Low-temperature atmospheric discharge plasma and its applications for the surface treatment

The atmospheric pressure low-temperature homogeneous discharge using helium and nitrogen, both known for industrial applications, was reviewed. In case of helium, metastable atoms (21s and 23s) produced in the glow discharge were able to dissociate mixed molecular gases to produce radicals or atoms. Radical species undergo chemical reactions, such as oxidation or nitration reaction and form products on the electrode surfaces. Applications of helium atmospheric pressure glow discharge including surface treatment of plastic films to enhance adhesibility with glue, weakening strength with pressure-sensitive glue, and deposition of solid material on a flat plate or powder surfaces, were described. Moreover, the microwave low-temperature discharge using nitrogen, as a cost-saving carrier gas, were introduced for the surface cleaning of silicon wafer.


Introduction to the Atmospheric Pressure Glow Discharge (APGD)
Plasma chemical vapor deposition (CVD) and etching or surface treatment using glow discharge in low pressure are experimental techniques widely applied in hightechnology research industries. However, there is yet for commercial use since the operations are done in a vacuum system thus the apparatus will be extraordinarily expensive. Therefore, plasma application, such as the surface treatment on largesized film materials in low pressure was not so easy in practice. In the same way, the reason of the maintenance difficulty at the pumping system, the surface treatment of powder will be also difficult to treat in low pressure discharge system. The plasma CVD and surface treatment or powder treatment at atmospheric pressure are a promising approach for not only a reduction of costs for mass-production systems but also to add a new functionality. For example, APGD system can treat nearly all kind of industrial plastics, such as polyimide, polytetrafluoroethylene, and so on, but could not attain in the industrial corona treatment using air fed barrier discharge (DBD) system that is commonly used for surface treatment of consumer plastics.
The APGD which has homogeneous and low-temperature glow region was first proposed by M. Kogoma and S. Okazaki (Kanazawa et al. 1987). In the system, they used dielectric barrier discharge (DBD) to have short length pulse discharge and helium mixed with small amount of monomer gases to realize the lowest starting voltage in the discharge. Short length pulse discharges in helium gas will intercept the gas temperature rising which can realize low-temperature glow discharge in the atmospheric pressure. APGD is categorized as non-thermal equilibrium plasma, electron temperature (T e ) is higher than 10,000 K, gas temperature (T g ) is nearly room temperature, and the maximum electron density is about 3 × 10 10 cm −3 as same as in the low-pressure glow discharge .
The theoretical approach of the APGD in helium gas has been proposed by Tochikubo et al. (1996). The reason why APGD in helium is easy to be generated glow discharge is due to the ionization coefficient in low reduced electric field. The advantage of helium is its larger ionization rate at the low electric field than other gases. The atmospheric discharge in helium, the reduced electric filed at the ionization region that is near of the starting voltage is at most 30 Townsend (1 Td = 1 × 10 -17 V·cm 2 ) or so which is much lower than that of the nitrogen (− 1000 Td). In this case, since the multiple ionization proceeds rather slowly, the discharge will not be non-uniform like as in a streamer discharge. However, even used He as a carrier gas, the continual discharge brought about arc discharge by the thermal accumulation in the plasma. They have also suggested that the trace impurity of nitrogen in helium helps in easy ionization by the Penning ionization reaction shown in Eq. (1) with helium metastable atoms (He 2 1 s and He 2 3 s) that produced in the former discharge. The metastable atoms (He m ) which has high electronic state energy (2 1 s, 20.7 eV and 2 3 s, 19.8 eV), can dissociate the mixed gas, such as monomer molecule M 2 as shown in Eq. (2) in addition with the ionization process (Eq. (1)).
Therefore, enough concentration of radical species can be expected that proceeds the chemical reactions as like as in the low-pressure glow discharge. When we use nitrogen instead of helium for carrier gas, we will have a glow-like discharge, the socalled Atmospheric Pressure Glow-like Townsend Discharge (APTD) that was first proposed by Massines et al. (2000). The APTD is a kind of diffused discharge that functions similarly to APGD. The N 2 discharge will arise to contamination of nitrogen atom or nitrogen oxide in the discharge system, although APTD is useful for the surface treatment of plastic film, especially for the industry that needs surface modification for products. Normally, APGD or APTD treatment system are applicable for approximately flat substrate, such as paper, film, and printed circuit board, because the electrode gap is restricted shorter than 10 mm except of using the plasma jet reactor.
In the following chapters, several applications, such as surface treatment of plastic films, silica deposition on the powder materials and so on, will be described which have been achieved by the author's group using the APGD system.

Plasma systems in APGD
For the realization of APGD, three conditions are generally needed to produce the glow discharge (Kanazawa et al. 1987).
(1) The presence of solid dielectric material between discharge electrodes.
(2) The suitable kinds of dilution gases, such as He, Ar passing between the electrodes.
In the first condition, dielectric plate (barrier electrode) inserted between two electrodes assists pulse formation at low frequency applied voltage, in the same way as in the air fed ozone generator system in which many fine filament discharges are generated on the dielectric plate. If we use high voltage, very short length pulse electric source, such as a Nano-Pulse Discharge System, we could eliminate the dielectric plate between the electrodes. When we introduce helium to the barrier discharge system, only one pulse current should be found (Tanaka et al. 1999) as shown in Fig. 1. The pulse time duration is about 100 times longer than that of the air fed DBD. This is attributed to the formation and extinction of positive column in the glow discharge system same as in low-pressure glow discharge, because the electric field in positive column is very weak compared with a streamer discharge system. In weak field plasma, the ions and electrons need long time to away off to the electrodes.
After stopping the current, a proportion of the metastable atom (He m) is still retained which initiates the next glow discharge. In frequencies lower than 1 kHz, He m concentration decreased in no plasma period, which becomes unstable during plasma period, needing to consider a third condition.
The atmospheric pressure low-temperature plasma described in the following chapters of the applications, is a notable topic of the research since there are needs for developing some novel ways of plasma generation.  Figure 2 shows a typical discharge tube with parallel plate electrodes for the atmospheric pressure glow discharge treatment. One of the two electrodes can be a metal plate. In that case, shower type gas inlet nozzle electrodes are available. However, if both of them are covered with dielectrics, such as glass plates, filamentary discharges like as streamers are not easily generated. The gap should generally be thinner than 10 mm so that the uniformity of the plasma can be sustained. When a parallel plate electrode type is used, a substrate is usually placed on either upper or lower electrode surfaces. If a specimen is an insulator, such as a polymer, the discharge current will pass through the substrate, even if it is floating. If a specimen is a conductor, some care has to be taken. Namely when the plasma density is high, a high electric field at the edge of the specimen or at a print pattern can induce locally high-density discharge. In the case, when a parallel plate electrodes type is used, the uniformity of feeding gas in a gap affects the uniformity of the treatment. Apart from the discharge tube with parallel plate electrodes, the researchers have developed a remote-type or jet-type discharge tube as shown in Fig. 3. If helium or argon is used as a carrier gas of the remote-type discharge tube, the activated neutral species generated in the discharge can blow out in to the air.
By exposing a substrate into the downstream which includes the activated species, such as fluorine atom, one can chemically treat its surface. Utilizing this remote type, Nagata, Horiike et al. (Nagata et al. 1989) successfully etched a surface of a silicon substrate using CF 4 with He carrier gas in the atmosphere. The concentration of the activated species decreases as the samples stay in atmospheric pressure air. Using the remote type typically requires higher gas flow rate than using the parallel plate type. However, the remote type is free from direct exposure in a discharge, and thus there is no influence of charged particles, such as ions and electrons. On the other hand, the treatment in a parallel plate type is significantly influenced by the charged particles. The remote type is therefore applicable to direct cleaning of substrates on which semiconductor devices and various chips are attached. In addition, it can be easily installed for inline treatment where the plasma device is placed within the existing process. This is one of the marvelous advantages of APGD which enables the treatment in atmosphere. This technique can be applied to the surface cleaning of liquid crystal display panels in the mass production line using Ar or N 2 instead of He for carrier gas.

Copper-polypropylene facial adhesion using various gas mixtures
and surface analysis using gas phase chemical derivatization reactions of atmospheric pressure glow discharge (APGD)-treated polypropylene (PP)

Introduction
The objective of this work (Prat et al. 1998) is 1) to determine the chemical functionalities which are responsible for the adhesive strength of the treated polymer by following the amounts of the different functionalities at the treated-polymer surfaces with the Gas-phase Chemical Derivatization Reactions (GCDR) method and comparing them with adhesive strength and surface treatment; 2) to study the aging of these functionalities and these properties with elapsed time after treatment. In the  Fig. 3 Side and cross-sectional views of an after-glow type discharge set up for in line surface treatment (Tochikubo et al. 1996) case of the polymer surface treatment, the silent discharges were produced in the same effect as with the industrial corona discharge apparatus that is generally used in the industry. We made a comparison the aging effects of the treated surfaces with using APGD and the dielectric barrier discharge systems (DBD).
In the first part of the review, we describe the effects of APGD treatments on the adhesion capability of polypropylene for different gas mixtures and treatment times. The adhesion capability was determined using in situ copper metallization (200 nmthick) immediately after APGD treatment in a parallel established vacuumed chamber using copper-metal vaporization. After copper metallization, a diamond stylus is used to scratch the copper surface and the minimum value of the load necessary to scratch the surface is measured (described as critical load). We assumed this value to be related to the adhesive properties of the polymer.
In the second part, we report the study of the gas phase chemical functionalization of the plasma treated surfaces and their aging in ambient atmosphere. After the treatment of a polymer in the APGD, numerus different chemical functionalities are created on the surface. These functionalities are very difficult to detect and quantify by X-ray photo electron spectroscopy (XPS), the oxygen containing ones in particular, mainly due to the small chemical shift differences in C 1s region. With the chemical modification technique different functional groups can be labeled. Fluorine substituted labeling reagents are used because of the high chemical shift induced by fluorine, its high cross section and because it is not present on the original polymer. The gas phase chemical modifications utilized are listed in Scheme I.
The details gas chemical procedures, the estimation of chemical functionalities and their precision has been reported in the papers (Nakayama et al. 1988;Sutherland et al. 1994;Chitoki et al. 1990).
The C = O evaluation is based on the amount of N atoms on the polymer surface after the reaction between hydrazine and the carbonyl functionalities as shown in Eq. (4). This evaluation is impossible in the case of N 2 /He discharge treatment because of the incorporation of nitrogen atoms during the discharge treatment. The -NH 2 evaluation in N 2 /He discharge has been done by reaction between -NH 2 and C 6 F 5 CHO which attributed to Eq. (6).

