Abstract
The anticorrosive activity of Combretum indicum (CI) leaf extract has been examined on mild steel corrosion in 1M HCl by using weight loss and electrochemical measurement techniques. The results of these experimental techniques have consistent in confirming the effect of the CI leaf extract on corrosion inhibition and a mechanism for the inhibition was proposed. The dissolution rate of steel in acidic solution was found to be sensitive to the concentration of CI leaf extract and the corrosion rate reduces when the concentration of CI leaf extract is increased and reaches the high protection efficiency. The potentiodynamic polarization study confirms the mixed mode of inhibition. Ultraviolet–visible (UV) and Fourier -transform infrared (FTIR) spectroscopic techniques were performed to evaluate the phenomenon of adsorption in the plant extract and the functional groups. The surface morphology analysis (SEM) further corroborates the adsorption of inhibitor molecules over the metal surface.
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23 November 2020
In the original version of this article unfortunately column six and seven in Table 2 were wrong due to typesetting mistakes.
References
Vu NSH, Binh PMQ, Dao VA, Thu VTH, Van Hien P, Panaitescu C, Nam ND (2020) J Mol Liq. https://doi.org/10.1016/j.molliq.2020.113787
Ikhmal WMKWM, Maria MFM, Rafizah WAW, Norsani WNWM, Sabri MM (2019) Int J Corros Scale Inhib 8:628–643
Fouda AS, Eissa M, Fakih M (2019) J Bio- Tribo-Corros 5:5–17
Faiz M, Zahari A, Awang K, Hussin H (2020) RSC Adv 10:6547–6562
Sedik A, Lerari D, Salci A, Athmani S, Bachari K, Gecibesler İH, Solmaz R (2020) J Taiwan Inst Chem Eng 107:189–200
Sanaei Z, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B (2019) J Ind Eng Chem 69:18–31
Dehghani A, Bahlakeh G, Ramezanzadeh B, Ramezanzadeh M (2020) J Mol Liq. https://doi.org/10.1016/j.molliq.2019.112046
Jayakumar S, Nandakumar T, Vadivel M, Thinaharan C, George RP, Philip J (2020) J Adhes Sci Technol 34:713–743
Ferdosi Heragh M, Tavakoli H (2019) Met Mater Int. https://doi.org/10.1007/s12540-019-00453-6
Alibakhshi E, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B, Mahdavian M, Motamedi M (2018) J Mol Liq 255:185–198
Qiang Y, Zhang S (2018) TanB, Chen S. Corros Sci 133:6–16
Baran E, Cakir A, Yazici B (2019) Arab J Chem 12:4303–4319
Mbah CN, Onah CC, Nnakwo KC (2020) Eng Res Express 2:015039–015051
Akinbulumo OA, Odejobi OJ, Odekanle EL (2020) Results Mater 5:100074–100080
Okewale AO, Adesina OA (2020) J Appl Sci Environ Manag 24:37–47
Bhuvaneswari TK, Jeyaprabha C, Arulmathi P (2020) J Adhes Sci Technol. https://doi.org/10.1080/01694243.2020.1766395
Bhardwaj N, Prasad D, Haldhar R (2018) J Bio- Tribo-Corros 4:61–70
Li D, Zhang P, Guo X, Zhao X, Xu Y (2019) RSC Adv 9:40997–41009
Haldhar R, Prasad D, Saxena A (2018) J Environ Chem Eng 6:5230–5238
Boumhara K, Harhar H, Tabyaoui M, Bellaouchou A, Guenbour A, Zarrouk A (2019) J Bio- Tribo-Corros 5:8–16
Ezeamaku UL, Iheaturu NC, Chike KO, Onukwuli OD (2019) Int J Adv Res Chem Sci 6:1–9
Vasanthajothi R, Saratha R, Krishnaveni K (2020) J Adhes Sci Technol. https://doi.org/10.1080/01694243.2020.1801248
