Spectroscopic evaluation of vibrational temperature and electron density in reduced pressure radio frequency nitrogen plasma

The optical emission spectroscopy technique is used to determine the vibrational temperature of the second positive band system,N2(C,υ′-B,υ″\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ N_{2} (C,\upsilon^{^{\prime}} - B,\upsilon^{^{\prime\prime}}$$\end{document}) in the wavelength range 367.1–380.5 nm by using the line-ratio and Boltzmann plot methods. The electron temperature is evaluated from the intensity ratio of the selected molecular bands corresponding to N2+(B,υ-X,υ′,\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$N_{2}^{ + } (B,\upsilon - X, \upsilon^{^{\prime}} , $$\end{document} 391.44 nm), and, N2(C,υ′-B,υ″\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$N_{2} (C,\upsilon^{^{\prime}} - B,\upsilon^{^{\prime\prime}}$$\end{document}, 375.4 nm) transitions, respectively. The selected bands have a different threshold of excitation energies and thus serve as a sensitive indicator of the electron energy distribution function (EEDF). The electron density has been determined from the intensity ratio of the molecular transitions corresponding to N2+(B,υ-X,υ′,\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$N_{2}^{ + } (B,\upsilon - X, \upsilon^{^{\prime}} , $$\end{document} 391.44 nm), and, N2(C,υ′-B,υ″\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ N_{2} (C,\upsilon^{^{\prime}} - B,\upsilon^{^{\prime\prime}}$$\end{document}, 380.5 nm) for different levels of pressure and radio frequency power. The results show that the vibrational temperature decreases with increasing nitrogen fill pressure and radio frequency power. However, the electron temperature increases with radio frequency power and reduces with fill pressure. The electron density increases both with nitrogen fill pressure and radio frequency power that attributes to the effective collisional transfer of energy producing electron impact ionization. Plasma parameters show a significant dependence on discharge conditions and can be fine-tuned for specific surface treatments. Spectrum analysis of RF-driven nitrogen plasma for varying discharge conditions Evaluation of vibrational temperature using line-ratio and Boltzmann plot methods Comparison of vibrational temperatures for line-ratio and Boltzmann plot methods Evaluation of electron temperature and density using the intensity-ratio of bands Correlation of temperature and density with varying fill pressure and RF power Spectrum analysis of RF-driven nitrogen plasma for varying discharge conditions Evaluation of vibrational temperature using line-ratio and Boltzmann plot methods Comparison of vibrational temperatures for line-ratio and Boltzmann plot methods Evaluation of electron temperature and density using the intensity-ratio of bands Correlation of temperature and density with varying fill pressure and RF power


Introduction
Radio frequency plasma-based surface treatment such as etching, sputtering, and thin-film deposition is the emerging research field aimed at diverse industrial applications [1][2][3]. Therefore, studies on radiofrequency (RF) discharges are essential to select the plasma conditions for specific surface modifications to have potential applications in the field of material and electronic sciences. It is affectionate to produce low-density, low-temperature plasma in RF discharge for high-tech industrial applications. RF sources are someway more advanced than DC sources regardless of some common properties. They demonstrate well-controlled plasma kinetics and have more ability to excitation/ionization. RF plasma sources are generally subdivided into two types depending on their energy coupling mechanisms. These types are inductively coupled plasma (ICP) and capacitively coupled plasma (CCP). Both configurations can use electrodes conductive or nonconductive, built within the tube of low-pressure gas or outside of it. Commonly RF plasma source with a frequency of 13.56 MHz in the capacitively coupled configuration is preferred for surface treatments [4,5].
