Skip to main content
SpringerLink
Log in

A europium(III) metal-organic framework as ratiometric turn-on luminescent sensor for Al3+ ions

基于含铕金属-有机框架的比率turn-on型铝离子发光传感器

  • Letter
  • Published:
Science China Materials Aims and scope Submit manuscript

摘要

文制备了三种同构镧系金属有机框架材料(Me2NH2)[Ln2L2(NO3)-OH)(H2O)]·2H2O·2DMA, (Ln = Eu(1), Gd(2) and Tb(3), H2L =9-甲基-9-羟基-2,7-芴二羧酸, DMA = 二甲基乙酰胺). 研究结果显示它们具有三维阴离子型框架结构, 该结构可简化为含有单一的8连接型节点的体心立方(bcu)型拓扑结构. 化合物1表现出基于配体的荧光发射峰以及铕离子的特征荧光发射峰. 荧光实验表明在DMF溶液中Al3+会明显增强配体的荧光强度, 而对Eu3+的荧光强度影响却很小, 这使得1成为了优秀的比率式发光Al3+传感器. 在Al3+浓度处于0.02-0.1 mmol L—1范围内时, 配体与Eu3+荧光强度的比值与Al3+浓度成正比(斜率为18,502 mol—1 L). 本文证实了配体9位的羟基与Al3+之间的相互作用是引起配体荧光增强的主要原因.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. Allendorf MD, Bauer CA, Bhakta RK, et al. Luminescent metal–organic frameworks. Chem Soc Rev, 2009, 38: 1330–1352

    Article  Google Scholar 

  2. Cui Y, Yue Y, Qian G, et al. Luminescent functional metal–organic frameworks. Chem Rev, 2012, 112: 1126–1162

    Article  Google Scholar 

  3. Rocha J, Brites CDS, Carlos LD. Lanthanide organic framework luminescent thermometers. Chem Eur J, 2016, 22: 14782–14795

    Article  Google Scholar 

  4. Li L, Zhu Y, Zhou X, et al. Visible-light excited luminescent thermometer based on single lanthanide organic frameworks. Adv Funct Mater, 2016, 26: 8677–8684

    Article  Google Scholar 

  5. Cui Y, Xu H, Yue Y, et al. A luminescent mixed-lanthanide metal–organic framework thermometer. J Am Chem Soc, 2012, 134: 3979–3982

    Article  Google Scholar 

  6. Cui Y, Song R, Yu J, et al. Dual-emitting mof⊃dye composite for ratiometric temperature sensing. Adv Mater, 2015, 27: 1420–1425

    Article  Google Scholar 

  7. Hu Z, Deibert BJ, Li J. Luminescent metal–organic frameworks for chemical sensing and explosive detection. Chem Soc Rev, 2014, 43: 5815–5840

    Article  Google Scholar 

  8. Li L, Chen Q, Niu Z, et al. Lanthanide metal–organic frameworks assembled from a fluorene-based ligand: selective sensing of Pb2+ and Fe3+ ions. J Mater Chem C, 2016, 4: 1900–1905

    Article  Google Scholar 

  9. Liu B, Hou L, Wu WP, et al. Highly selective luminescence sensing for Cu2+ ions and selective CO2. capture in a doubly interpenetrated MOF with Lewis basic pyridyl sites. Dalton Trans, 2015, 44: 4423–4427

    Article  Google Scholar 

  10. Hao JN, Yan B. A water-stable lanthanide-functionalized MOF as a highly selective and sensitive fluorescent probe for Cd2+. Chem Commun, 2015, 51: 7737–7740

    Article  Google Scholar 

  11. Dou Z, Yu J, Cui Y, et al. Luminescent metal–organic framework films as highly sensitive and fast-response oxygen sensors. J Am Chem Soc, 2014, 136: 5527–5530

    Article  Google Scholar 

  12. Hu Z, Tan K, Lustig WP, et al. Effective sensing of RDX via instant and selective detection of ketone vapors. Chem Sci, 2014, 5: 4873–4877

    Article  Google Scholar 

  13. Li A, Li L, Lin Z, et al. Guest-induced reversible structural transitions and concomitant on/off luminescence switching of an Eu(III) metal–organic framework and its application in detecting picric acid. New J Chem, 2015, 39: 2289–2295

