A Feasibility Study to Minimize the Carbon Footprint of Cast Iron Production While Maintaining the Technical Requirements

The industrial sector is responsible for significant amounts of CO2 emissions. Although research activities have already given their attention to major industries such as steel, small sectors such as metal casting have been overlooked. Therefore, there are evident knowledge gaps regarding the environmental impact of the foundry industry and the possibilities of decarbonizing the sector. Herein, this study focuses on the CO2 emissions associated with cast iron production and introduces an interdisciplinary framework in order to study the environmental impact, technical performance and production costs. The theoretical and experimental analyses illustrate the interconnections between the environmental, technical and economic aspects of cast iron production. The results emphasize the role of the smelting process and renewable energies in decreasing the carbon footprint. In terms of the input materials, the outcomes demonstrate that increasing the steel scrap content achieves considerable reductions in the CO2 emissions. An alloy composition with a steel scrap content of 25% leads to a minimum carbon footprint of 650 kg CO2 eq./ton. However, increasing the steel scrap content further results in higher carbon footprints due to the additional materials required to maintain the alloy composition. Moreover, a higher strength and lower ductility of the alloy were recorded due to higher amounts of carbide stabilizing elements. The study highlights the importance of adopting a holistic approach in order to define the optimal material combinations. Hence, the presented interdisciplinary approach can be applied by the foundries in order to achieving the technical, economic and ecological goals of the sector.


Introduction
Climate change has enforced the major industrial economies to set environmental goals to mitigate their greenhouse gas (GHG) emissions. For example, the EU has committed to become carbon-neutral by 2050 and Germany wants to achieve this goal even earlier (i.e. 2045) [1]. Herein, the industrial sector has major responsibilities due to the significant amounts of CO 2 emitted by the different industries. The German industries are responsible for 23% of the total annual GHG emissions in Germany due to its process and energy-related emissions, in addition to the indirect emissions related to power consumption [2]. The casting industry is classified as an energy-intensive sector, which means that it also has to deal more intensively with the topic of CO 2 savings. In Germany, metal casting consumes significant amounts of energy such as natural gas, coke and electricity, in addition to the emissions embedded in the inputs such as pig iron. Energy transition incurs both opportunities and challenges for the foundry industry. On the one hand, the industry is the main provider of crucial components for the sector of renewable energies such as cast gears, shafts and hubs for the wind turbines [3,4]. On the other hand, decarbonizing the sector is associated with various challenges due to its characteristics like small-scale plants and many products and processes.
In a few words, metal casting refers to shaping the respective metal via melting and molding [5]. Depending on the application and required properties, several alloys can be used such as cast iron, steel, aluminum, etc. The sector yields several sophisticated products and intricate designs, some of which are key inputs for other high-value products such as wind energy parts, automotive, and machines. There are approximately 600 foundries in Germany, which secure 70.000 jobs and achieve a turnover of 12.5 billion EUR [6,7]. In total, the German foundry industry produces more than 5 Mt cast metals, 75% of which are cast iron products [8]. Cast iron alloys are commonly classified into lamellar graphite cast iron (LGI), compacted graphite cast iron (CGI) and spheroidal graphite cast iron (SGI) [9]. For the melting process, various furnaces are currently adopted by the producers such as cupola and induction furnaces.
So far, the production technique has been based on the product's specifications and associated costs. However, reducing the carbon footprint necessitates a new factor, which is the direct and embedded emissions. Although the foundry industry is typically known as environmentallyfriendly sector as scrap metals are the main input material [10], this notion is intrinsically not fully correct as the current production processes consume significant amounts of fossil fuels or electricity produced via fossil energy. Moreover, the industry consumes various input materials such as pig iron and inoculants, which have significant amounts of embedded emissions. While there is an extensive number of studies investigating the different technical aspects of the cast iron production, there is an obvious lack of research addressing the environmental impacts. The analysis of [11] is one of the few studies addressed the topic. The authors compared between the carbon footprint of three materials used in the automotive industry (i.e. thin-wall ductile cast iron, conventional cast iron and cast aluminum), while considering the whole life cycle. Herein, the authors used a parametric model to calculate the associated emissions based on the masses and consumed energy, including the use phase. The study of [12] also aimed at comparing between two materials (i.e. cast iron and aluminum) by considering all the material and energy flows along the life cycle (a cradle-to-grave approach). Similarly, the analyses of [13][14][15] compared between the environmental impacts of cast iron and other materials such as aluminum, steel, plastics and concrete. However, as can be deduced, these studies do not address the production process of cast iron itself and how the carbon footprint can be minimized. Other studies such as [16,17] presented more detailed environmental analyses regarding the impacts of casting and molding processes. Nonetheless, they do not indicate practical measures or alternative possibilities to mitigate the CO 2 emissions.
In the few studies that addressed the topic, there is an agreement regarding the crucial role of energy consumption in minimizing the carbon footprint. However, in addition to energy-efficient melting and the switch to renewable energies, there is a great potential to mitigate the CO 2 emissions via the input materials. According to our best knowledge, no study has addressed this topic despite its importance in minimizing the carbon footprint of cast iron products. A recent study of [18] highlighted the significance of the theme, however, the analysis focused on zinc and also did not integrate a technical assessment. A standard cast iron alloy usually contains up to 20% pig iron which is associated with high GHG emissions during the production process (1.45 t CO 2 eq./t pig iron in a modern blast furnace [19]). One way to reduce these emissions is to use a higher amount of steel scrap during the production process. Hence, the aim of this research is to present comprehensive analyses regarding the possibility of minimizing the environmental impact of the cast iron products via using more secondary inputs (i.e. steel scrap).
Herein, the study focuses on the production of ductile cast iron, which is also referred to as spheroidal graphite cast iron (SGI). According to the European standard for ductile iron alloys, DIN EN 1563, it can be classified into the conventional ferritic-pearlitic grades [20]. Due to the comparatively low notch effect of the nodular graphite precipitates, it can show elongations of 22% at fracture with an ultimate tensile strength (UTS) of 350 Mpa. Depending on the pearlite content set, strengths of up to 900 Mpa can likewise be achieved with still 2% elongation at fracture. While the fully ferritic grades are very ductile materials due to a high elongation at fracture, pearlitic grades have increasingly higher strength and are wear resistant. The combination of ductility, strength and good castability allows ductile iron to be widely used material in mechanical engineering, power engineering and the automotive industry [4,21,22]. In terms of melting technology, cupola or medium frequency induction furnaces are usually used. While cupola furnace depends on fossil fuels, the induction furnace is supplied with electric energy [23].
In order to evaluate the process route of cast iron holistically, it is necessary to evaluate both the metallurgical and technological criteria. In particular, microstructural aspects as well as mechanical properties have to be still achieved to ensure a continued competitiveness of cast iron alloys and further enable technical applications. Hence, the ecological analysis is accompanied with experimental casting trials to produce the respective samples and perform the required tests to examine their microstructural and mechanical properties. Moreover, a cost analysis has been conducted in order to explore the impact on the production expenses. In the following section, the methodological framework of the techno-economic and environmental (TEE) assessment is first explained and the investigated material and samples are presented. Thereafter, the results and outcomes are discussed in "Results and Discussion". Finally, "Conclusions and Outlook" presents the main conclusions and outlook for future research.