Plasma spectroscopy has a wide range of applications in the field of plasma analysis and parametric optimization. The most convenient and commonly used method for the diagnostic of reactive plasma is optical emission spectroscopy (OES) because it does not perturb the plasma, like other diagnostic tools such as Langmuir probes. The plasma particles go through electron impact excitation and subsequent de-excitation emitting light of a specific wavelength. These radiations provide the details of the plasma species and their energies, making OES in the visible range an attractive method for plasma analysis with an easily manageable experimental setup [6][7][8]. The line radiations from plasma take in some broadening in their energy levels owing to different broadening mechanisms including natural broadening, pressure broadening, Doppler broadening, and Stark broadening, etc. Consequent broadening in the wavelength of spectral lines depends on the plasma environments [9][10][11]. Alternatively, the intensity of the spectral line is sensitive to the shape of the electron energy distribution function (EEDF), electron temperature, and electron number density (n e ), fundamental parameters characterizing the discharge conditions. Molecular spectroscopy deals with three basic modes of molecular excitation named rotational, vibrational, and electronic, and subsequent de-excitation. However, here the main focus is on the electron impact excitation of the vibrational and the electronic states of the molecule to determine the vibrational and the electron temperatures. In a vibrational mode of excitation, the electrons gain energy from the applied electric field and transfer to nitrogen molecules through the collisional process. As a result, the nitrogen molecules jump to the higher vibrational levels without changing the electronic level and subsequently de-excited by emitting photons of characteristic wavelengths in the infrared region. The identification of the spectral lines/bands and quantification of their respective intensities give information on the energy and density of the charged particles, the population density of the excited states, and plasma composition. The knowledge of vibrational temperature is essential to understand the physical and chemical properties of N 2 discharge. Qianghua et al. [12] studied the vibrational temperature of second positive system of N 2 for varying values of RF power at a fixed fill pressure of 0.26 mbar. Levaton et al. [13] investigated the effect of gas flow rate, fill pressure and discharge current on the emission intensity of the second positive system of N 2 , and vibrational temperature. They found that vibrational temperature has a strong dependence on the discharge conditions. The reactive nature of nitrogen plasma makes it very suitable for surface modification and deposition. Plasma nitriding is the most useful method for surface treatments and has potential industrial applications [14].
The paper reports the vibrational temperature obtained from the relative intensity of the bands of the second posi- for different values of RF power and nitrogen pressure at a fixed frequency of 13.56 MHz. The information of the electron temperature and number density is also mandatory to understand the physical properties of the electric discharge. To characterize the large group of the electron's energy distribution, the intensity of the N 2 -bands having a large difference in the excitation threshold energies has been used to determine the electron temperature. Therefore, the intensity-ratio of the emission bands belonging to the first negative system N + .44 nm, and the second positive system N 2 (C 3 Π u → B 3 Π u ) at 375.4 nm, and 380.5 nm is analyzed for electron temperature and density respectively.

Experimental details
For optical characterization of capacitively coupled RFgenerated nitrogen plasma between two disk-like electrodes, spectroscopic analysis is performed for different levels of RF power and nitrogen fill pressure. The vacuum chamber is a cylindrical shape made of Pyrex glass that provides the best possible visibility for the discharge dynamics and eliminates the need for extra optical windows for light collection to make plasma observations. The height and diameter of the chamber are 28-cm and 16-cm. The plasma chamber includes upper and bottom parallel disc-like circular brass electrodes assembly with a diameter of 5-cm, and the distance between electrodes is 2.5-cm. The upper electrode serves as the power electrode, and the bottom electrode is grounded, serves as the cathode for the glow discharge. Digital clamp multimeter (UT-201) measures discharge current. The voltage between discharge electrodes is monitored by True RMS Multimeter (FLUKE-175). Digital storage oscilloscope (Tektronix TDS 2014C) attached to Pearson's current transformer has been used to monitor the shape of the discharge current. To avoid impurities not being added to the plasma during discharge the electrodes are insulated with ceramic material except the front side facing the plasma discharges. Figure 1 shows the schematic diagram of the experimental setup along with the optical components of the diagnostic system. The chamber has four vacuum-tight multi-purposes ports. The optical fiber coupled with Ocean HR 2000 + high-resolution spectrometer is used to collect and record the optical emission spectrum for wavelength characterization in the range is from 248 to 465 nm. It provides a line of sight measurement of the light emission from the plasma glow region. A rotary vane pump is coupled to one of the ports and has been used to get pressure down in the plasma chamber to working level. Another port connects Bayard-Alpert Pirani Gauge FRG-720 coupled with a pressure-displaying unit to monitor the working pressure inside the plasma chamber during the plasma generation and characterization. The third port is used to enter the nitrogen gas in the vacuum chamber in a controlled way. A matching network is an essential part of the plasma generation system and helps to couple maximum RF power to plasma discharge by minimizing the power reflection. Its function is basically to equalize the output impedance of the generator to the load of the varying discharge that changes with the discharge conditions. Therefore, it seems necessary to add an auto-matching network between the RF generator and dc-electrode plasma discharge for the efficient coupling of 13.56 MHz RF power that generates the plasma between two disk-like electrodes housed in the glass chamber. The RF generator is manufactured by Plasma Technology Ltd for Lab experiments.