Bhuiya NMA (2020) Int J Green Pharm (IJGP) 14:169–174
Anupama KK, Joseph A (2018) J Bio- Tribo-Corros 4:30–43
Fernandes CM, Fagundes TDSF, dos Santos NE, Rocha TSDM, Garrett R, Borges RM, Muricy G, Valverde AL, Ponzio EA (2019) Electrochim Acta 312:137–148
Boudjellal F, Ouici HB, Guendouzi A, Benali O, Sehmi A (2020) J Mol Struct 1199:127051–127063
Singh A, Ansari KR, Chauhan DS, Quraishi MA, Lgaz H, Chung IM (2020) J Colloid Interface Sci 560:225–236
Rbaa M, Lgaz H, El Kacimi Y, Lakhrissi B, Bentiss F, Zarrouk A (2018) Mater Discov 12:43–54
Berrissoul A, Ouarhach A, Benhiba F, Romane A, Zarrouk A, Guenbour A, Dikici B, Dafali A (2020) J Mol Liq 313:113493–113508
Dehghani A, Bahlakeh G, Ramezanzadeh B, Ramezanzadeh M (2019) J Mol Liq 277:895–911
Chaouiki A, Chafiq M, Lgaz H, Al-Hadeethi MR, Ali IH, Masroor S, Chung IM (2020) Coatings 10:640–656
Dohare P, Quraishi MA, Obot IB (2018) J Chem Sci 130:8–26
Haldhar R, Prasad D, Saxena A, Kumar R (2018) Sustain Chem Pharm 9:95–105
Bhuvaneswari TK, Vasantha VS, Jeyaprabha C (2018) Silicon 10:1793–1807
Khattabi M, Benhiba F, Tabti S, Djedouani A, El Assyry A, Touzani R, Warad I, Oudda H, Zarrouk A (2019) J Mol Struct 1196:231–244
Saxena A, Prasad D, Haldhar R, Singh G, Kumar A (2018) J Environ Chem Eng 6:694–700
Thomas A, Prajila M, Shainy KM, Joseph A (2020) J Mol Liq 312:113369–113381
Bahlakeh G, Dehghani A, Ramezanzadeh B, Ramezanzadeh M (2019) J Mol Liq 293:111559–111574
Haque J, Ansari KR, Srivastava V, Quraishi MA, Obot IB (2017) J Ind Eng Chem 49:176–188
Fouda AEAS, Shahba RMA, El-Shenawy AE, Seyam TJA (2018) Int J Electrochem Sci 13:7057–7075
Barrahi M, Elhartiti H, El Mostaphi A, Chahboun N, Saadouni M, Salghi R, Zarrouk A, Ouhssine M (2019) Int J Corros Scale Inhib 8:937–953
Mobin M, Aslam R, Aslam J (2017) Mater Chem Phys 191:151–167
Ahmed SK, Ali WB, Khadom AA (2019) Int J Ind Chem 10:159–173
Saxena A, Prasad D, Haldhar R (2018) J Mater Sci 53:8523–8535
Ojha LK, Tüzün B, Bhawsar J (2020) J Bio- Tribo-Corros 6:1–10
Anyiam CK, Ogbobe O, Oguzie EE, Madufor IC, Nwanonenyi SC, Onuegbu GC, Obasi HC, Chidiebere MA (2020) SN Appl Sci 2:520–530
Emori W, Zhang RH, Okafor PC, Zheng XW, He T, Wei K, Lin XZ, Cheng CR (2020) Colloids Surf, A 590:124534–124546
Acknowledgements
Authors gratefully acknowledge the support of Dr. Arun M Isloor and Dr. A Nityananda Shetty of National Institute of Technology Karnataka for providing instrumental facility to carry out electrochemical studies
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The original online version of this article was revised: In the original version of this article unfortunately columns six and seven in Table 2 were wrong due to typesetting mistakes.
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Neriyana, P.S., Alva, V.D...P. A Green Approach: Evaluation of Combretum indicum (CI) Leaf Extract as an Eco-friendly Corrosion Inhibitor for Mild Steel in 1M HCl. Chemistry Africa 3, 1087–1098 (2020). https://doi.org/10.1007/s42250-020-00190-z
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DOI: https://doi.org/10.1007/s42250-020-00190-z