Copper adhesion with polypropylene film surface
The best adhesive properties (corresponding to the highest critical load (CL) necessary to scratch the surface) is obtained for the N 2 /He plasma (Fig. 4). CL increases with increasing treatment time until three minutes and then slightly decreases. It is always higher than the line for He or O 2 /He discharge treatments. The strong adhesive properties after He/N 2 plasma treatment can be explained by following the amount of primary amines versus treatment times (Fig. 5). Primary amine concentration was followed by XPS after pentafluorobenzaldehyde (PFBA) labeling (Eq. (6)). In the same way, trifluoroaceticacid (TFAA) was used for -OH group, hydrazine was used for RC = O and trifluoroethanole (TFE) was used for COOH group. The N/C and NH 2 /C ratios increase with increasing of treatment time. NH 2 is the main nitrogen-containing functionality on the surface. For longer treatment time, the NH 2 /N total ratio decreases but the total amount of NH 2 still grows.
After copper depositions that performed on N 2 /He, O 2 /He discharge treated PP, and untreated PP, we tried to peel off the polymer. Then, performed XPS analysis on both metal and polymer peeled off side. In the case of the untreated PP, the wide scan spectrum (WS) of the metal side is the same as that of the metal copper and the polymer side is the same as the PP in WS. On the other hand, for both of N 2 /He and O 2 /He discharge treated PP, the WS of the metal and the polymer side are identical to that of PP. These results show that the separation of the two layers occurs into the polymer and not the Copper-PP interface. The morphological changes that measured by SEM (Photo 1), are found for every treatment, but in the case of treated in N 2 /He, particularly significant changes were found since the polymer is deeply modified.
The combination of the following two factors could explain the strong adhesion capability of the He-treated PP. 1) Primary amine functionalities detected on the polymer surface can form chelates with copper and improve the adhesion dramatically as shown in Fig. 6. 2) The profound change of morphological shapes can result in an anchoring effect.
In this case, the only way to the peeling of copper trapped between the surface projections is to break the polymer. The loss of adhesive power for durations of longer than 3 min could be due to the degradation of the surface and creation of weak boundary layers well known effect in the low-pressure plasma treatment. 3) After the plasma treatments, PP samples stayed in atmosphere for aging until the measuring of the functions. At the N-containing group, NH 2 /N rations were decreased from 0.7 to 04 in 60 days.

Conclusion
The important adhesion capability of treated PP in N 2 /He-APGD can be explained by the formation of chelates between copper and primary amines by an "anchor effect" due to the substantial change in the surface morphology.

Introduction
Pressure-sensitive adhesive (PSA) tapes are generally kept in rolls. PSA tapes consist of three layers: the adhesive layer, the base film and the release coating. We would like to peel the tape off smoothly when we use it, so the release coating needs to be present. Commonly, the release coating has been made of some silicone polymers that have quite low surface energy. However, these silicone release coatings have some defects; for example, these polymers become serious impurities for the semiconductor industry and some alternative material to replace silicone is desired. Although the fluorinated polymers as coating agents have low peel strength just like the silicone polymers, they need some special solvent for applying the release coating, so they are rarely used. Furthermore, some experts believe that polytetrafluoroethylene (PTFE), which is a typical fluorinated polymer, should be chosen as the base film of PSA tape instead of polyethylene terephthalate (PET), but PTFE is also rarely used because there are several problems, such as expensiveness, difficulty of fabrication, and waste disposal. From these points of view, we have been concerned with the fluorinated polymer thin coating of PET by plasma. Although many investigators (Millard et al. 1973;Yagi et al. 1982;Anand et al. 1981) have carried out the fluorinated polymer coating of polymeric materials by low pressure plasma polymerization, we would like to achieve it by the APGD technique, because it is a useful technology for the surface treatment without using a vacuum pump that is needed with low pressure plasma devices (Yokoyama et al. 1990). In our previous study, we have reported that some fluorinated plasma-polymer (FPP) depositions of PET using the APGD technique had low enough adhesive strength for use. However, we could not completely prevent the peeling off of deposited FPP, because those depositions were essentially fragile (Tanaka et al. 2000Nakajima et al. 2001;Babukutty et al. 1999;Tanaka and Kogoma 2003a,b). In this study, we have focused on the APGD fluorination of PET surfaces, which was different from the FPP deposition, to solve this problem. However, it seems that the fluorination alone would not make the peel property higher. Generally, the adhesive strength between PSA tape and solids depends on not only the surface energy but also the surface morphology of the solids (Karmann and Kummer 2001). Mann et al. (1998) reported that the roughening of the solid surface over 0.1 μm makes the adhesive strength weaker. Therefore, we also investigated whether a combination of two surface treatments, the fluorination and the surface roughening, would make the peel property higher.

Experimental
The smooth surface PET film (Diafoil S-100-25, Mitsubishi Polyester Film Co. Ltd., thickness: 25 μm) was used for this study. And we also prepared seven rough surface PET (matte PET) films, whose roughnesses are shown in Table 1. Further details regarding the manufacturing process of the matte PET films are not able to be described because of a confidentiality agreement. No.31B PSA tape (Nitto Denko Co., Ltd, width = 20 mm) was used for peeling test. This PSA tape has the following properties: the base film is a 25 μm-thick PET, and the adhesive is an acrylic PSA (thickness = 30 μm). This PSA tape is widely used as the evaluation tape of the peel test in the release-related industry. A schematic diagram of the reactor used in this study is shown in Fig. 7 (reactor type A). The reactor was made of a Pyrex glass tube whose inner diameter was 46 mm The high voltage electrode was made of a copper mesh that wrapped around the Pyrex reactor. The inner stainless electrode, with a diameter of 44 mm, was the ground electrode. Cooling water flowed in the inner stainless electrode during the discharge.
The PET film or the matte PET film, which was wrapped around the inner stainless electrode whose height was 130 mm, was used as the specimen for various measurements.
The discharge gap between Pylex galss and inner erectrode was 2 mm. He carrier gas flow rate was 5 l min −1 (slm) that mixed with 20 cm −3 min −1 (sccm) of 3 Page 12 of 65 CF 4 or SF 6 . The reactor was vacuumed with a rotary pump until 3 Pa to remove impurity gas. As soon as the pressure reached 3 Pa, the vacuuming was finished. He gas was then admitted into the reactor and the reactor pressure was restored to atmospheric pressure. Afterwards, the high voltage at a frequency of 100 kHz was applied into the reactor for 30 s; and this introduces radical sites on the PET film. Finally, the CF 4 or the SF 6 gas was added while the discharge was maintained and the PET film surface was fluorinated. After the fluorination, the PET film was taken from the reaction chamber, and pieces of film served as specimens for XPS studies, scanning electron microscope (SEM) studies to measure the morphology, PSA tape was pressed onto the fluorinated film using a 2 kg roller and then peeled off at a speed of 300 mm min −1 . Although peel strength was formerly presented in units of grams strength per 20 mm, the SI unit, N m −1 , is used in this article, the relationship between these units is 1.0 gf (20 mm) −1 ≈ 4.9 × 10 -1 N m −1 . The chemical state of the fluorinated films was determined by XPS (ESCA-5800ci, ULVAC-Phi Co. Ltd.). XPS was carried out using ex situ measurements, and the specimen was exposed in the air after plasma treatment for approximately one hour. The take-off angle of the X-ray source position was 45˚. The XPS spectrum binding energy was corrected by shifting the hydrocarbon component (CH x , x = 0 to 3) peak in the C 1s spectrum to 284.6 eV. Then we carried out curve fitting with the XPS program of ULVAC-Phi by reference to the interval energies between each chemical group observed from references Gelius et al. (1970) and Clark et al. (1973).
The surface morphology of the fluorinated matte PET film was observed using SEM (JSM-6100, JEOL Ltd.) at 20 kV accelerating voltage.