Spectrum analysis and evaluation of plasma parameters
The corona model is quite a satisfactory approach to determine the electron temperature (T e ) and number density (n e ) in the low temperature and low-density non-LTE plasmas. Herein the electron temperature, ion temperature, and temperature of neutral particles follow the relation (T e > T i > T n ). For the nitrogen, the main part of the observed spectra belongs to the second positive system, which results from the transition the upper state and having higher energy than B 3 Π u (lower state) [15]. The main reaction pathway involving the electron impact excitation from the ground state N 2 (X, = 0) to the excited state N 2 C, ′ is as follows [15][16][17] Subsequently, the radiative de-excitation is given by For the specific C, ′ → B, ′′ transition, the emission intensity of the second positive system is stated as [6,18].
where n n 2 represent the number density of N 2 (X, = 0) , the n e is the number density of electrons, X C X T e is the excitation rate coefficient for electron impact excitation, A CB is the Einstein coefficient and C(λ) is the spectral response of spectrometer at specific wavelength λ [18]. The other major part of nitrogen spectra is the first negative system mentioned early. The positive ion of nitrogen N + 2 B, can also be produced through electron impact ionization either by direct or step-wise following the channels is given by [19,20] The pathway of radiative de-excitation of N + 2 B, � state is described as [21] The resulting emission intensity of N + band is stated as [18] The emission spectra of the first negative system the spectra of the second positive system have different bands of vibrational transitions ( Δ ), that are Δ = 1, Δ = 0,Δ = -1, Δ = − 2, Δ = − 3, and Δ = − 4 as shown in Fig. 2 [22]. The sequential intensity of vibrational bands of the second positive system N 2 (C 3 Π u → B 3 Π g ) is related to the population density of the respective state as below [23,29].
where I ′ ′′ is the emission intensity between two vibrational levels, ′ and ′′ while ′ is the upper vibrational level and ′′ is the lower vibrational level, C(λ) is for the spectral response of spectrometer,A ′ ′′ is the transition probability or Einstein coefficient and λ is the respective wavelength.
If we evaluate the emission intensity of each band of the specific wavelength and know the value of each corresponding constant, it is very easy to find the value of the respective excited state population N, ′ [1]. The labeling and intensity distributions of emission bands/lines in the experimental spectrums for the first negative system N + 2 (B − X) and the second positive system N 2 (C − B) are presented in Fig. 2. Figure 3 shows the emission of second positive band system for vibrational transitions Δ = − 2 observed at different nitrogen pressure and RF power. The band for Δ = − 2 at different pressure and power is shown in Fig. 3. In this band, we can see four emission line . The spectra at different nitrogen fill pressures varying from 0.1 to 1 mbar at constant RF power 80 W, and frequency 13.56 MHz are presented in Fig. 3. The spectral lines at 0.4 mbar, 0.6 mbar, and 0.8 mbar are shown in Fig. 3a. Alternatively, we recorded the intensities of these spectral lines at different values of RF power that is from 10 to 100 W with the difference of 10 W at constant pressure 1 mbar and frequency 13.56 MHz. Some observed intensities of these spectral lines at different power that is 40 W, 70 W and 100 W are shown in Fig. 3b. The vibrational temperature T is estimated by using two different methods, one is the Boltzmann plot method while the other one is the line-ratio method. Here it is assumed that the plasma particles are in a steady state so excited states follow the Boltzmann distribution. For the Boltzmann plot method, the population densities of the upper excited state of N 2 (C − B ) band that is N 2 (C, ′ ) versus corresponding vibrational energies G( ′ ) is plotted to determine the slope.
