Experimental study of the addition of oil palm mesocarp fiber on the physical and mechanical properties of fiber cement mortar composites

Composite materials based on natural fibers are increasing in demand in various sectors of industry because of their interesting specific properties. This work is a contribution to the valorization, of plant fibers from agricultural plantations in Cameroon, in fiber cement mortar (FCM). This paper studies the influence of the addition of oil palm mesocarp fiber (OPMF) on the physical (water absorption, density and compactness) and mechanical (compressive strength and flexural strength) properties of cement mortars. The fibers used in this paper are extracted from oil palm mesocarp (palm kernel pulp) by a mechanical and manual process. Cement mortar specimens were then made with different proportions of fibers: 0% (reference mortar), 1%, 2%, 3% and 3.5% fibers. Physical and mechanical tests are then carried out on our specimens. Regardless of the duration of immersion in water, the results show that the water absorption rate increases with a greater amount of fiber in the FCM specimens. On the other hand, an inverse effect is observed on density, which decreases from 2277.5 (samples with 0% fiber) to 942.1 kg/m3 (samples with 3.5% fiber) for apparent density and from 2641.2 to 1945.7 kg/m3 for absolute density. On the mechanical properties, there is a steady decrease in compressive strength from 42.47 (for the reference mortar at 0% fiber) to 31.1 MPa (for the sample at 3.5% fiber). In bending, there is first an increase and then a decrease in strength with the amount of fibers. The maximum flexural strength is obtained for a 2% fiber composition. The FCM has a better strength/density ratio. Finally, the addition of OPMF, in small proportion in the cement mortar, allows a lightening of the structure, but induces a small decrease in mechanical resistance. Our FCM can be used in the manufacture of cinderblocks or as internal wall roughcoating mortar.


Introduction
Cement mortar reinforced with fiber is applied in the domain of infrastructure, renovation works and building of houses [1][2][3][4]. The uniqueness of its mixture makes this mortar a material with good mechanical characteristics especially in terms of durability. This mortar is made up of synthetic fibers, cements and siliceous sands. A reduction in natural deposits especially oil and an increase in the knowledge of pollution from the application of synthetic fibers [5,6] has increased an interest in fibers from natural origin, renewable and biodegradable resources. For business purposes, studies done on fibers are mainly concerned with industrially produced plants like flax, hemp, palm kernel, cotton, banana, etc. [7][8][9].
Composites reinforced with natural fibers occupy among the highest area of research nowadays. Çomak et al. [10] have evaluated the effects of hemp fibers on the characteristics of mortar from cement. In their studies, they mixed cement mortar with hemp fiber in different formulations (0%, 1%, 2% and 3%) and lengths (6 mm, 12 mm and 18 mm). From their results, they proved that, 12 mm lengths, reinforced with 2-3% cement mortars provided the most important results. Danso et al. [11] studied the influence of lime and fibers of coconut on the properties of cement-soil mortar. From their studies they concluded that coconut fibers and lime positively affect the characteristics of cement-soil mortars for use with the highest strength noted at 0.2% fiber and 5% lime addition on the sample.
Kesikidou et al. [12] have carried out studies on natural fiber reinforced mortars and the results gave more lights on the application of natural (bio) fibers in construction materials to promote the reuse of bio-fibers in the construction sector. In their studies, they used three types of vegetal fibers (coconut, kelp and jute) as additives and 1.5% mortar by volume. Ramakrishna et al. [13] carried out studies on the effects of natural fiber-reinforced cement mortar slabs and proved that adding coconut fibers from 0.5 to 2.5% highly increased the impact resistance of slabs. Vantadori et al. [14] studied date palm fibers-reinforced mortars and concluded that adding the quantity of fiber increased the ratio of ductility and weight of the cement mortar.
Vegetal fibers used in this paper are oil palm mesocarp fiber from Cameroon, precisely from the West Region and are extracted from the specie of palm oil called E-Elaeis guineensis using a set of procedures having several steps; mechanical washing and drying [15]. Palm oil is responsible for a very important part of activities in the agricultural sector in Cameroon. It is mostly planted for the oil of its nuts. Waste like husk from rice and mesocarp fibers from palm oil are mostly thrown into the wild or burnt. The study in this paper seeks to look at ways to give value to this waste so as to offer cultivators an added economic advantage. Normally, the domain of construction has to promote the valorization of biomass fibers and recycling in a quest to solve problems linked to the environment. In Africa, vegetal fiber-reinforced earth mortars still have a wide application in the construction sector (cob, adobe, etc.). However, the mortar matrix from cement remains the basic building material in towns.
In this article, the focus is on the possibility of using oil palm nut fibers from Cameroon to reinforce cement mortars in order to produce cinderblocks as a sustainable replacement for conventional cinderblocks. The aim of the study is to evaluate the influence of adding oil palm mesocarp fiber (OPMF) on the mechanical characteristics of cement mortar. We start by forming reinforced fiber cement mortar samples following recommended standards. The fiber content of OPMF in FCM ranges from 0 to 3.5%.