    Article  Google Scholar 

  14. Wang L, Fan G, Xu X, et al. Detection of polychlorinated benzenes (persistent organic pollutants) by a luminescent sensor based on a lanthanide metal–organic framework. J Mater Chem A, 2017, 5: 5541–5549

    Article  Google Scholar 

  15. Cheng T, Hu J, Zhou C, et al. Luminescent metal-organic frameworks for nitro explosives detection. Sci China Chem, 2016, 59: 929–947

    Article  Google Scholar 

  16. Zhou J, Li H, Zhang H, et al. A bimetallic lanthanide metal-organic material as a self-calibrating color-gradient luminescent sensor. Adv Mater, 2015, 27: 7072–7077

    Article  Google Scholar 

  17. Zhang SY, Shi W, Cheng P, et al. A mixed-crystal lanthanide zeolite-like metal–organic framework as a fluorescent indicator for lysophosphatidic acid, a cancer biomarker. J Am Chem Soc, 2015, 137: 12203–12206

    Article  Google Scholar 

  18. Zhao M, Yuan K, Wang Y, et al. Metal–organic frameworks as selectivity regulators for hydrogenation reactions. Nature, 2016, 539: 76–80

    Article  Google Scholar 

  19. He L, Liu Y, Liu J, et al. Core-shell noble-metal@metal-organicframework nanoparticles with highly selective sensing property. Angew Chem Int Ed, 2013, 52: 3741–3745

    Article  Google Scholar 

  20. Wang T, Jia Y, Chen Q, et al. A new luminescent metal-organic framework for selective sensing of nitroaromatic explosives. Sci China Chem, 2016, 59: 959–964

    Article  Google Scholar 

  21. Wang S, Ma R, Chen Z, et al. Solvent-and metal-directed lanthanide-organic frameworks based on pamoic acid: observation of slow magnetization relaxation, magnetocaloric effect and luminescent sensing. Sci China Chem, 2016, 59: 948–958

    Article  Google Scholar 

  22. Li B, Wen HM, Cui Y, et al. Emerging multifunctional metalorganic framework materials. Adv Mater, 2016, 28: 8819–8860

    Article  Google Scholar 

  23. Zhao M, Deng Z, Tang J, et al. 2-(1-Pyrenyl) benzimidazole as a ratiometric and “turn-on” fluorescent probe for iron(III) ions in aqueous solution. Analyst, 2016, 141: 2308–2312

    Article  Google Scholar 

  24. Gupta VK, Jain AK, Maheshwari G. Aluminum(III) selective potentiometric sensor based on morin in poly(vinyl chloride) matrix. Talanta, 2007, 72: 1469–1473

    Article  Google Scholar 

  25. Deng M, Wang S, Liang C, et al. A FRET fluorescent nanosensor based on carbon dots for ratiometric detection of Fe3+ in aqueous solution. RSC Adv, 2016, 6: 26936–26940

    Article  Google Scholar 

  26. Patidar R, Rebary B, Bhadu GR, et al. Fluorescent carbon nanoparticles as label-free recognizer of Hg2+ and Fe3+ through effective fluorescence quenching in aqueous media. J Lumin, 2016, 173: 243–249

    Article  Google Scholar 

  27. Diao Q, Ma P, Lv L, et al. A water-soluble and reversible fluorescent probe for Al3+ and F- in living cells. Sensors Actuators BChem, 2016, 229: 138–144

    Article  Google Scholar 

  28. Pithadia AS, Lim MH. Metal-associated amyloid-β species in Alzheimer’s disease. Curr Opin Chem Biol, 2012, 16: 67–73

    Article  Google Scholar 

  29. Gauthier E, Fortier I, Courchesne F, et al. Aluminum forms in drinking water and risk of Alzheimer’s disease. Environ Res, 2000, 84: 234–246

    Article  Google Scholar 

  30. Flaten TP. Aluminium as a risk factor in Alzheimer’s disease, with emphasis on drinking water. Brain Res Bull, 2001, 55: 187–196

    Article  Google Scholar 

  31. Fu Y, Jiang XJ, Zhu YY, et al. A new fluorescent probe for Al3+ based on rhodamine 6G and its application to bioimaging. Dalton Trans, 2014, 43: 12624–12632

    Article  Google Scholar 

  32. Afshani J, Badiei A, Lashgari N, et al. A simple nanoporous silicabased dual mode optical sensor for detection of multiple analytes (Fe3+, Al3+ and CN-) in water mimicking XOR logic gate. RSC Adv, 2016, 6: 5957–5964

