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Research on the mechanical properties and electrical conductivity of cement mortar based on recycled nano-iron boride

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Abstract

Traditional cement-based materials are being gradually replaced by nanomodified cement-based materials because the traditional materials cannot meet the production needs of modern society. Nano-iron boride (nano-FeB) is a high-performance nanomaterial prepared from waste iron powder during construction. Its one-dimensional structure is similar to that of carbon nanotubes, which makes it a potential candidate for nano-reinforcement materials. In this paper, the effects of different contents of recycled nano-FeB (0%, 0.05%, 0.075%, and 0.1 wt.%, based on cement weight) on the mechanical properties and electrical conductivity of cement mortar were studied. The results showed that the mechanical properties of the composite cement mortar were improved with the addition of nano-FeB. When the content of nano-FeB was 0.075%, the 28 d compressive strength and flexural strength of the composite cement mortar increased by 60.2% and 42.1%, respectively. In addition, a 0.075% nano-FeB content favorably improved the conductivity of cement mortar. Compared with that of the control group, the volume resistivity of the composite cement mortar decreased by one order of magnitude.

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References

  1. Ming, L. 2012. Opening a new chapter in the cement industry in the new century. In The 7th member representative conference of China Cement Association. Beijing, 31 October 2012.

  2. Parveen, S., Rana, S., Fangueiro R., et al. 2013. A Review on Nanomaterial Dispersion, Microstructure, and Mechanical Properties of Carbon Nanotube and Nanofiber Reinforced Cementitious Composites. Journal of Nanomaterials 2013: 710715.

  3. Liu, J., Fu, J.L., Ni, T.Y., et al. 2019. Fracture toughness improvement of multi-wall carbon nanotubes/graphene sheets reinforced cement paste. Construction and Building Materials 200: 530–538.

    Article  CAS  Google Scholar 

  4. Tang, S.W., Yao, Y., Andrade, C., et al. 2015. Recent durability studies on concrete structure. Cement and Concrete Research 78: 143–154.

    Article  CAS  Google Scholar 

  5. Xu, S., Liu, J., and Li, Q. 2015. Mechanical properties and microstructure of multi-walled carbon nanotube-reinforced cement paste. Journal of Materials in Civil Engineering 76: 16–23.

    Google Scholar 

  6. Dimov, D., Amit, I., Gorrie, O. et al. 2018. Ultrahigh performance nanoengineered graphene-concrete composites for multifunctional applications. Advanced Functional Materials 28 (23): 1705183.

    Article  Google Scholar 

  7. Mohseni, E., Naseri, F., Amjadi, R., et al. 2016. Microstructure and durability properties of cement mortars containing nano-TiO2 and rice husk ash. Construction and Building Materials. 114: 656–664.

    Article  CAS  Google Scholar 

  8. Mohseni, E., Khotbehsara, M.M., Naseri, F., et al. 2016. Polypropylene fiber reinforced cement mortars containing rice husk ash and nano-alumina. Construction and Building Materials. 111: 429–439.

    Article  CAS  Google Scholar 

  9. Li, H., Xiao, H.G., Yuan, J., et al. 2004. Microstructure of cement mortar with nano-particles. Composites Part B: Engineering 35 (2): 185–189.

    Article  Google Scholar 

  10. Walters, D.A., Ericson, L.M., Casavant, M.J., et al. 1999. A molecular dynamics study on tle-wall carbon nanotube ropes. Applied Physics Letters 74 (25): 3803–3805.

    Article  CAS  Google Scholar 

  11. Zhang, S., Zhang, N., and Zhang, J. 2020. Controlled synthesis of carbon nanotubes: past, present and future. Acta Phys-Chim. Sin. 36 (1): 1907021.

    Article  Google Scholar 

  12. Silvestre, N., Faria, B., José, N., et al. 2011. A molecular dynamics study on the thickness and post-critical strength of carbon nanotubes. Composite Structures. 94 (4): 1352–1358.