Results and discussion
(1) SurfSace fluorination of PET film To examine whether the surface fluorination of PET film made the peel property of PET surfaces higher, we tried to treat PET film by CF 4 /He or SF 6 /He-APGD. Figures 8a and b show the peel strengths between PSA tape and the PET treated by CF 4 /He and SF 6 /He discharge, respectively. Both CF 4 /He and SF 6 /He discharge treatments decreased the peel strength with increasing the treatment time, but the peel strength of SF 6 /He plasma-treated PET did not decrease in the value of the CF 4 /He plasma-treated one. Since the emission of the SF 6 /He plasma was weaker than that of the CF 4 /He discharge, the discharge power was changed from 100 to 150 W. However, there were no significant differences in the resulting peel strengths. The comparison between the peel strength of polytetrafluoroethylene (PTFE, dotted line) and that of the CF 4 /He plasma-treated PET shows that the peel strength in the CF 4 /He discharge was not lower than that of PTFE. The electrostatic force between no adhesive side of PSA tape and fluorinated PET film were measured. From the experiments, the electrostatic force was considered negligible, and was excluded from the peel force on the PSA adhesive side.
Next, we investigated why there were changes in the peel strength due to the plasma. It is well-known that the adhesive strength affects not only surface chemistry (functionality) but also surface physics (roughness and configuration). However, we did not consider the change in the surface physics by plasma treatment. This reason is as follows: our previous study (Kosugi et al. 1992) has shown that the surface roughness, R a , of polyimide after CF 4 /He-APGD treat-3 Page 14 of 65 ment for 60 min was changed from 0.027 (untreated) to 0.023 μm. This result indicates that only a minor change in surface roughness occurs during APGD treatment under fluorine gases, such as CF 4 and SF 6 . Therefore, we only investigated the relationship between surface chemistry and peel property. Figure 9a and b shows the atomic ratios F/C and O/C obtained from the XPS spectra of the PET treated with the CF 4 /He and the SF 6 /He plasma as a function of the treatment time, respectively.
Although the XPS spectra of the SF 6 /He-APGD treated PET contained sulfur, we neglected it because S/C < 0.1. The F/C ratio in the CF 4 /He plasma was higher than that in the SF 6 /He discharge, but lower than that of PTFE (F/C = 2.0). We also found that oxygen atoms still remained in the discharge-treated PET films. That were the reasons why the peel strength of plasma treated one was higher than that of PTFE. To make the difference between the two discharge treatments in the peel strength clear, the PET films treated with each plasma were investigated using the C 1s XPS spectra.
The C 1s XPS spectra of untreated and the discharge -treated PET films are shown in Fig. 10. The C 1s spectra of the discharge -treated PET films were decomposed into five components, which were assigned to C-C, -C-CF n (and/ or -C-O), -CF (and, or -COO), -CF 2 , and -CF 3 groups. This result indicated that C-C, C-O, and COO groups were modified into C-CF n , CF, CF 2 , and CF 3 groups during the plasma treatments. When the effects of the two plasmas on these modifications were compared, we found that the concentrations of CF 2 and CF 3 groups, which bring lower surface energies than C-C, C-O, COO, and CF groups, in the CF 4 /He discharge were higher than those in the SF 6 /He discharge. Furthermore, we examined the relationship between the atomic ratios, F/C and O/C, and the peel strength. These results are shown in Fig. 11. The peel strength showed a nearly linear relationship with F/C. When the straight line depicted in Fig. 11 was extrapolated, the F/C value at the peel strength = 20 N m −1 (PTFE) was 1.58. This result suggested that the peel strength about equal to that of PTFE could be obtained if the F/C value was raised up to 1.58. However, a higher discharge power or a higher discharge frequency might be needed to increase F/C using the plasma treatments. Since PET film is weak against heat, we considered that it would be difficult to achieve such an increase only by the plasma treatments.
Finally, we investigated whether the treated layer could be peeled off from the PET film and moved to the PSA tape glue side after the peeling test. Figure 12 shows the variation of the F/C values of CF 4 /He discharge -treated PET side and of PSA tape glue side after peeling tests with the treatment time. The F/C values of the PSA tape glue side as peeled off from the plasma-treated PET were near zero. Those of the PET side as peeled off from the treated PET were almost identical to those of the treated PET. These results indicate that part of the plasma-treated layers was not peeled from the PET. Therefore, we concluded that the surface fluorination of PET by APGD could prevent the peeling from the treated layer. (2) Surface fluorination of PET films with different surface roughness values We tried to combine the APGD fluorination and the surface roughening for the formation of the surface with high peel property on PET film. The seven matte PET films (Table 1) were treated with the CF 4 /He APGD at a discharge power of 100 W for 10 min. Figure 13 shows the peel strength of the matte PET films with and without the fluorination. The peel strengths of smooth surface PET films with and without the fluorination and of PTFE film are also shown in Fig. 13. We found that the peel strength of the matte PET films without the plasma treatment showed lower peel strengths than the value of the untreated smooth surface PET. This result indicates that the surface roughening made the peel property higher. Moreover, the matte PET peel strengths were decreased by the fluorination; especially the roughest matte PET, #7, showed lower peel strength than that of PTFE. The peel strength of the roughest matte PET with fluorination was 3.0 N m −1 . Therefore, from the viewpoint of the formation of the high peel property, our expectation was achieved.

Conclusion
The surface fluorination of PET films by APGD could prevent the peeling off of the treated layer but did not lead to high enough peel property. The combination of the surface fluorination and the surface roughening made the peel property higher than the value needed for use as a release coating of PSA tapes. Since the relationships between the surface roughness parameters or the surface configurations and the peel property were not clear, we intend to examine them in further research.

Introduction
The laminated polymer films are widely used for the packaging materials of foods, cosmetics, pharmaceutical products and so on. These laminated films are generally pasted two or more kinds of polymer films with an organic adhesive diluted by an organic solvent. The adhesives and/or solvents, which remain between the films,  Table 1 sometimes exude into the package content. And the organic solvent is cause of the environmental pollution in the manufacturing plant as a volatile organic compound (VOC). Thus, a new adhesive-free lamination technique is desired. In this study, an adhesive-free lamination technique was investigated using the atmospheric pressure glow discharge surface treatment and thermo-compression.

Experimental
The popular lamination materials, such as polyethylene terephthalate (PET), nylon (NY), low density polyethylene (LDPE) films, were used as samples for the adhesive-free lamination. These films were first treated by N 2 /He or He APGD. Low frequency (LF; 100 kHz) and Radio Frequency (RF; 13.56 MHz) were used as discharge frequency.
In this experiment, the tubular type discharge apparatus was used as shown in Fig. 7 (reactor type A) for long time (10-90 s) treatment of sample films which wind round on the inner electrode. Figure 14 shows a slider type discharge apparatus (reactor type B) for brief time (1 ms-10 s) treatment in the air ambient. In the apparatus, plasma is kept between upper electrode and lower sliding electrode. The treatment time with the slider type discharge apparatus (reactor type B) was varied by changing the velocity of the slider. Then, the treated films of each combinations, such as PET/LDPE and NY/LDPE were laminated by the thermo-compression (140-180 °C, 0.4 MPa, 10 s). An adhesive strength of the laminated film was measured 180º peel strength with tensile tester.
When we measured the adhesive strength by heat pressing of LDPE with PET or NY film, once PET or NY film side was fixed on a steel plate with epoxy glue and then LDPE was pulled. The chemical state of the films was determined by XPS (ULVAC-Phi Co., Ltd., ESCA-5800ci); light source was monochromatic Al K α ray and take-off angle was 5º. The details of the discharge conditions are shown in Table 2.

Results and discussions
All combinations of the untreated films were not stuck only by the heat press. Although the adhesion strength values of the treated films that used the reactor type A did not exceed the industrial desired values, they exhibited higher values than those of the untreated as shown in Table 3.
We obtained small increasing effect on the adhesion strength value with decreasing the treatment time from 15 s. However, when we use the reactor type A, we cannot have the treatment time shorter than 10 s, so we used the reactor type B.
In Fig. 15, we obtained the maximum adhesion strength for times including those under 0.04 s. After passing the maximum point, adhesion strength is decreased with decreasing of the time. The insufficient plasma irradiation on the sample surface results in the reduction of adhesive strength.
As shown in Fig. 16, the adhesive strength of PET/ LDPE and NY/LDPE using RF power source is obviously refined compare with LF discharge treatment and attained extremely higher values than that of the desired values shown by the dotted lines in the figures. In the high frequency discharge higher than 1 MHz, ions with heavy masses cannot move across the gap causing loss on the electrodes in the half cycle. High density ions built in the intensive electric field in the plasma that causes higher density plasma than those of LF discharge. Since the plasma density in RF discharge is much higher than those of the LF discharge, our experimental results exhibited high adhesion ability in the short time treatment with RF discharge. Figure 17a and b shows the XPS-valence band spectra of untreated and the N 2 / He plasma treated LDPE. The adhesion strength of plasma treated films is much higher than that of the untreated film as indicated by the adhesion strength (AS) marks in the figures.
The main peak of Fig. 17a obtained around 15 eV is related to C-C bonds of the PE structure (Delhalle et al. 1974;Foerch et al. 1991   smaller as in the plasma treated in Fig. 17b). This result suggested that the polymer chains were once dissociated and recombined after the plasma treatment to produce lower molecular weight polymer. It seemed that some low molecular weight PE was consisted on the film surface and that they acted as an adhesive for the heat-press lamination with lowering of the glass-transition temperature. That is confirmed using atomic force microscope (AFM). The glass-transition temperature of the surface was clearly decreased after plasma irradiation (Dobashi et al. 2011). This mechanism was extended for polymers, such as nylon-polypropylene or polyethylene terephthalate-polypropylene. The altered layer depth from the surface by plasma irradiation was about 0.9-7 nm that measured by take-off angle method (Dobashi et al. 2011).

Conclusion
The adhesive-free lamination technique was successfully developed using the atmospheric pressure discharge. The adhesive strength for PET/LDPE and NY/LDPE are strongly depended with the discharge frequency and the treatment time.

Introduction
Fluorinated polymers, such as poly vinyl fluoride (PVF), tetrafluoroethylene-hexafluoropropylene copolymer (FEP), tetrafluoroethylene-perfluoro alkylvinylether copolymer (PFA), and polytetrafluoroethylene (PTFE) have many unique characteristics, for example, high chemical resistance, high heat resistance, low coefficient of friction and so on. Thus, they have been used as typical inert materials for many hard situations. Nevertheless, they have problems, such as difficulty of adhesion and hydrophobic nature. In general, fluorinated polymers cannot treat with a convenient process, such as corona discharges, because they can add only low effects to the chemically inert surfaces. Some agents, which contain metal sodium, are usually used to add the adhesibility or the hydrophilicity to the fluorinated polymers. However, this treatment needs a large amount of cleaning water and thus the disposal of much waste fluid. Moreover, the treated surfaces become blackish. From the reason, a new dry process had been desired instead of the wet treatments. Several studies of the surface treatment with low-pressure glow discharge (LPD) were reported (Badey et al. 1996;Hirotsu and Ohnishi 1980). However, this method has not been widely used for industry because of the low through put and difficulty of applying it to an assembly line directly. At first, we will examine three fluorinated polymers (PVF, FEP, and PFA) other than PTFE. The changes of their adhesion strength and chemical states measured by XPS will be shown (Tanaka and Kogoma 2003b).
In the case of PTFE, it has only-CF 2 bonds that are surrounded on the strait carbon chain. From the reason, it is most difficult substance to eliminate the fluorine atom from the carbon chain. Hence, we needed to use a different system and gas to treat PTFE Kogoma et al. 2015) other than those above three fluoropolymers. At final, we will try to compare the APGD and the LPD (Wenfeng et al. 2015) in which is better plasma system for the PTFE treatment.

