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A Green Approach: Evaluation of Combretum indicum (CI) Leaf Extract as an Eco-friendly Corrosion Inhibitor for Mild Steel in 1M HCl

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A Publisher Correction to this article was published on 23 November 2020

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Abstract

The anticorrosive activity of Combretum indicum (CI) leaf extract has been examined on mild steel corrosion in 1M HCl by using weight loss and electrochemical measurement techniques. The results of these experimental techniques have consistent in confirming the effect of the CI leaf extract on corrosion inhibition and a mechanism for the inhibition was proposed. The dissolution rate of steel in acidic solution was found to be sensitive to the concentration of CI leaf extract and the corrosion rate reduces when the concentration of CI leaf extract is increased and reaches the high protection efficiency. The potentiodynamic polarization study confirms the mixed mode of inhibition. Ultraviolet–visible (UV) and Fourier -transform infrared (FTIR) spectroscopic techniques were performed to evaluate the phenomenon of adsorption in the plant extract and the functional groups. The surface morphology analysis (SEM) further corroborates the adsorption of inhibitor molecules over the metal surface.

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  • 23 November 2020

    In the original version of this article unfortunately column six and seven in Table 2 were wrong due to typesetting mistakes.

References

  1. Vu NSH, Binh PMQ, Dao VA, Thu VTH, Van Hien P, Panaitescu C, Nam ND (2020) J Mol Liq. https://doi.org/10.1016/j.molliq.2020.113787

    Article  Google Scholar 

  2. Ikhmal WMKWM, Maria MFM, Rafizah WAW, Norsani WNWM, Sabri MM (2019) Int J Corros Scale Inhib 8:628–643

    CAS  Google Scholar 

  3. Fouda AS, Eissa M, Fakih M (2019) J Bio- Tribo-Corros 5:5–17

    Google Scholar 

  4. Faiz M, Zahari A, Awang K, Hussin H (2020) RSC Adv 10:6547–6562

    CAS  Google Scholar 

  5. Sedik A, Lerari D, Salci A, Athmani S, Bachari K, Gecibesler İH, Solmaz R (2020) J Taiwan Inst Chem Eng 107:189–200

    CAS  Google Scholar 

  6. Sanaei Z, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B (2019) J Ind Eng Chem 69:18–31

    CAS  Google Scholar 

  7. Dehghani A, Bahlakeh G, Ramezanzadeh B, Ramezanzadeh M (2020) J Mol Liq. https://doi.org/10.1016/j.molliq.2019.112046

    Article  Google Scholar 

  8. Jayakumar S, Nandakumar T, Vadivel M, Thinaharan C, George RP, Philip J (2020) J Adhes Sci Technol 34:713–743

    CAS  Google Scholar 

  9. Ferdosi Heragh M, Tavakoli H (2019) Met Mater Int. https://doi.org/10.1007/s12540-019-00453-6

    Article  Google Scholar 

  10. Alibakhshi E, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B, Mahdavian M, Motamedi M (2018) J Mol Liq 255:185–198

    CAS  Google Scholar 

  11. Qiang Y, Zhang S (2018) TanB, Chen S. Corros Sci 133:6–16

    CAS  Google Scholar 

  12. Baran E, Cakir A, Yazici B (2019) Arab J Chem 12:4303–4319

    CAS  Google Scholar 

  13. Mbah CN, Onah CC, Nnakwo KC (2020) Eng Res Express 2:015039–015051

    Google Scholar 

  14. Akinbulumo OA, Odejobi OJ, Odekanle EL (2020) Results Mater 5:100074–100080

    Google Scholar 

  15. Okewale AO, Adesina OA (2020) J Appl Sci Environ Manag 24:37–47

    Google Scholar 

  16. Bhuvaneswari TK, Jeyaprabha C, Arulmathi P (2020) J Adhes Sci Technol. https://doi.org/10.1080/01694243.2020.1766395

    Article  Google Scholar 

  17. Bhardwaj N, Prasad D, Haldhar R (2018) J Bio- Tribo-Corros 4:61–70

    Google Scholar 

  18. Li D, Zhang P, Guo X, Zhao X, Xu Y (2019) RSC Adv 9:40997–41009

    CAS  Google Scholar 

  19. Haldhar R, Prasad D, Saxena A (2018) J Environ Chem Eng 6:5230–5238

    CAS  Google Scholar 

  20. Boumhara K, Harhar H, Tabyaoui M, Bellaouchou A, Guenbour A, Zarrouk A (2019) J Bio- Tribo-Corros 5:8–16

    Google Scholar 

  21. Ezeamaku UL, Iheaturu NC, Chike KO, Onukwuli OD (2019) Int J Adv Res Chem Sci 6:1–9

    Google Scholar 

  22. Vasanthajothi R, Saratha R, Krishnaveni K (2020) J Adhes Sci Technol. https://doi.org/10.1080/01694243.2020.1801248

    Article  Google Scholar 

  23. Bhuiya NMA (2020) Int J Green Pharm (IJGP) 14:169–174

    Google Scholar 

  24. Anupama KK, Joseph A (2018) J Bio- Tribo-Corros 4:30–43

    Google Scholar 

  25. Fernandes CM, Fagundes TDSF, dos Santos NE, Rocha TSDM, Garrett R, Borges RM, Muricy G, Valverde AL, Ponzio EA (2019) Electrochim Acta 312:137–148