    Article  Google Scholar 

  33. Xu XY, Yan B. Eu(III)-functionalized MIL-124 as fluorescent probe for highly selectively sensing ions and organic small molecules especially for Fe(III) and Fe(II). ACS Appl Mater Interfaces, 2015, 7: 721–729

    Article  Google Scholar 

  34. Dong XY, Wang R, Wang JZ, et al. Highly selective Fe3+ sensing and proton conduction in a water-stable sulfonate–carboxylate Tb–organic-framework. J Mater Chem A, 2015, 3: 641–647

    Article  Google Scholar 

  35. Liang YT, Yang GP, Liu B, et al. Four super water-stable lanthanide–organic frameworks with active uncoordinated carboxylic and pyridyl groups for selective luminescence sensing of Fe3+. Dalton Trans, 2015, 44: 13325–13330

    Article  Google Scholar 

  36. Chen Z, Sun Y, Zhang L, et al. A tubular europium–organic framework exhibiting selective sensing of Fe3+ and Al3+ over mixed metal ions. Chem Commun, 2013, 49: 11557–11559

    Article  Google Scholar 

  37. Cao LH, Shi F, Zhang WM, et al. Selective sensing of Fe3+ and Al3+ ions and detection of 2,4,6-trinitrophenol by a water-stable terbium-based metal-organic framework. Chem Eur J, 2015, 21: 15705–15712

    Article  Google Scholar 

  38. Zhang M, Han J, Wu H, et al. Tb-MOF: a naked-eye and regenerable fluorescent probe for selective and quantitative detection of Fe3+ and Al3+ ions. RSC Adv, 2016, 6: 94622–94628

    Article  Google Scholar 

  39. Spek AL. Single-crystal structure validation with the program PLATON. J Appl Crystlogr, 2003, 36: 7–13

    Article  Google Scholar 

  40. Blatov VA, O’Keeffe M, Proserpio DM. Vertex-, face-, point-, Schläfli-, and Delaney-symbols in nets, polyhedra and tilings: recommended terminology. CrystEngComm, 2010, 12: 44–48

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (21271143), Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) (YX03001), Jiangsu Province Double Innovation Talent Program (090300014001), Nanjing University of Posts & Telecommunications (NY212004).

Author information

Authors and Affiliations

  1. Key Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, Nanjing, 210023, China

    Xinhui Zhou  (周馨慧), Jiahui Cheng  (程嘉荟), Liang Li  (李亮), Qiang Chen  (陈强), Yujian You  (游宇健) & Wei Huang  (黄维)

  2. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035, China

    Hongping Xiao  (肖洪平)

  3. Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University, Nanjing 211816, China

    Wei Huang  (黄维)

Authors
  1. Xinhui Zhou  (周馨慧)
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jiahui Cheng  (程嘉荟)
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Liang Li  (李亮)
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Qiang Chen  (陈强)
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yujian You  (游宇健)
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Hongping Xiao  (肖洪平)
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Wei Huang  (黄维)
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Xinhui Zhou  (周馨慧) or Wei Huang  (黄维).

Additional information

Xinhui Zhou received his Bachelor degree from Dalian University of Technology in 2001, his Master degree from Shantou University in 2006, under the supervision of Prof. Dan Li and his PhD degree from Nanjing University in 2009, under the supervision of Prof. Jinglin Zuo. He joined the Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications in 2009. His research interests are focused on the MOF-based luminescent sensing materials.

Wei Huang received his PhD degree from Peking University in 1992. In 1993, he began his postdoctoral research at the National University of Singapore. In 2001, he was appointed as a chair professor of Fudan University, where he founded and chaired the Institute of Advanced Materials (IAM). In 2006, he was appointed vice president of Nanjing University of Posts & Telecommunications. In 2012, he was appointed the president of Nanjing Tech University. Now, he is the vice president of Northwestern Polytechnical University. He was elected as Academician of the Chinese Academy of Sciences in 2011. His research interests include organic/plastic materials and devices, nanomaterials, and nanotechnology.

Electronic supplementary material

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhou, X., Cheng, J., Li, L. et al. A europium(III) metal-organic framework as ratiometric turn-on luminescent sensor for Al3+ ions. Sci. China Mater. 61, 752–757 (2018). https://doi.org/10.1007/s40843-017-9186-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40843-017-9186-3

Search

Navigation