
The application of the life cycle gap analysis in this study demonstrates the usefulness of a LCGA as a supporting element within the interpretation phase of LCA studies. The LCGA enables the systematic evaluation of the environmental impacts of circularity options within the well-established and frequently used LCA method without demanding new impact assessment methods or modifications of the core methodology.
This pragmatic integration of circular economy thinking into LCA methodology bears a potential weakness. A LCGA does not scrutinize the general necessity of a given product or service. Instead, it aims to increase its circularity and recyclability in given (linear) value chains and business models. The LCGA results for the three entirely different products not only show improvements in environmental performance and circularity, but also reveal large life cycle gaps even after considering ambitious options for improvement. Beyond LCGAs, disruptive innovations and new CEoriented business models might be better suited to achieve more comprehensive levels of circularity and sustainability, e.g., by preserving the function of products or services by sharing platforms and schemes promoting product redundancy and multifunctionality, or by preserving the product itself through lifetime increase with strategies such as durability, reuse, restore, refurbish, and remanufacture (Moraga et al. 2019).

Conclusions and Outlook
Many LCA studies, including the three different product examples considered in this paper, identify manufacturing and use phases as the main drivers of overall impact, and make significant efforts to analyze these phases accordingly. In contrast, the EoL phase is treated rather coarsely due to the fact that its processes, such as waste incineration, do not contribute significantly to overall impacts. Taking a CE perspective, the EoL phase holds enormous potential, though. Large portions of the efforts put into raw material acquisition and production could potentially be reclaimed by means of reuse, recycling, or other CE approaches. Developing CE strategies hence need a thorough investigation of the circularity potential of energy and material flows at the end of a product's life cycle. LCGA allows a transition of this mindset into LCA methodology by considering two novel principles within the interpretation stage: 1. Environmental credits in the EoL phase, stemming from the substitution of primary materials and energy, are uncoupled from the environmental impacts for recycling and not offset anymore, as it is done in classical crediting systems of common LCA studies. 2. The environmental credits are shifted to the manufacturing phase, as the focus of CE strategies is to close products material and energy flows and to minimize resource input and waste, emission, and energy leakages.
Using LCGA allows to shed light on the advantages of circular economy-oriented options within LCA interpretation, and on possible trade-offs with regard to life cycle thinking and sustainability. Further research is required to cover more complete sets of environmental impact categories and their trade-offs as well as other industries and product groups. The integration of cost assessments into LCGA is a further promising research strategy for the future (Dieterle and Viere 2021). This includes both the comparison of additional costs for and income from CE improvements for the manufacturer, and (macro-)economic assessments of the societal costs of CE strategies and their entire life cycle impacts. Integrated assessments of environmental impacts and economic aspects within LCGA might eventually also be used to identify barriers to and drivers of business models for circular and sustainable products.
The integration of circular decision-making and life cycle thinking is a vital challenge for industrial ecology and corporate sustainability research and application. Life cycle gap analyses provide an analytical contribution to this further development.