The populations' densities have been inferred from the measured intensities of selected bands using relation 3. The values of wavelength, transition probabilities, and vibrational term values are given in Table 1 Fig. 3a and for different RF power are shown in Fig. 3b.
Here, c is the speed of light that is 3 × 10 8 ms −1 , h is Planck's constant E ′ is the vibrational energy of upper excited state N 2 (C, ′ ), e and e x e are Herzberg's vibrational constant [12]. Figure 4 shows that the Boltzmann plot results in an almost straight line suggesting the EEDF behaves as Maxwellian. Accordingly, the vibrational temperature can be readily evaluated from the slope of the Boltzmann plots on a semi-log scale. During the analysis of the population densities, the role of the metastable states has been neglected owing to their small concentration in the discharge. Another method simple in vogue for the calculation of vibrational temperature is the line-ratio method.
Because in low-density plasma, the dominant pathway of the excitation is only electron impact and the effect of cascading is not considered important for populating of N 2 (C, ′ ) state [15]. So it seems convenient and reliable to use the line-ratio method for the calculation of vibrational temperature [27]. Equation 3 can be written as, The intensity ratio of two bands belonging to the second positive system N 2 (C 3 Π u → B 3 Π u ) at the wavelength 371 nm and 380.5 nm are used to determine the vibrational temperature via a line-ratio method. The relation for intensity ratio can be easily derived using Eq. 5 while incorporating the values of known spectroscopic constants given in Table 1. OES is a widely used diagnostic tool for measuring the electron temperature (T e ) and electron number density (n e ) in industrial plasmas. There are different methods to determine the T e and n e from the intensity distribution of the measured spectrum. Here the line-ratio method that uses the intensities of two selected emission bands of RF nitrogen plasma is analyzed for electron temperature. For line-ratio method, it is assumed that the electrons' velocity distribution is Maxwellian, and the excitation from the ground states to upper states follows the Boltzmann distribution [28][29][30]. However, in low-pressure RF discharges, there is some deviation from the Maxwellian behavior due to inefficient collisional transfer from electrons to other plasma species to equilibrate their temperatures. Despite this fact, the evaluation of electron temperature from the line intensities with different excitation energy thresholds represents an energy scan of the electrons. Because in low electron density plasmas, the corona model is generally applicable that assumes the population of the upper levels mainly by the direct electron impact excitation without any multi-stage excitation and the de-excitation radiative. Consequently, the electron temperature is sensitive to the relative intensity of two spectral lines having different excitation energy thresholds. Therefore, the line-ratio method gives reasonably accurate results in the case of low electron density, non-LTE plasmas with some deviation from Maxwellian EEDF [18,30]. Explicitly the final relation comes as: Here I 1 and the I 2 is the intensity of the selected bands from the second positive and the first positive systems at wavelengths 375.4 nm, and 391.44 nm, respectively, λ is the wavelength, E is excitation energy, g is statistical weight, and A is transition probability. We measured the electron temperature and number density at different values of nitrogen pressure ranging from 0.1 mbar to 1 mbar at fixed power 80 W, and different values of RF power ranging from 10 to 100 W at fixed pressure 1 mbar. To determine the electron number density, we used the ratio of two emission bands at 391.44 nm from N + 2 (B − X) and the other one is at 380.5 nm from N 2 (C − B) [29, 30].