    CAS  Google Scholar 

  26. Boudjellal F, Ouici HB, Guendouzi A, Benali O, Sehmi A (2020) J Mol Struct 1199:127051–127063

    CAS  Google Scholar 

  27. Singh A, Ansari KR, Chauhan DS, Quraishi MA, Lgaz H, Chung IM (2020) J Colloid Interface Sci 560:225–236

    CAS  Google Scholar 

  28. Rbaa M, Lgaz H, El Kacimi Y, Lakhrissi B, Bentiss F, Zarrouk A (2018) Mater Discov 12:43–54

    Google Scholar 

  29. Berrissoul A, Ouarhach A, Benhiba F, Romane A, Zarrouk A, Guenbour A, Dikici B, Dafali A (2020) J Mol Liq 313:113493–113508

    CAS  Google Scholar 

  30. Dehghani A, Bahlakeh G, Ramezanzadeh B, Ramezanzadeh M (2019) J Mol Liq 277:895–911

    CAS  Google Scholar 

  31. Chaouiki A, Chafiq M, Lgaz H, Al-Hadeethi MR, Ali IH, Masroor S, Chung IM (2020) Coatings 10:640–656

    CAS  Google Scholar 

  32. Dohare P, Quraishi MA, Obot IB (2018) J Chem Sci 130:8–26

    Google Scholar 

  33. Haldhar R, Prasad D, Saxena A, Kumar R (2018) Sustain Chem Pharm 9:95–105

    Google Scholar 

  34. Bhuvaneswari TK, Vasantha VS, Jeyaprabha C (2018) Silicon 10:1793–1807

    CAS  Google Scholar 

  35. Khattabi M, Benhiba F, Tabti S, Djedouani A, El Assyry A, Touzani R, Warad I, Oudda H, Zarrouk A (2019) J Mol Struct 1196:231–244

    CAS  Google Scholar 

  36. Saxena A, Prasad D, Haldhar R, Singh G, Kumar A (2018) J Environ Chem Eng 6:694–700

    CAS  Google Scholar 

  37. Thomas A, Prajila M, Shainy KM, Joseph A (2020) J Mol Liq 312:113369–113381

    CAS  Google Scholar 

  38. Bahlakeh G, Dehghani A, Ramezanzadeh B, Ramezanzadeh M (2019) J Mol Liq 293:111559–111574

    CAS  Google Scholar 

  39. Haque J, Ansari KR, Srivastava V, Quraishi MA, Obot IB (2017) J Ind Eng Chem 49:176–188

    CAS  Google Scholar 

  40. Fouda AEAS, Shahba RMA, El-Shenawy AE, Seyam TJA (2018) Int J Electrochem Sci 13:7057–7075

    CAS  Google Scholar 

  41. Barrahi M, Elhartiti H, El Mostaphi A, Chahboun N, Saadouni M, Salghi R, Zarrouk A, Ouhssine M (2019) Int J Corros Scale Inhib 8:937–953

    CAS  Google Scholar 

  42. Mobin M, Aslam R, Aslam J (2017) Mater Chem Phys 191:151–167

    CAS  Google Scholar 

  43. Ahmed SK, Ali WB, Khadom AA (2019) Int J Ind Chem 10:159–173

    CAS  Google Scholar 

  44. Saxena A, Prasad D, Haldhar R (2018) J Mater Sci 53:8523–8535

    CAS  Google Scholar 

  45. Ojha LK, Tüzün B, Bhawsar J (2020) J Bio- Tribo-Corros 6:1–10

    Google Scholar 

  46. Anyiam CK, Ogbobe O, Oguzie EE, Madufor IC, Nwanonenyi SC, Onuegbu GC, Obasi HC, Chidiebere MA (2020) SN Appl Sci 2:520–530

    CAS  Google Scholar 

  47. Emori W, Zhang RH, Okafor PC, Zheng XW, He T, Wei K, Lin XZ, Cheng CR (2020) Colloids Surf, A 590:124534–124546

    CAS  Google Scholar 

Download references

Acknowledgements

Authors gratefully acknowledge the support of Dr. Arun M Isloor and Dr. A Nityananda Shetty of National Institute of Technology Karnataka for providing instrumental facility to carry out electrochemical studies

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Correspondence to Vijaya D . P. Alva.

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The original online version of this article was revised: In the original version of this article unfortunately columns six and seven in Table 2 were wrong due to typesetting mistakes.

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Neriyana, P.S., Alva, V.D...P. A Green Approach: Evaluation of Combretum indicum (CI) Leaf Extract as an Eco-friendly Corrosion Inhibitor for Mild Steel in 1M HCl. Chemistry Africa 3, 1087–1098 (2020). https://doi.org/10.1007/s42250-020-00190-z

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