Experimental
(1) Treatment of PVF, FEP, and PFA In the case of the treatment for three polymers, PVF, FEP, PFA, we used parallel plate electrode (diameter: 125 mm, the gap length: 2 mm, 1 atm) discharge system as shown in Fig. 2, that stored in a glass chamber. The plasma was generated with a 100 kHz power supply at 50 W. Treatment mixture gases were O 2 , N 2 , and Ar gases diluted with large amounts of He or He alone. The flow rates of gas mixture were as follows, He: 2 slm, and O 2 , N 2 , Ar were each 5 sccm. A rotary pump first evacuated the chamber and the pressure was then restored with a treatment mixture gas at atmospheric pressure. Treatment time was 0.5 ~ 5 min. Polymer sample (NILACO Co. Ltd., 0.05 mm films, sizes: 20 × 40 mm) was placed on the lower electrode that connected with the ground. Water contact angle was measured using contact angle meter. A treated sample film was glued on an aluminum plate with epoxy glue. Peeling force of the test piece was measured by 180° tensile tester . XPS (ULVAC-Phi, ESCA5800ci) was used for the surface analysis. The details of the schematics were shown in reference (Kogoma et al. 2015).
(2) Treatment of polytetrafluoroethylene (PTFE) with diborane-plasma system Boron trifluoride (BF 3 ) is the gaseous fluorine compounds at room temperature and the bond enthalpy of fluorine with boron (757 kJ mol −1 ) is much bigger than that of fluorine with hydrogen or carbon (570 or 552 kJ mol −1 ) (Lide 2000). It seemed that defluorination of PTFE will be possible with using diborane (B 2 H 6 ) dissociation plasma. Figure 18 shows the discharge apparatus which have two discharge areas. The discharge areas were bounded for quartz glass plates, and so H 2 /He mixture gas 3 Page 24 of 65 flowed in one direction. The upstream discharge was used for the reaction of hydrogen and boron plate to have the diborane generation and the downstream discharge was used for PTFE surface treatment with boron atom by dissociation of diborane which was transferred from the upstream, respectively. The boron plate (thickness, about 0.1 mm) was prepared by solidification of boron powder (0.3 g) with inorganic adhesive (0.3 g, Aron Alpha Inc., Aron Ceramic D). PTFE sheet, whose sizes were 20 mm × 20 mm × 0.2 mm was used.
The treated sample surface was evaluated as same as in the 2.1. Discharge power for diborane generation was 27.12 MHz, 500 W, and for diborane dissociation plasma was 300 kHz, 50 W. The flow rates of gas mixture were as follows, He: 2 slm, H 2 : 10 sccm. Treatment time was 0.5 ~ 5 min.
(3) Treatment of PTFE with NH 3 -H 2 O/He in low pressure discharge (LPD) and APGD systems RF (13.56 MHz, 100 W) discharge and parallel electrodes were used in the both plasma systems as same as in Fig. 2. The electrode gaps were 15 mm for low pressure (0.6 Torr) system and 2 mm for APGD (1 atm) system respectively. The sample film (PTFE, 0.5 mm × 2 cm × 3 cm) was placed on the grounded electrode. Sample gas was introduced to the chamber path troughed the bubbling system of NH 3 (10%) aqueous solution with 10 sccm of He flow. The sample gas conditions were followed with in the reference (Tanaka and Kogoma 2003b). In the case of the APGD, NH 3 + H 2 O (10%) vapor with 10 sccm of He flow that was diluted by 2 slm of He.

Results and discussion
(1) PVF, FEP and PFA treatments   Figure 19a shows the untreated PVF and they were slightly oxidized. The variation of F/C shows the reduction of fluorine atoms. And O/C + N/C show some additional atoms due to the plasma treatments. In the case of PVF, the ratios of O/C + N/C were saturated for a brief time treatment. We assumed that PVF had only one fluorine atom in its unit structure and that PVF was oxidized more easily than other fluorinated polymers. On the other hand, the ratios of O/C + N/C of FEP and PFA increased as the treatment time increased. Especially, those of He plasma-treated samples increased significantly, and the ratios of F/C decreased simultaneously. All the results of O 2 /He discharge treatment showed relatively low ratios of O/C + N/C and high ratios of F/C. It seemed that O atom has lower reactivity than that of the N 2 /He plasma on the fluorinated polymers. Figure 20 shows adhesive strength of FEP and PFA treated in APGD.
The peel forces of plasma-treated PVF could not be measured because their adhesive forces were beyond the value of the measurement instrument limit (2.00 kg•20 mm −1 ). Moreover, it was higher than that of the target level, whose value was 1.06 kg•20 mm −1 . The adhesive forces of FEP and PFA treated by plasma were approximately 180 and 80 times stronger than the forces of untreated films, whose values were 0.4 and 0.6 kg•20 mm −1 . In addition, the results of FEP showed the higher force values than the target level, while those of PFA showed slightly lower than that of the target level. For the treatment of PFA, further harder system will be needed, because PFA has no hydrogen in the structure.
(2) Treatment of polytetrafluoroethylene (PTFE) with diborane plasma system Figure 21 shows the variation of the atomic content ratios of F/C and O/C calculated from XPS results of the diborane/H 2 /He plasma treated PTFE. The O/C values of the treated PTFE were quite low as shown in Fig. 21. This result suggested that the chemical state of the treated PTFE surface came close to that of polyethylene because of defluorination of PTFE and additional reaction of hydrogen atoms. It is certain that the surface morphology of the treated PTFE became rougher that provides the increasing of the adhesive force. Although the fluorine atoms on the treated PTFE surface were not removed completely, the F/C value was decreased to about twentieth of that of untreated PTFE.
Next, the adhesive strength between treated PTFE and epoxy glue was examined. Figure 22 shows the variation of the adhesive strength. The adhesive strength became stronger linearly as increasing the treatment time. And those treated longer than 2 min showed higher values than that of target value. The adhesive strength of 5 min treated PTFE was about twice as higher as that of target value treated with Tetra-Etch (DuPont, sodium-naphthalene), and it was high enough adhesive strength for practical use.
(3) Treatment of PTFE with NH 3 -H 2 O/He in low pressure discharge (LPD) and APGD systems For a reaffirmation, a comparative study has been done with the LPD and APGD systems. Figure 23 shows the surface wettability of PTFE as a changing of the treated time in LPD and APGD. When we use LPD with NH 3 -H 2 O/He, water contact angle was decreased with increasing of the elapse time. In the longer treating time than 30 min, the contact angle was going to lower than 5°. Thus, the appearance of the super hydrophilicity on the PTFE surface which is shown in the reference (Wenfeng et al. 2015) has been demonstrated. On the PTFE treated with NH 3 -H 2 O/He in LPD system, O 1s or N 1s spectra were found that for certain assigned as carboxyl or amide group which was measured by XPS (not shown). Normally, an electro negativity of the carboxyl group is enhanced by containing of amide group that arise the enhancement of hydrophilicity in the molecule. This is one of the reasons why we see the super hydrophilicity at longer treatment time of PTFE in LPD in Fig. 23. In contrary, in the APGD, the water contact angle shows almost no change with changing of the elapse time even using the same gas composition and discharge power in low pressure discharge, except of the operating pressure. It is well known that some kinds of radicals cannot easy react with PTFE, such as O atom, H atom, OH and NH n .

Treatment time/min
Because, -CF 2 bond is too strong to react with such radicals. Hence, in LPD, some supporting reaction should be expected, such as sputtering reaction to enhance the radical reaction on the PTFE in LPD. The peeling force which treated in APGD with NH 3 -H 2 O/He was the same as that of the untreated PTFE. Figure 24 shows the peeling force which treated in low pressure discharge with NH 3 -H 2 O/He. In the fig., also shows the surface treated in the diborane-APGD system. In the LPD treated surfaces, H 2 O/He system shows faster increasing rate than that of NH 3 -H 2 O/He, but it shows much slower rate than that of the treated in boron compound-APGD system. Suppose the rate determining step will be attributed to the slow sputtering reaction on the PTFE even in the NH 3 -H 2 O/ He LPD. On the other hand, at the diborane-APGD system, the atomic boron produced in APGD directly extracts the fluorine atom from -CF 2 bond of PTFE and then post oxidation will be occurred by the exposing in the air. In the case of PFA, also it could attain good adhesibility with boron-APGD system.

Conclusion
For PVF and FEP, they are relatively easy to obtain good adhesibility with O 2 , N 2 , and Ar in He, or He only in APGD. In the PFA and PTFE, from the reason of the perfluorinated polymers, diborane-APGD is better system than that of the LPD to refine the surface adhesion strength.

Introduction
The creation of hydroxyl chemical group on the solid surfaces is especially useful as the pre-activation step before the surface coating, such as silane coupling reaction to insert functional chains, grafting of PEG for biocompatible surface and hydrophilic surface to take wettable surface. We previously reported the surface oxidation to have the wettability on the polyethylene powder using APGD ). The plasma oxidation of the polymer will produce mixture of -COOH, -CO, and -OH groups as the hydrophilic groups on the treated surfaces. From the reason, it is difficult to obtain -OH group without of production of any other oxidants on the treated surfaces. Gombotz et al. (1991) introduced hydroxyl group by low pressure glow discharge CVD of allyl alcohol on the PET film to activate the surface before immobilizing the PEG on the surface. However, they could not obtain the complete surface coverage of hydroxyl group by low pressure PCVD. In the low-pressure glow discharge, ion impact to the deposited surface is too active to keep the hydroxyl group that is comprised in the monomer molecule. Hence, the low pressure PCVD of allyl alcohol could not have enough concentration of hydroxyl group on the surfaces. On the other hands, because of the low ion energy in high pressure discharge, APGD-CVD can eliminate the possibility of any reaction which attributed to the ion impact reaction on the surface. We will report the thin layer deposition on the glass surface by the APGD-CVD using allyl alcohol.