Materials
The natural fibers that are the subject of this manuscript come from the oil palm, variety E Elaeis guineensis, from the town of BAZOU, West Region of Cameroon (Fig. 1). The fibers valued in this study are extracted from oil palm mesocarp fiber (OPMF) (Fig. 1d).
A hydraulic press is used to extract oil from the OPMF. At the exit of the press, the oilcake is made of a very dense mixture of fibers and palm nut (Fig. 2a). The fibers, which are manually cleared from the nuts and some pulp particles, are washed at a temperature of 70 °C and then dried (Fig. 2b, c). Figure 2 shows the pictures of the oilcake and the state of the fibers at different stages of extraction. The mechanical extraction process used in this paper increases the roughness of the outer surface of the fibers and contributes to a better fiber/matrix adhesion [16] (see Table 1).

Elaboration of fiber-cement mortar (FCM) sample
After removal of oil from the palm nuts, the remaining fiber waste will be used to make the FCM samples. The final product is a dimensionally standardized brick of natural short fiber-reinforced cement mortar (Fig. 3). The test specimens thus made are as follows: • Sand: River sand (YONG River) from Cameroon's Central Region (City of Mbalmayo). The sand used has a granulometry of 0/2 according to standard NF EN 196-1 (Sand 0-2 mm). • Cement: Cement type CEMI BP42.5R according to standard NC 234: 2009-06 (Manufactured by the company DANGOTE CEMENT -Cameroon). • Short fibers: Natural fibers waste from the extraction of palm nut pulp (Fiber density: 521 kg/m 3 ). • The mixing water is free of impurities in accordance with standard NF P 18-303 (Water/cement ratio = 0.6).
The FCM specimens shall be prismatic in shape and shall have a size of 40 mm × 40 mm × 160 mm (volume: 256.10-6 m 3 ) for the flexural test. The dimensions for compression test are: 40 mm × 40 mm × 80 mm. The manufacture and dimensions of the FCM specimens are carried out according to the European standard NF EN 196-1. This standard details the methodology to be followed for the preparation and determination of the mechanical properties of cement mortars. Figures 3 and 4 show respectively the stages of preparation and an image of the sample. Table 2 shows the designation and the fiber composition of the various manufactured samples.

Water absorption
The experimental protocol for measuring the water absorption of FCM samples is carried out after determining the dry mass of the specimens (drying operation in an oven at 105 °C for about 24 h). After this step, the protocol is as follows: • Immersion of the test specimen in a water tank (the samples are previously dried M 105 °C to 105 °C). • Weighing each test specimen at x-day increment: M xDay (x equal a value between 1 and 21 days).   where TA: water absorption, M 105 °C : mass of the dry test specimen (in grams) after drying at 105 °C, M xDay : mass of the specimen, after a stay of "x days" in the water tank, M sat : saturation mass (g): mass corresponding to a nearly zero mass variation (TA is maximal for M xJours = M sat ).

Density of sample
The dry density of the sample is determined following the protocol presented in the standard BS EN 771-1.The bulk density is calculated using the following standard equation (Eq. 2):

Compression machine
A numerically controlled compression machine of CON-TROLAB type, equipped with a data acquisition system, was used in this study. Using an appropriate fixation system, this device is also used for 3-point bending tests. The dimension and forms of the samples used are illustrated in the Fig. 4.