Result and discussion
In RF discharges, plasma species get excited to the higher energy states owing to electron impact excitation and then de-excite to a lower energy state by emitting a photon of characteristic energy and wavelength. Using OES, it is very affectionate to characterize the particular emission lines/bands present in the emission spectrum and consequently the energy of charged particles the plasma composition. Hence, OES provides detailed information on the excitation and ionization processes involved in the optical emission of different molecules, atoms, and their ions. The intensities of emission lines may be related to the population densities of respective excited states safely if the concentration of metastable states in the discharge is negligible. If the transitions have a different threshold of excitation energies, they encompass different energy groups of electrons for electron impact excitation. As a result, any change in the emission intensity-ratio suggests a variation in the EEDF, and corresponding vibrational and electron temperatures. However, the analysis becomes more difficult in the presence of a large number of metastable states. Figure 2 shows the emission lines of the band head of the first negative system N + 2 (B − X ) at 391.44 nm and the band head of the second positive system N 2 (C − B) at 380.5 nm for different nitrogen fill pressure and RF power. The intensity of spectral bands increases with increasing RF power and similarly for nitrogen fill pressure. However, the increase in the intensity of the first negative system N + 2 (B − X ) at 391.44 nm is more apparent relative to the second positive system N 2 (C − B) at 380.5 nm with RF power. The discharge parameters actuality has a great influence on the shape of the EEDF, and consequently on the population densities of excited state such as N + 2 B, � and N 2 (C, ′ ). The excita- state. All these factors affect the determination process of vibrational temperature, electron temperature, and electron number density. Figure 3 shows the dependence of emission spectra of N 2 second positive band system N 2 (C,-B)  ). Figure 4 shows the Boltzmann plot at different nitrogen fill pressure RF power and presents the relative population of the upper state N 2 (C, � ) against the vibrational energy term on a semi-log scale. Because the intensity of the band resulted from the transition between two vibrational levels with sequence Δ = − 2 can be measured and all the constants are known, it is possible to obtain the relative population of the upper states from the respective intensities. The slope of the Boltzmann plot gives the vibrational temperature at different nitrogen pressure, and RF power when other corresponding discharge parameters kept constant. Figure 5a shows the variation of vibrational temperature with nitrogen fill pressure. The values of nitrogen pressure are varied from 0.1 mbar to 1 mbar in regular steps by fixing RF power at the level of 80 W at a frequency of 13.56 MHz. The vibrational temperature has been obtained using the line-ratio and Boltzmann plot methods. The values of vibrational temperature with fill pressure vary from 0.78 to 0.39 eV in decreasing order for Boltzmann plot method, and from 0.99 to 0.51 eV in decreasing order for line ratio method. Figure 5b demonstrates the effect of increasing power from 10 to 100 W at a pressure of 1 mbar on the vibrational temperature. The values of vibrational temperature show the decreasing trend for the both Boltzmann plot, and for the line-ratio methods. This fact may be attributed to the collisional relaxation of nitrogen molecule at higher gas pressure, and fast quenching which causes the reduction of vibrational temperature. The values vary from 0.56 to 0.36 eV for the Boltzmann plot method, and 0.88-0.53 eV for the line-ratio method, respectively. The value of T measured from the line-ratio method is somewhat higher than the value of T estimated from the Boltzmann plot method. It is because the line-ratio method involves only the intensity contribution of two spectral lines (smaller group of the electrons) while the Boltzmann plot method involves the contribution from several spectral lines. Therefore, the Boltzmann plot method represents more shares of | https://doi.org/10.1007/s42452-021-04651-z the electrons present in the EEDF compared with the line-ratio method which represents a smaller group of electrons, and measures the vibrational temperature more accurately. Figure 6a demonstrates the relationship between nitrogen fill pressure and the corresponding electron temperature T e at the given value of the RF power. The electron temperature is determined by the line-ratio method that uses the relative intensity ratio of the molecular bands corresponding to N + 2 (B, − X , � , 391.44 nm), and, N 2 (C, � − B, �� , 375.4 nm), transitions, and known spectroscopic constants. The results show that the T e continuously decreases with increasing nitrogen fill pressure. This outcome can be explained as follows: When the working pressure of nitrogen increases, it shorten the mean free path and increases the collisional frequency among the discharge particles. As a result of an effective collisional transfer of energy, the electrons are cool down, causing a reduction in electron temperature. Figure 6b shows the increasing trend