Experimental
LF (300 kHz) discharge power from 10 to 40 W is applied to the discharge apparatus that is composed by parallel Pyrex glass plates and outer metal electrodes as shown in Fig. 2. Allyl alcohol was used as a monomer substance for the simplest alcohol molecule which has a double bond in the structure. The 2 slm of He gas is mixed with few ten sccm of ally alcohol vapor then introduced to the discharge zone. The glass plate (0.5 mm × 10 mm × 30 mm) is used as the substrate which inserted between the electrodes. The discharge gap is 2 mm. The deposited films are investigated by surface roughness profiler, wettability measurement using water contact angle method, elemental analysis, XPS for the chemical derivatization techniques to measure the absolute concentration of hydroxyl groups on the deposited surfaces.

Results and discussions
Deposited film surfaces show slightly yellowish-brown collar and are not soluble in water and ethanol. Figure 25 shows the deposition thickness as a function of the discharge time at 30 W of the discharge power and 23.2 sccm of the monomer flow rate. The film thickness is almost linear dependent with the discharge time. The deposition rate is attained about 0.4 μm min −1 which is 30 times faster than that obtained in low pressure discharge (Rinsch et al. 1996). This means that APGDchemical vapor deposition is very efficient deposition system for polymer deposition. We suppose that the reason of high deposition rate in APGD is attributed to no ion effect on the surface, because the fast ion impact in the low-pressure glow discharge will bring the etching effect for the deposition film. Figure 26 shows the deposition thickness as a function of the discharge power. The deposition rate is little bit decreased at the high-power region. This means that monomer flow limitation will be attained at high power region. Figure 27 shows the film thickness as a function of the monomer flow rate. The thickness is almost linear dependent with the flow rate of the monomer. Even in the highest flow rate, the thickness is still increasing linearly. This means that the flow rate limitation does not attain in the figures. It seems that if we increase the flow rate higher than 7 sccm, we will obtain higher than 0.4 μm min −1 . Figure 28a shows the XPS C 1s spectra of the deposited film surface. Figure 28b shows the C 1s spectra of the surface after treated by trifluoroaceticacid anhydride (TFAA). After treated with TFAA, two new peaks appeared in the high binding energy region that attributed to CF 3 and -COO. We can calculate the OH group surface concentration with comparing of XPS spectra data of the TFAA treated standard material, such as polyvinyl alcohol (PVA) and using the Eq. (7). Figure 29 shows the concentration of hydroxyl group on the deposited films as a function of the discharge power measured by chemical derivatization technique. In the figure, we attained about 18% of OH group on the deposited film surfaces. The OH group concentration is almost constant between 10 and 30 W in the discharge power.
The elemental analysis was done with the deposited films to confirm the results obtained by chemical derivatization technique as shown in Table 4. For the measurement of the elemental analysis, the sample materials were collected from the deposited films by scribing of the substrates. The collected samples were combusted in the fine tubing with oxygen. Elemental analysis was calculated by weight changing after oxidation of the samples.

Thickness / Pm
Allyl alcohol flow rate / sccm Table 4 shows the mean data of the elemental analysis of the deposited material. Difference between XPS data and elemental analysis data will be attributed to the small amount of carbonyl group which included in the deposited materials and the structure changing by the cross linking of the allyl alcohol polymer.

Conclusion
We succeed to deposit the cross-linked solid polymer film which shows very analogous composition of the allyl alcohol. The deposition rate was attained 30 times higher than in low pressure plasma CVD. Obtained films contained about 18% of the hydroxyl group on the deposited surfaces.

Introduction
Some kinds of pigments that are used for cosmetics give rise to a skin irritation problem when they contact the skin directly. TiO 2 is an UV reflective white pigment powder for cosmetics. However, naked TiO 2 is a kind of photosensitive catalyst, so the powder easily attacks a human skin surface and oxidizes oil in the sweat as a squalene. Oxidized squalene molecules will produce many kinds of peroxy-organic compounds that may cause an allergy or cancer, needing to avoid such effects caused by the catalytic ability of TiO 2 particles. Previous studies reported the possibility of powder handling with atmospheric pressure glow discharge (Yokoyama et al. 1990;Mori et al. 1998;Ogawa et al. 2001). Then, at the first stage in this experiment, we will try to develop some SiO 2 coating on the TiO 2 powder pigments by means of APGD using tetraethoxysilane (TEOS) adsorbing and plasma oxidation to prevent the oxidation of squalene oil in the UV irradiation. On the other hand, the SiO 2 -coated TiO 2 powders will not have only a very high refractive index for the UV region but also high transparency for visible and IR regions. For such reasons, silica-treated powders will have too white a tint to use for the cosmetics and cannot prevent IR penetration through the powder, which is also a cause of human skin irritation. We can expect that some metal ion doping can achieve wide band light absorption in TiO 2 . At the second stage, we will try to obtain a thin deposition layer of iron between the TiO 2 surface and the silica layer to eliminate the photo-catalytic ability and to suppress the wide band light transparency of bulk TiO 2 .
Finally, we measure the catalytic effect and light absorption of the new material iron doped silica-coated TiO 2 .

Experimental
The mean diameter of TiO 2 particles is two hundred nm; they contain 80% of anatase and 20% of rutile (Toho Titanium Corporation, HT-170R). For iron doping, we used tris (2, 4-pentanedionato) iron (IAA). In this study, we employed the Adsorb and Dry method to achieve the coated surface. The schematics of the discharge reactor are shown in Fig. 30. The discharge conditions are as follows: discharge frequency, 13.56 MHz; power, 1.5-2.5 kW; O 2 /He gas flow rate, 100 ml min −1 /10 l min −1 . Treating rate is about 2 g min −1 for the powder.

Process 1) Silica coating on TiO 2 using adsorb and dry method
At first, we tried to make sure of the possibility of the Adsorb and Dry method with TEOS to coat SiO 2 on the bulk TiO 2 . In this treatment, adsorbed TEOS is partly reacted with naturally adsorbed water on the TiO 2 surfaces to deposit SiO 2 . The percentages of SiO 2 on the sample TiO 2 powders are calculated using the next Eq.:  Weighed TEOS is diluted in ethanol (lower than 10%); then the powder was dried in air ambience. Adsorbed powder was treated in the atmospheric pressure glow plasma in He-O 2 system to eliminate the organic part from the adsorbed TEOS molecules.

Process 2) Iron ion doping
TiO 2 powders were pre-treated with IAA-ethanol mixture to adsorb organic metal molecules on the surfaces of the particles. The amount of IAA in ethanol is calculated on the pattern of Eq. (7). After the evaporation of the ethanol, the IAA adsorbed powders are treated to have iron ion doped TiO 2 using atmospheric pressure glow plasma in He-O 2 system to eliminate the organic part from the adsorbed IAA molecules.

Process 3) Silica-Iron-TiO 2 multicoating
After process 2, the iron-doped TiO 2 powders were pre-treated with TEOS (tetraethoxysilane-ethanol) mixture aerosol to adsorb TEOS on the surfaces of the particles. After the ethanol evaporation, the powders are oxidized in APGD. Using the plasma treatment, SiO 2 was deposited on the iron-doped TiO 2 surface as an inorganic fine layer. The thickness of SiO 2 deposited can be controlled by the concentration of TEOS in the solvent ethanol during the adsorbing process.

Results and discussion
4.6.3.1 Process 1) From the XPS analysis, we found Si 2p and Ti 2p spectra for TiO 2 that adsorbed TEOS (b), and for TiO 2 that adsorbed TEOS and then was oxidized in the He-O 2 plasma (c), as shown in Fig. 31. After plasma oxidation (c), Si atomic concentration is increased because the naked TiO 2 surfaces are completely covered by an inorganic SiO2 thin layer.
In Fig. 32, sharp peaks of O 1s were obtained in the spectra of (a), (b) and (c). In the spectrum of (a) only one peak (529.9 eV) assigned to TiO 2 existed. On the other hand, in the spectrum of (b) the peak (532.5 eV) assigned to SiO 2 newly appeared while the peak assigned to TiO 2 decreased. Therefore, we concluded that the surface of (b) was coated with SiO 2, but the coating was not enough. The surface of TiO2 is still partly covered by half-dissociated TEOS molecules that are reacted with adsorbed water on the surface of TiO 2 . In the spectrum of (c), the peak assigned to TiO 2 has almost disappeared and the shape of the peak looked like that of pure SiO 2 . We could confirm that the surface of (c) was almost completely coated with an inorganic SiO 2 layer without any organic contamination.
A transmission electron microscope (TEM) image of silica-coated TiO 2 particles is shown in photo 2. In the photo, homogeneous SiO 2 thin layer (1-2 nm in thickness) is found on the particles. Hence, we attained a very homogeneous SiO 2 layer with the TEOS Adsorb and Dry method. Figure 33 shows the XPS Fe 2p spectra of IAA-treated TiO 2 particles oxidized in the O 2 /He plasma. In the fig., we can find Fe 2p1/2 and Fe 2p3/2 peaks assigned as Fe ion, but the binding energies of Fe 2+ and Fe 3+ ions are remarkably similar to each other rising to difficulty to distinguish ions on the TiO 2 . The amount of deposited Fe ion can be controlled by the concentration of IAA in the solvent ethanol at the adsorbing process. Figure 34 show the UV-VIS reflection spectra of naked TiO 2 , IAA 1% adsorbed TiO 2 ; adsorbed, then plasma-treated TiO 2 ; and pure IAA powder. Naked TiO 2 show a high and flat reflectivity from near IR region to UV region. Light incident to the surface partly penetrates the bulk and is absorbed in the solid, and then it reflects to the surface boundary, so the reflection spectra contain the absorption characteristics. IAA-adsorbed TiO 2 shows small peaks attributed to adsorbed IAA on the TiO 2 but such a peak is lost in the plasma-irradiated IAA itself. It seemed that plasma-treated IAA on the TiO 2 was completely oxidized to inorganic Fe ion. Figure 35 show the gas chromatography mass spectrometer (GCMS) spectra of gas products in squalene which contained the powders after being irradiated by a Xe lamp for one hour. Untreated TiO 2 produces many kinds of organic oxides, such as ethanol, acetone and long chain oxidant compounds that should be harmful materials for human skin. Also, the oil emits a foul odor. The product concentrations decreased with increasing of the concentration of the doped iron. However even for 2.5% iron-doped TiO 2 , we still have a small amount of alcohol in the spectrum.