    Article  Google Scholar 

  13. Yu, L.Q., Dong, K.T., Yang, C., et al. 2014. Facile synthesis and dehydrogenation properties of Fe3B nanoalloys. Materials Letters 132: 4–7.

    Article  CAS  Google Scholar 

  14. Siddique, R., and Mehta, A. 2014. Effect of carbon nanotubes on properties of cement mortars. Construction and Building Materials 50: 116–129.

    Article  Google Scholar 

  15. Konsta-Gdoutos, M.S., Metaxa, Z.S., and Shah, S.P. 2010. Highly dispersed carbon nanotube reinforced cement based materials. Cement and Concrete Research 40 (7): 1052–1059.

    Article  CAS  Google Scholar 

  16. García-Macías, E., D’Alessandro, A., Castro-Triguero, R., et al. 2017. Micromechanics modeling of the electrical conductivity of carbon nanotube cement-matrix composites. Sensors 108: 451–469.

    Google Scholar 

  17. Konsta-Gdoutos, M.S., Metaxa, Z.S., and Shah, S.P. 2009. Multi-scale mechanical and fracture characteristics and early-age strain capacity of high performance carbon nanotube/cement nanocomposites. Cement and Concrete Composites 32 (2): 110–115.

    Article  Google Scholar 

  18. Yan, L., and Chang, R. 2006. Synthesis and characterization of iron silicon boron (Fe5Si2B) and iron boride (Fe3B) nanowires. Journal of the American Chemical Society 128 (39): 12778–12784.

    Article  Google Scholar 

  19. Yu, L., Dong, K., Yang, C., et al. 2014. Facile synthesis and dehydrogenation properties of Fe3B nanoalloys. Materials Letters 132: 4–7.

    Article  CAS  Google Scholar 

  20. Ocon, J.D., Tuan, T.N., Yi, Y., et al. 2013. Ultrafast and stable hydrogen generation from sodium borohydride in methanol and water over Fe–B nanoparticles. Journal of Power Sources 243: 444–450.

    Article  CAS  Google Scholar 

  21. Abrenica, G.H., Ocon, J.D., and Lee, J. 2016. Dip-coating synthesis of high-surface area nanostructured FeB for direct usage as anode in metal/metalloid-air battery. Current Applied Physics 16 (9): 1075–1080.

    Article  Google Scholar 

  22. Zhou, G.M., Wang, D.W., Li, F., et al. 2011. The effect of carbon particle morphology on the electrochemical properties of nanocarbon/polyaniline composites in supercapacitors. New Carbon Materials 49 (13): 4608–4609.

    CAS  Google Scholar 

  23. Wei, Y.N. 2017. Synthesis of Me-B(Me=Cr, V, Fe) powders by molten salt method and its properties, vol. 6. Anhui University of Technology.

  24. Doñu, M.A., Perrusquia, N., Huerta, D., et al. 2015. Growth kinetics of boride coatings formed at the surface AISI M2 during dehydrated paste pack boriding. Thin Solid Films 596: 147–154.

    Article  Google Scholar 

  25. Li, T., Wei, Y., Zhang, L., et al. 2015. Sintered SrFe12O19/Fe-B composites: precipitation of α-Fe and magnetic properties. Journal of Alloys and Compounds 649: 760–765.

    Article  CAS  Google Scholar 

  26. Shao, H., Chen, B., Li, B., et al. 2017. Influence of dispersants on the properties of CNTs reinforced cement-based materials. Construction and Building Materials 131: 186–194.

    Article  CAS  Google Scholar 

  27. Hu, S., Xu, Y., Wang, J., et al. 2020. Modification effects of carbon nanotube dispersion on the mechanical properties Pore Structure, and Microstructure of Cement Mortar. Materials 13 (5): 1101.

    Article  CAS  Google Scholar 

  28. Kim, G.M., Yang, B.J., Cho, K.J., et al. 2017. Influences of CNT dispersion and pore characteristics on the electrical performance of cementitious composites. Composite Structures 164: 32–42.