of electron temperature versus the RF power. This is because the electrons receive more energy at a higher value of the RF field at higher input power and transfer to the plasma species through the collisional process. The collisional process increases the population density of the emitting states and consequently the intensity of the spectral lines. The electron temperature is related to the population density of the excited-states involved in the optical emission process, subject to the multi-stage excitation/de-excitation is negligible. The high-energy electrons having energies above the excitation thresholds contribute to the excitation/ionization of the plasma species via inelastic collisions. The excitation rate coefficient is the function of the electron energy and the electron number density. Therefore, with increasing RF powers, the inelastic collisions between high-energy electrons and plasma particles increase producing more, ion-electron pairs, and excited plasma The variation of T e with RF power species. As a result of the dissipation of electron energy, the electrons are relatively cooled and reduce the tail of the EEDF. However, both the electron temperature and the electron density increase with RF power due to the continuous absorption of RF power compensating the energy loss of the electrons. Figure 7a shows the variation of the electron density with varying nitrogen fill pressure at constant RF power. As nitrogen fills pressure increases, it causes an increase in the rate of collisions among the electrons and the other plasma species. Consequently, the collisional transfer of energy by way of the electron impact ionization results in charge multiplication. Therefore, as a result of charge multiplication, the electron density increases while the electron temperature decreases due to the energy loss of the electrons by the collisional processes. Figure 7b shows the variation of the electron density with changing RF power when the fill pressure is kept constant. The plot again shows an increase in the number density attributed to the electron heating at higher RF powers that result in a higher ionization rate. Actually, with increasing RF power, the electron impact ionization process produces more ions and electrons and therefore increases the electron number density. However, in this case, the electron temperature also increases owing to compensation of energy loss of electrons involving in the collisional process due to their continuous RF heating.

Conclusions
In this work, capacitively coupled radio frequency nitrogen plasma at a fixed 13.6 MHz frequency has been generated and subsequently investigated for plasma parameters using optical emission spectroscopy. The emission intensity of the selected spectral lines/bands has been analyzed to evaluate the vibrational temperature T , electron temperature T e , and electron number density n e at different nitrogen fill pressure (0.1 to 1 mbar) and radio frequency power (10-100 W) by keeping the other corresponding parameters fixed. First, we used the population density for the measurement of vibrational temperature via both the line-ratio and the Boltzmann plot methods. The values of the vibrational temperature obtained from the line-ratio method are slightly higher than the Boltzmann plot method. The difference may be because the line-ratio method considers only the intensity of the two spectral lines and thus represents a narrow segment of the electron energy distribution function contributing to the selected optical transitions. Whereas the Boltzmann plots method uses the intensity of the several spectral lines instead of two lines and thus represents a broadened segment of the electron energy distribution function taking part in the optical transitions. The ratio of the intensity of nitrogen molecular ion N + 2 (B, 0 − X, 0) at 391.44 nm and molecule N 2 (C, 0 − B, 0 ) at 375.4 nm has been taken into account for the quantification of T e . For n e , the intensity ratio of nitrogen ion N + 2 (B, 0 − X, 0) at 391.44 nm and nitrogen molecule N 2 (C, 0 − B, 2 ) at 380.5 nm has been used along with spectroscopic constants. The results show that with increasing radio frequency power both n e and T e increases but T reduces . The increase in T e and decrease in T with increasing RF power may be explained by the fact that electronic excitation is more sensitive to highenergy electrons compared with vibrational excitation. At the higher value of RF power, the EEDF shifts to higher energies reducing the number of low energy electrons responsible for the vibrational excitations. Consequently, the vibrational temperature decreases relative to electron temperature. On the other hand, with increasing nitrogen fill pressure n e increases but both T and T e decrease.
Acknowledgements The authors thank the team of the Pakistan TOKAMAK Plasma Research Institute for their cooperation and support. The authors declare that accepted principles of ethical and professional conduct have been followed in this research. Moreover, there are no potential conflicts of interest (financial or non-financial) and the research involves the human participants with consent and does not involve animals.

Declarations
Conflict of interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
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