Process 3)
However, using silica-coated iron-doped TiO 2 which is produced in process 3), we have almost no signal assigned as an organic oxide in the GCMS spectra of the UV irradiated squalene, except for a very small amount of ethanol signal. Normally the anatase-type TiO 2 crystals have small rectangular open spaces, such a few angstroms in size, in the structure. It seemed that the iron ions are partly inserted into the open spaces of the TiO 2 lattice. However, the crystal lattice of irondoped TiO 2 is the same as that of untreated one measured by XRD. Therefore, we could not infer whether the iron ion is in solid solution in TiO 2 . The treated powder shows fine and flesh color with pearl-like glowing, that should be caused from a multi-reflection effect from the thin layer boundaries of silica-iron-TiO 2 . Especially, the powder can cover the skin furrows and prevent easy drop-off of the powder from the skin surface by sweat, because of the high reflection for the incident light in the skin furrow and the strong absorbing ability of the nanopowder to absorb the skin oil.

Conclusion
We attained Fe ion doped TiO 2 particles by means of atmospheric pressure glow discharge plasma oxidation using IAA and TEOS adsorption. The particles were coated by a silica protection layer to avoid the UV catalytic ability of TiO 2 . The plasma-treated TiO 2 powders will provide many functional contributions for future cosmetics.

Introduction
Polyethylene glycol (PEG or PEO) has a non-fouling property by inhibition of protein or cell adsorption. However, to obtain the bio-compatibility surface, strong chemical bonds between the substance and PEG is required, because PEG is soluble in water or some organic solvent. Few kinds of process to fix the PEG was developed in the plasma processing technology. A method of grafting of PEG on to deposited amorphous silica film obtained by plasma CVD was developed by Alcantara et al. (2000). However, the grafting of PEG needs long time to achieve the desirable thick film. From the point of view, the method of CASING (cross-linking by activated species of inert gas) was adopted to take the cross-link reaction of physically coated low molecular PEG to have a thicker film in one time (Sheu et al. 1992). The cross-linked PEG films on the low-density polyethylene (LDPE) films by irradiation of Ar plasma in low pressure show a significant increase of the hydrophilicity and reduction of baboon fibrinogen adsorption. PEG film has not only anti-fouling of protein but also hydrophilicity. From the reason, we can apply the PEG film for some enzyme reaction as a carrier layer with out of any protein adsorption on the surface. However, the catalytic chemical reaction needs much larger surface area than that of the film. Moreover, polyethylene fine powder surface oxidation treatment using APGD was reported by our group. If we obtain the PEG film on the fine powder surface, we can enlarge the surface area than that of the plane film to improve the catalytic process and to improve the biocompatibility of the powder. We will report the combination study of the both processes to attain the PEG fixation on the fine polyethylene powder surface by using raw PEG adsorption and irradiation of APGD.

Scheme 1. Polyethylene (PE) powder oxidation in APGD
Before the PEG adsorption, polyethylene powder surfaces should be oxidized because polyethylene is one of the most difficult materials to absorb hydrophilic material on the surfaces hence the non-oxidized polyethylene powder will not absorb PEG. The powder is oxidized by APGD in advance of PEG absorption on the powder to refine the surface wettability of PE.
He (3 slm) gas was mixed with 50 sccm of O 2 , and then introduced in to the discharge zone with PE powder which was introduced from powder pool and 1.8-2.5 kW of RF (13.56 MHz) high voltage is applied to have APGD.

Scheme 2. PEG adsorption on PE powders
1-10% of PEG 2000 MW (raw-PEG) was dissolved in ethanol (99.5%, Kantou Kagaku Co, LTD). The oxidized polyethylene powder (8 μm∅, high density PE) is charged in to the solution and kept during 30 min to two hours in room temperature to absorb raw-PEG. The PEG adsorbed 3 Page 42 of 65 PE powder is separated with filter then dried. The dried powder will be irradiated in APGD to take cross linking reaction of the adsorbed raw-PEG. Figure 36 shows the schematics of the plasma system to treat the powder by CASING reaction in the atmospheric pressure. Some weighted raw-PEG absorbed PE powder is introduced from the powder pool to the plasma reaction zone using He flow. We used RF (13.56 MHz) discharge to treat the powder. The RF power is modulated by 10 kHz pulse of 50% on time and 50% of off time to decrease the gas temperature in the plasma zone. The plasma activated particles passing through the He discharge are collected in the vessel. Table 5 show the discharge conditions for the cross linking of the raw-PEG that absorbed on the powder. Figure 37 shows the XPS C 1s spectra of the oxide PE. In Fig. 37, oxygen content is about 10% in atomic composition on the surfaces. Oxide surface absorb hydrophilic molecules, such as PEG. Figure 38 shows XPS C 1s spectra of PEG on the oxide PE powder that adsorbed in 10% of PEG 2000 (raw PEG) ethanol solution. In Fig. 38, almost the same spectra as shown in Fig. 37 were obtained except of increasing of -CO bond. The -CO bond peak is increased with increasing of the concentration of PEG in ethanol solution. However, other bonds, such as -C = O, -COO were not increased with increasing of the concentration of PEG. Therefore, the -CO bonds in Fig. 38 will be assigned as that of in raw PEG structure of H(OCH 2 CH 2 ) n OH. Figure 39 shows the XPS C 1s spectra of 10% absorbed PEG that treated in He cross-linking plasma. The height of -CO bonds is slightly decreased in Fig. 39 than that of in Fig. 38. We suppose that a part of -CO bonds of the surfaces were dissociated by charged of meta-stable exited He atom. Figure 40 shows the ATR-FTIR spectra of untreated and treated PE surfaces. Oxide PE (b) shows some increasing of C = O stretching peak at 1704 cm −1 , but if adsorbed by PEG in (c), strong C-O-C stretching peak at 1114 cm −1 will be appeared attributed to the chemical structure of raw PEG. When the plasma irradiation takes place on the surface of (c), CH stretching peaks at 2915 and 2850 cm −1 in (d) are modified and deformation by cross linking structure on the PEG film surfaces.

Results and discussion
Finally, we measured the surface wettability of the treated and untreated powders using with capillary raise method as shown in Fig. 41. Surface wettability is normally measured by contact angle measurement of liquid droplet on the flat surface. However, the method is not usable for the particle surface. Figure 41 shows the capillary raise method for the surface wettability measurement of the powder.
The powder is stuffed in the tube then the bottom is stopped by the filter paper and soaked in the test liquid. The liquid is raising path through the clink of the powder particles then the raising height is measured with soaking time. In the method, the raising rate (dl/dt) of the liquid is shown by the Eq. (9). In the equation, r is the inside radius of the tube (6 mmϕ), η is the liquid viscosity, γ l is the liquid surface tension, θ is the contact angle of the surface, ∆p is the pressure difference between the outside and inside of the tube.
If ∆p is enough lower than outer pressure, Thus, l 2 is in proportion to the increasing time because the other factors (r, γ l cosθ, η) are constant. In the measurement, benzyl alcohol is used as the test liquid. The slope of Fig. 42 is attributed to the surface energy that contained constants in Eq. (10). As shown in Fig. 42, oxide PE has highest surface energy in the figure. Although the cross-linked PEG PE shows second higher value, it Binding energy / eV PEG on the PE should be chemically stable and biocompatible polymer layer in the air environment than that of oxide PE surfaces. Raw-PEG adsorbed PE show close values as in untreated PE. Probably adsorbed raw PEG molecule was dissolved in the benzyl alcohol.
The solubility in the water of the cross-linked PEG layer fabricated on the solid surface was tested by water resistance of the spin coated raw PEG layer on the glass surface. After APGD surface treatment, the raw-PEG surface became insoluble in the water.

Conclusion
We succeed the water insoluble polyethylene glycol films as a core shell of polymer powder by the combination techniques of adsorption of PEG on the powder surfaces and atmospheric glow discharge irradiation to the surface. The cross-linked PEG layer fabricated on the polymer powder show very hydrophilic nature on the surfaces.

Introduction
A fluoro-polymer layer on the inner surface of poly-vinyl chloride (PVC) tube increases its blood compatibility and suppresses the bleeding of plasticizers present in the commercial PVC. Furthermore, it is so difficult for the conventional Intensity (a.u.)

Binding energy / eV
Cross linked PEG low-pressure glow plasma to coat the inner surface of soft tubular structures due to the pressure differences between the tube inside and outside which will distort the walls (d 'Agostino 1990;Ratner 1992;Yasuda 1985;Occhiello et al. 1991;Suzuki et al. 1986;Griesser et al. 1994). The APGD system is useful in modifying materials by way of surface treatment, deposition, and surface etching similar to low pressure glow plasmas (Suwa et al. 1996;Breitbarth et al. 1990) even for inside of the fine tube. We report the application of APGD to fluorinate the inner surface of commercial poly(vinyl chloride) (PVC) tubes to enhance biocompatibility for a blood circulating tube.