    Article  Google Scholar 

  29. Yao, W., Zuo, J.Q., Wu, K.R., 2013. Microstructure and thermoelectric properties of carbon nanotube-carbon fiber/cement composites. Journal of Functional Materials 44 (13): 1924-1927,1931.

    CAS  Google Scholar 

  30. álvaro Garcí, A., Schlangen, E., Ven M.V.D., et al. 2009. Electrical conductivity of asphalt mortar containing conductive fibers and fillers. Construction and Building Materials 23(10): 3175–3181.

  31. Jeevanagoudar, Y.V., Hari Krishna, R., Gowda, R., et al. 2017. Improved mechanical properties and piezoresistive sensitivity evaluation of MWCNTs reinforced cement mortars. Construction and Building Materials. 144: 188–194.

    Article  CAS  Google Scholar 

  32. Pan, Z., He, L., Qiu, L., et al. 2015. Mechanical properties and microstructure of a graphene oxide–cement composite. Cement and Concrete Composites 58: 140–147.

    Article  CAS  Google Scholar 

  33. Mehta, P.K., Monteiro, P. 2006. Concrete: microstructure, properties, and materials. McGraw-Hill Education: New York, NY.

  34. Chuah, S., Pan, Z., Sanjayan, J.G., et al. 2014. Nano reinforced cement and concrete composites and new perspective from graphene oxide. Construction and Building Materials 73: 113–124.

    Article  Google Scholar 

  35. Nazari, A., Riahi, S., Riahi, S., et al. 2010. Benefits of Fe2O3 nanoparticles in concrete mixing matrix. Journal of American ence 6 (4): 102–106.

    Google Scholar 

  36. Sobolev, S.K. 2010. Nanotechnology in concrete—a review. Construction and Building Materials 24 (11): 2060–2071.

    Article  Google Scholar 

  37. Xu, S., Liu, J., and Li, Q. 2015. Mechanical properties and microstructure of multi-walled carbon nanotube-reinforced cement paste. Construction and Building Materials 76 (Feb.1): 16–23.

    Article  Google Scholar 

  38. Zuo, J., Yao, W., Wu, K. 2015. Seebeck effect and mechanical properties of carbon nanotube-carbon Fiber/Cement Nanocomposites. Fullerenes, Nanotubes and Carbon Nanostructures 23 (5): 383–391.

    Article  CAS  Google Scholar 

  39. Manzur, T., and Yazdani, N. 2015. Optimum mix ratio for carbon nanotubes in cement mortar. KSCE Journal of Civil Engineering 19 (5): 1405–1412.

    Article  Google Scholar 

  40. Kong, D., Su, Y., Du, X., et al. 2013. Influence of nano-silica agglomeration on fresh properties of cement pastes. Construction and Building Materials 43: 557–562.

    Article  Google Scholar 

  41. Wu, S., Mo, L., Shui, Z., et al. 2004. Investigation of the conductivity of asphalt concrete containing conductive fillers. Carbon 43 (7): 1358–1363.

    Article  Google Scholar 

  42. Feng, C.H., Wang, X.J., Zhu, J.P., et al. 2013. Research progress of the application of nanometer materials in concrete. Bulletin of the Chinese Ceramic Society 2013 (08): 1557–1561.

    Google Scholar 

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Acknowledgements

Financial support from the National Natural Science Foundation of China under the grants of 51578477 and 51708403, the Key Research and Development Project of Hebei Province under the grant of 19211505D, and the China Postdoctoral Science Foundation under the grants of 2018T110200 and 2018M640236 is gratefully acknowledged.

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Correspondence to Wei He.

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He, W., Jiao, Z., Wang, Y. et al. Research on the mechanical properties and electrical conductivity of cement mortar based on recycled nano-iron boride. Waste Dispos. Sustain. Energy 3, 155–164 (2021). https://doi.org/10.1007/s42768-021-00072-1

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