Results and discussions
In this section, we present the results and analyses of the tests carried out on specimens of fiber-reinforced cement mortar (with different amounts of fibers). Figure 5 shows the influence of the quantity of fibers on the water absorption of the different FCM samples. Regardless of the quantity of fibers in the FCM, it can be  5 3.5 seen in Fig. 5a that water absorption increases with the time of immersion in water. Beyond a period of about 5 days, this value tends towards a threshold, corresponding to water absorption at saturation. In Fig. 5b, it is clearly seen that the quantity of fiber in the specimen affects the water absorption. As the quantity of fibers in the mortar increases, the water absorption increases. In fact, the water absorption increases from 2.63% for the reference sample (0% fiber) to 4.3% for the sample containing 3.5% fibers. This observation of the influence of fibre quantity on the water absorption is confirmed by other studies in the literature. Raut et al. [17] have shown that for an increasing proportion of oil palm fibre from 0 to 1.5%, the mortar specimen has a higher water absorption. A slightly increasing water absorption, with the hemp fiber content (1-3% fiber) in the cement mortar, was also obtained by Comak [10]. Studies by Danso et al. [11] on a coconut fiberreinforced cement mortar (0-0.8% fiber) clearly show an increase in water absorption with increasing fiber content.

Influence of the quantity of fiber on the density of the FCM
This paragraph presents the study of the influence of fiber quantity on sample densities (bulk density and absolute density). Figure 6 shows the results of the variation of the density as a function of the quantity of fibers. It can be seen in Fig. 6 that densities (apparent and absolute) decrease gradually with the addition of a significant quantity of fibers to the sample. The apparent density decreases from 2277.5 kg/m 3 for the reference sample (0% fiber) to 942.1 kg/m 3 for the sample with 3.5% fibers. The absolute density decreases from 2641.2 kg/m 3 (for the 0% fibers sample) to 1945.7% (for the 3.5% fibers sample). The addition of fibers in the cement mortar makes it lighter. This shape is similar to that obtained by Vantadori [14] and Raut [17] who worked on cement mortars successively reinforced by date and oil palm fibers. In the work of Raut et al. [17], the density decreases from about 1900-1600 kg/ m 3 respectively for an increasing proportion of oil palm fiber from 0 to 1.5%. The decrease in density is partly due to the increase in porosity inherent to the cellular structure of the fibres [14].
The compactness corresponding to the ratio of the bulk density and the absolute density of the samples is calculated as shown in Fig. 7 below (Compactness = 100 * [ρ App /ρ Abs ]). The compactness as a function of the fiber load is shown in Fig. 7. We observe that the bars decrease progressively. The increase of fibers in the cement matrix tends to increase the quantity of micro vacuum in the mortar structure. The fibers are likely to absorb a certain quantity of water.

Mechanical properties
The results of the mechanical properties of FCM specimens are discussed in this section. The results in Fig. 8 are obtained from the compression test and three-point bending tests under monotonic loading until failure of the different FCM. The test specimens tested all have a maturity of 28 days. Figure 8a shows the influence of the addition of fibers on the compressive strength. A progressive decrease in compressive strength is observed from 42.4 (0% fiber mortar) to 31.1 MPa (3.5% fibers mortar). For a fiber composition of 0 and 3.5% the loss of compressive strength is about 27%. The results obtained by Comak et al. [10] show a (less regular) decrease in the compressive strength of hemp fibre-reinforced mortar. On the other hand, the work of Raut et al. [17] on FCM mortar reinforced with oil palm fibre confirms a progressive decrease in compressive strength (from 50 to 30 MPa) with the quantity of fibres in the proportions from 0 to 1.5%. Figure 8b shows  [10] show the same shape in flexural strength as a function of the hemp fibre content. Figure 9 shows a correlative evolution between the mechanical resistances (flexural and compression) and the density of the different samples of FCM. Overall from Fig. 9a, it can be seen that the mechanical properties decrease with decreasing density (despite a slight increase in flexural strength). Nevertheless, if we consider the strength-to-density ratio in Fig. 9b, we can see

Conclusion
This paper presented an experimental study of the influence of the quantity of OPMF on the physical and mechanical properties of cement mortar.
FCM test specimens, with standardized dimensions, were made containing variable proportions of short fibers of oil palm mesocarp (between 0 and 3.5% fibers). The specimens were then tested to determine certain physical (density, absorption rate) and mechanical (flexural and compressive strength) characteristics. The results showed that the addition of fibers allows a decrease in weight of the cement mortar and overall a slight decrease in mechanical resistance. However, considering the mechanical strength/density ratio, it was found that samples containing a higher proportion of fibers were superior to the reference mortar samples (0% fiber).
Acknowledgements The authors would like to thank the LABOGENIE (National Civil Engineering Laboratory) and some oil palm producers, respectively for access to their documentation and plant raw material.

Compliance with ethical standards
Conflict of interest On behalf of all authors, Christian Bopda Fokam states that there is no conflict of interest.
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