Experimental
(1) Plasma treatment Figure 43 is a schematic representation of the system we used for the plasma polymer deposition. In the figure, double helix Cu electrodes are attached on the inside of the glass tubing. The sample PVC tubing is inserted in to the glass tubing. The mixture gas of monomer/He is introduced in the sample tubing. One side of the double helix Cu electrode is connected to the high voltage and the other side was connected to the ground. APGD between the electrodes will be immediately appeared in the sample tubing by turn on the high voltage power source. If we use the wind-up system of the tubing at the end side of the tube, we could apply for longer tubing treatment. We used 5 kV, 20 kHz power source to have the APGD for PVC tubing. The helium carrier gas and the monomer-tetrafluoroethylene (TFE) or hexafluoropropylene (HFP) pass through flow meters before being introduced into the mixing chamber, and then flow directly at atmospheric pressure into the PVC tubing, thereby APGD is limited in the inner surface of the PVC tubing. The standard conditions of treatment used to deposit the fluorocarbon layer are: the voltage was 5 kV and the frequency 20 kHz unless otherwise indicated. The frequency range is hugely different from that of the low-pressure plasma which is in the order of MHz (RF). The tubular discharge needs pair coil type electrodes. In the case, high frequency radio-wave cannot penetrate in to the pair coil electrodes because of the induction of itself. In the point of view of the convenient system, tube treatment system in APGD should be much better than that of used in the low-pressure discharge.
(2) Materials The monomer gases used, TFE and HFP, were obtained from PCR Inc. (Gainesville, FL). Both molecules have a double bond between two carbons. Their chemical compositions are C 2 F 4 and C 3 F 6 , respectively. Commercially available soft PVC tubes having internal diameter 6.5 mm and outer diameter 8.4 mm were used as received.
(3) Surface analysis techniques X-ray Photoelectron Spectroscopy (XPS) analyses were performed within a few days after plasma treatment with an ESCALAB 220i-XL XPS (VG instruments), using aluminum K α monochromatized X-ray source. The binding energy shift from the surface charging of the polymers was compensated with an electron flood gun set at 4 eV. The compositions of the surface were determined, in terms of chemical functionalities, with a Janssen Micro FT/IR-200 with ATR attachment (JASCO Corporation, Tokyo, Japan). The contact angles were meas-  ured by the sessile-drop technique. Briefly, a 2 μl droplet of redistilled water was placed onto the surface to be studied by a syringe with a micrometer driven plunger. The contact angles were then measured with a contact angle meter (FACE Contact Angle Meter, Kyowa Interface Science Co., Ltd, Tokyo, Japan). Contact angles were measured before and just after treatment on PVC tubes exposed to HFP/He or TFE/He APG plasmas for different treatment periods while all other parameters, flow rates, plasma frequency and plasma power were kept constant. Angles were averaged for 25 measurements (five essays at five different sites on a tube). (4) Biocompatibility of the surface To demonstrate the surface biocompatibility, the brood adhesion test was done using with fresh rabbit brood soaking of the treated surface. After brood soaking, the surface was analyzed by SEM observation.

Results and discussion
The change in contact angle on treatment with HFP/He APGD is presented in Fig. 44 (He flow rate: 1000 sccm; HFP flow rate: 2 sccm). It is observed from this Fig. that a layer of hydrophobic polymer, i.e., fluoro-polymer, is deposited rapidly on the PVC surface. The contact angles increased significantly in the first 3 min of plasma treatment. As treatment continued, the thickness of the layer increased but the degree of hydrophobicity of the outer surface remained the same. The contact angle of untreated commercial PVC tube was 90° and after helium plasma (i.e., etching processing without monomer) it was decreased to 75°. The contact angles of the surface after APG plasma treatment were about 98°, not as high as pure polytetrafluoroethylene (PTFE, 115°). The contact angles after each experiment were constant along the tube or within the same section, indicating a homogeneous deposition. The results after TFE/He APGD also showed a similar trend (data not shown). The change in contact angles from 75°to about 98° in the absence and presence, respectively, of the fluorine containing monomers showed that the hydrophobic behavior of the plasma-treated PVC is entirely due to the fluorinated monomers. The Fourier transform infrared (FTIR) attenuated total internal reflection (ATR) spectra (FTIR-ATR) of untreated PVC tube (Fig. 45, lower) showed an absorbance peak at about 1720 cm −1 which is due to carbonyl groups (C = O) in additives, such as plasticizers present in the commercial PVC. The peaks due to C-Cl bonds occurred at about 650-700 cm −1 . After both HFP/He (Fig. 45, upper) and TFE/He APG (Fig. 45, middle) plasma treatments, the carbonyl peak due to plasticizers decreased significantly. Since the analysis depth of the FTIR-ATR is about 1 μm, the thickness of the deposition was assumed to be very close to this value. We also observed a very intense absorption at about 1200 cm −1 due to fluorine-containing functional groups. The FTIR-ATR spectrum of the treated PVC tube which had undergone TFE/He APG plasma treatment resembled that of the HFP/He APG plasma treated PVC tube. However, the main peak of the TFE/He APG treated PVC surface was at 1200 cm −1 , while that of the HFP/He-treated PVC surface was at 1130 cm −1 , indicating that the structures of fluorine-containing plasma-deposited polymers differ slightly from each other. As to the TFE/He APG plasma treated PVC, the main peak consisted of two different absorbance bands from CF 2 υ asym and υ sym modes. The separation of these two absorbance bands indicates a rather linear polymer (Mackie et al. 1997). We calculated the ratio of absorbance of peaks typical of polymer deposition (at about 1200 or 1130 cm −1 ) to that of the carbonyl peak (plasticizer) typical of the commercial PVC tube to study the degree of polymer deposition. Figure 46 shows the absorbance ratio of the PVC surface after HFP/He APG plasma treatment with As the HFP flow rate was increased from 0 to 4 sccm, the deposition of fluoropolymer was increased. However, as the percentage of HFP in the gas mixture was increased further, the fluoro-polymer deposition was decreased. At a flow rate of HFP greater than 6 sccm, the absorbance ratio was reduced to that of an untreated sample, i.e., there was hardly any deposition. When the monomer flow rate is very low, deposition is limited by the monomer supply (the so-called "monomer-deficient region" (Nomura et al. 1984)). Deposition behavior at high monomer flow rates is related with APGD stability; that is, a large HFP/He ratio decreases the stability and efficiency of the APGD, and thus decreases the number of active species capable of effecting the polymer deposition. PVC tube was subjected to HFP/He APG treatment for different time intervals between 20 and 60 min at optimum gas flow conditions (2 sccm of HFP with 1000 sccm of helium). The optimum gas flow rate and treatment time for polymer deposition with TFE/He-APGD (i.e., 2.5 sccm of TFE with 600 sccm of helium for 20 min) have been investigated and reported earlier .
XPS is widely used for the analysis of polymer surfaces and especially plasmatreated or plasma-deposited polymers. With this technique we can obtain information on the chemical content of the surface up to a few nanometer depths of the polymer. Wide scan spectra of XPS were used to determine to identify and to estimate the amount of the elements present on the surface, and the high-resolution spectra of XPS were used to reveal the element-bonding environment. The XPS wide scan untreated and treated PVC are presented in Fig. 47. The untreated PVC XPS spectrum Fig. 47c showed a C 1s peak at about 285 eV. Cl peaks appear at 199 and 201 eV for Cl 2p , and 272 eV for Cl 2s . The weak intensity of the Cl peaks and the presence of the O 1s peak at 532 eV confirm the presence of plasticizers and other additional products in commercial PVC. In the XPS spectra of PVC tubes subjected to HFP/He APGD treatment and TFE/He APGD treatment, an intense peak occurred at 688.8 eV, corresponding to F 1s , with no trace of Cl peaks ( Fig. 47a and  b). The absence of Cl atoms at the surface of APGD-treated PVC is due to: (1) etching of chlorine atoms (the XPS wide scan spectrum of the He only plasma treated-PVC shows a decreased intensity of the Cl peak; not shown); and (2) concealment by polymer deposition. The weak O 1s peak which indicates the presence of a small amount of oxygen at the surface (about 3% of the atomic composition), is mainly due to post-plasma reactions between oxygen from the air and the freshly prepared and still-reactive surface. Table 6 shows the F/C ratio and relative percentages of the chemical functionality groups which is measured by high-resolution XPS (Prat et al. 2000) in APGDdeposited polymers. After TFE/He APGD treatment, the main contribution to the C 1s peak is from CF 2 (57.1% of total carbons), as expected, but small contributions from CF and CF 3 which arise from secondary reactions or to degradation of the newly deposited polymer, are also observed (18.6 and 11.3%, respectively, of total carbons). Nevertheless, these contributions (CF and CF 3 ) remain weak, as does the C-CF contribution indicating a rather weakly crosslinked surface. This is in contrast  Normally, the fluorocarbons deposited by low-pressure plasma treatments show a highly cross-linked surface. On the other hand, the ion bombardment, which enhances cross-linking in low pressure plasmas (Yasuda 1985), can be neglected in the APGD due to the decrease of ion velocity. From the reason, in the APGD, the weakly cross-linked surface will be mainly occupied. As with HFP/He APGD treatment, the PVC surface after TFE/He APGD is completely covered by the fluoropolymer (Kogoma et al. 1997) (i.e., hydrocarbons no longer contribute to the spectra), but chemical compositions and structure of the two deposited polymers are slightly different from each other. Although plasma treatment is an effective way of developing surface-specific novel materials, the experimental conditions of conventional low-pressure glow discharge treatment limit the nature and size of the materials to be modified. Continuous treatment, uneven materials, selectivity of treatment area etc. are some of those limitations. Even though plasticized PVC is commonly used for biomedical purposes, the presence of plasticizers (mainly di-2-ethylhexyl phthalate (DEHP)) is of much concern to the biological system. Hence, we attempted in this study to develop PVC supported biomaterials with fluoro-polymer surface coating by the APGD treatment of monomers like HFP and TFE onto the inner surface of PVC tubes. The characteristics of fluoro-polymers obtained using APGD treatment were similar in nature to those of other fluoro-polymers obtained by radio frequency glow discharge in low pressure (Kiaei et al. 1992;Castner et al. 1997;Golub et al. 1996) as reported earlier.
Finally, we have tried to test the biocompatibility of the treated surface using the adhesibility of fresh rabbit brood PRP. Photo 3 show SEM photographs of plasma coated PVC inner surfaces soaked with the fresh rabbit brood PRP. In the photographs, they are many adhesive platelets are found on the untreated PVC surface (a). On the other hand, on the TFE plasma treated surface (b), we have noting of adhesive platelets except of small amount of inactive one.

Conclusion
APG plasma treatment is a simple, inexpensive process that is useful in a wide variety of applications including the coating of the inner surface of commercial flexible PVC tubes with a PTFE-like polymer formed from HFP or TFE gaseous monomer. The tube discharge system can treat exceptionally long tubes even longer than 100 m with simply winding the tube. Deposition by APGD is homogeneous and its thickness is about 1 μm. The deposited fluorinated polymer layer can suppress the bleeding of plasticizers which are present in commercial PVC tubes. Small structural variations between HFP-treated surfaces and TFE-treated surfaces were clear from XPS and FTIR/ATR results. APGD-TFE plasma treated PVC shows excellent biocompatibility for the adhesion of brood platelet on the surface. To elucidate the unique features of the APGD, we are currently studying the gas phase with mass spectrometry and optical emission spectroscopy. The APGD-derived fluoro-polymers were similar to the conventional low-pressure plasma fluoro-polymers in properties even though the APGD is moderate in energy characteristics.

Introduction
Microwaves are incredibly attractive power sources from the points of view of the system convenience and the cost of power to produce discharges at atmospheric pressure. However, the temperature in a microwave discharge in atmospheric pressure is finally going to several thousand degrees of K even use of rare gas, such as in high pressure induction coupled plasma (Reed 1961). That should be due to the GHz high frequency discharge. The high temperature plasma needs a thermal ionization mechanism to retain high electric conductivity. Otherwise, the plasma cannot gain a high enough current to heat the plasma itself. Owing to this reason, the microwave plasma is not useful for the surface treatment for soft materials, such as polymers or organic materials in the atmosphere. To overcome the plasma instability from the insufficient ionization rate in low-temperature condition in microwave plasma, we need some other way to maintain electric conductivity. The use of metal electrodes is one of the most convenient devices to exhaust thermal electrons from the surface in moderate temperature conditions. In this study, we used several kinds of metal electrodes, such as tungsten and tantalum which one inserts into the plasma zone to create stable plasma at moderate temperature. Solid surface treatment or ashing of organic contamination on the silicon wafer that is placed in the atmospheric ambience was done in the after-glow plasma region. Figure 48 shows the schematics of the microwave discharge system in atmospheric pressure. The outer diameter of the quartz discharge tube is 15 mm. A discharge Photo 3 SEM photographs of plasma coated PVC inner surfaces soaked with the fresh rabbit brood PRP. a untreated PVC surface, b TFE plasma treated surface tube is inserted in the center of the wave-guide type cavity. The end of the discharge tube which is made by quarts glass is taper-shaped to make rectangular slit nozzle (2 mm × 13 mm). We used a 1 kW, 2.45 GHz magnetron generator for the discharge power source. Pulse width modulation (PWM) of the anode current of magnetron tube is applied to control the discharge power. Nitrogen (commercial grade and five-nine pure grades) is used for carrier gas and small amount of oxygen is introduced to produce active species for oxidation of organic impurities on the silicon substrate. A metal rod electrode (2 mmϕ, 20 mmlong) is inserted into the discharge tube to start and to maintain the discharge during the experiment. We tested several kinds of metals, such as W, Mo, Zr, Ta, Si, and 20% T h -containing W, for the electrodes. In the metals, because they need to have higher melting temperatures (− 3000 °C) and are protective against attacks of active nitrogen or oxygen atoms, only W and Ta are available for the microwave discharge as the electrodes. The flow gas is cooled by the water jacket surrounding the tube at the downstream position of the discharge part. The substrate is set in the atmosphere and is exposed to blown gas that exhausted from the nozzle; then one measures the thickness using the surface roughness meter (Dektak 3, Sloan Co. LTD).

Experimental
The treated surfaces were analyzed using XPS (ULVAC-Phi, ESCA 5800ci). The temperatures of blown gas and substrate surface are measured using a thermocouple. Photoemission from the discharge zone is measured using an optical fiber multi-spectrometer (Solar Co. LTD, type TII). Spin-coated OFPR-800 (photo-resist, 1200 nm thick) on a silicon wafer is used as model organic contamination to measure the ashing rate. Experimental conditions are shown in Table 7.

Results and discussion
When the power was introduced to the system, the discharge immediately started with strong light emission and noisy sound. Figure 49 shows the blown nitrogen gas temperature vs. distance from the edge as a function of discharge power in 15 slm of flow rate. The gas temperature increases with increasing of the discharge power. The maximum temperature at 600 W is lower than 180 °C even at 2 mm as the shortest distance in the experimental conditions. We attained a relatively low-temperature plasma gas flow with this system. The blown gas temperature decreases with increasing of the distance from the edge or transit time, this is caused by gas diffusing to the surrounding and mixing with air in atmosphere. Figure 50 shows the ashing rates vs. discharge power in 15 slm of nitrogen gas flow at the position 2 mm from the edge. In the figures, the ashing rates increase with increasing of discharge power. The ashing rates are at least about 300 nm·min −1 at 600 W. The ashing rate in this system is almost the same rate related to that of the low-pressure oxygen plasma (Fujimura et al. 1991). Figure 51 shows the ashing rates vs nitrogen gas flow rate or transit time to the substrate as a function of discharge power. The half -life of the active flow is about 0.2 ms in air ambience. The decreasing of the flow rate slower than 7.8 slm in 600 W, it raises discharge instability and causes rapid dispersion in the air ambience. Figure 52 shows the ashing rates vs. distance (d/mm) from the substrate to the tube edge at the power of 500 W with using commercial grade nitrogen. In the figure, the ashing rates show almost no change between 2 and 6 mm and decrease with further increasing of the distance. The main reason of decreasing for distances longer than 6 mm will be the diffusion of after-glow flow in to the air. On the other hand, in case of He after-glow in the atmospheric pressure ambience, the ashing rates are rapidly decreased with increasing of transit time; the decrease is about 4-5 orders of magnitude with increasing of the transit distance from 2 to 6 mm . In this regard, the life time of the active species should be very long in nitrogen after-glow. The difference of the life time of active species in the after-glow flow between nitrogen and He will be attributed to the difference of the molecular weight.
From the point of the view of oxidation of organic impurities, a question will arise about what is the active agent in the discharged nitrogen is. In the case of the commercial grade nitrogen, a trace amount of oxygen molecule will be mixed in the system. To resolve the question, we tried to measure the ashing rates in three different concentrations of oxygen mixed in pure nitrogen. Figure 53 shows the ashing  Distance, d / mm rates vs. discharge power for different oxygen concentration in nitrogen. We used pure nitrogen (5-nine grade), commercial grade (about lower than 100 ppm of oxygen impurity) and 1300 ppm of oxygen mixture. Even in different concentrations of oxygen mixed in nitrogen, the ashing rates are not so much affected. It seems as if the nitrogen active species only works in the oxidation kinetics on the substrate. On the other hand, as shown in Fig. 54, in the ashing rate vs. oxygen concentration in pure nitrogen, we can find a sharp increasing attained at around of 130 ppm oxygen concentration. From both figures, it seems that the active species in oxygen-mixed nitrogen are not only active nitrogen ( S ), such as meta-stable molecules (nitrogen atoms do not have high enough activities to the organic reactant) but also oxygen atoms. Figure 55a shows the photo emission spectra of 130 ppm oxygen-mixed nitrogen discharge in 500 W of the power. We can find nitrogen 1st positive band (503.0-750.3 nm), 2nd positive band (281.4-497.6 nm) and small peak of oxygen atom emission at 502 nm. Figure 55b) shows the spectra between 200 and 350 nm region with three different oxygen concentrations. In the 1300 ppm oxygen mixed nitrogen, NO γ system was found in region from 231 to 290 nm. In general, NO γ system will due to the reaction (14): Power / W The fact confirms that the meta-stable molecules exist in the nitrogen discharge. However, the NO γ system disappears in concentrations lower than 130 ppm of oxygen. This disappearance should be attributed to the lack of NO concentration in the discharge zone. Ashing reaction on the treated surface should be mainly attributed to the oxidation by oxygen atoms. Figure 56 shows the intensity ratios between nitrogen emissions (388 nm) to oxygen atom emission (502 nm) as a function of oxygen concentration. Because Figs. 54 and 56 show very analogous configurations, the oxygen atom should be an important etching specie in relatively low concentration Concentration of O 2 in N 2 / ppm oxygen mixtures. When we increase the oxygen concentration at least higher than 130 ppm, oxygen atoms will be consumed by increasing of the NO chain reactions that consume O atoms in Eqs. (16) and (17): Treated sample surface was analyzed by XPS to estimate the erosion of metal electrode which will be deposited on the treated surface. In the case of the commercial grade N 2 as for carrier gas, trace amount of tungsten oxide was found on the treated sample surface because small amount of O 2 that was mixed in the N 2 as the impurity, eroded the electrode. On the other hand, nothing of tungsten oxide was found on the treated surface with using pure N 2 .

Conclusions
We succeeded in producing a low-temperature remote plasma system using microwave discharge and atmospheric pressure nitrogen flow. Relatively high ashing rates of about 600 nm·min −1 for organic contamination were attained in the system. We assumed that the main active species for ashing reaction should be oxygen atoms in the oxygen mixed nitrogen flow. Nitrogen is a very promising material as a carrier gas for ashing or cleaning of the surfaces at atmospheric pressure without of electrode erosion, because the gas cost is much cheaper than that of He (1/20) or Ar (1/10).

General conclusion
Applicable frequency for generating the APGD ranges from several kHz to higher than hundred MHz. It should be noted that the gas temperature during the treatment generally increases as the frequency increases. In the atmospheric pressure lowtemperature discharge, a pulse modulated discharge will be recommended to drive down the gas temperature. It will be important to control the plasma density and the increasing of the gas temperature, for instance, by adding on-off pulse modulated signals on a simple continuous sinusoidal wave of high voltage. Films can be treated by placing them on the electrode using parallel type or at the after-glow region in the remote type. However, several types of treatments have been developed to fulfill the requirements for treating substrates of different shapes (e.g., tube, continuous film, small sphere, powder, printed circuit board, fiber, etc.).
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