Methdology and Materials
In order to develop a suitable methodological approach, the relevant studies on similar problems have been reviewed. Promoting sustainability in the industrial sector necessitates developing integrative methods in order to realize the required interdisciplinarity. This is particularly indispensable if the technical, economic and environmental performances can be influenced by the introduced measures simultaneously. While Life Cycle Assessment (LCA) or carbon footprint can assess the direct and indirect environmental impact of the available alternatives, an interdisciplinary evaluation approach is required to investigate if the economic and technical performances are competing with the environmental measures (i.e. in the sense of a trade-off).
Therefore, TEE assessments have been used in various studies addressing similar questions. For example, the sensitivity analyses of [11] investigated the impact of different steel scrap and pig iron ratios on the carbon footprint. Herein, the study assumed that that these changes will only influence the environmental impact of the different cases. However, such assumption overly simplifies the situation as the such variations are also associated with changes in the metallurgical properties, which necessitate technical analyses. According to our best knowledge, no studies in the literature have yet adopted an evident integrative approach 1 3 to address sustainability in the field of casting production. Nonetheless, relevant approaches have been developed by studies addressing material recycling in other industries. For example, the recent studies of [24,25] assess the recovery processes of alumina from aluminum dross from the economic and environmental perspectives, while [26][27][28][29] conducted various TEE assessments on plastic recycling.
Methodologically, these studies implement scenario analysis by means of assessing the techno-economic and environmental performance of different systems or applications. Herein, LCA or carbon footprint are used to evaluate the environmental impact and the associated costs are quantified to assess the techno-economic performance. Accordingly, the optimum system or option can be selected via comparing the investigated scenarios. However, the technical assessment is usually omitted from these analyses, and the techno-economic assessment focuses mainly on the costs. Thus, these approaches usually assume that the technical performance or the final outputs are similar with regards to material properties and quality. For example, it is assumed that the recycled plastic will have the same functions and properties regardless of the recycling process. Although such assumptions can be accepted for some materials, they cannot be applied to cast products. Therefore, this study follows the same approach via implementing TEE assessments, but also considers the technical aspects via examining the mechanical properties and microstructural characteristics of the relevant samples.
As shown in the study's framework (Fig. 1), the research procedure can be divided into three parts. Firstly, a literature research was conducted in order to define the CO 2 -intensive processes, materials and mitigation potentials in the cast iron production. In order to study the possibility of minimizing the carbon footprint via the material inputs (i.e. steel scrap and pig iron), six different alloys, referred to as alloy I-VI, were defined in order to be investigated. Alloy I contains 15.2 wt% pig iron and no scrap steel, which serves as the reference alloy. Alloys II-V contain 25, 40, 60 and 75 wt% of steel scrap, respectively, with no pig iron addition. To study the effect of the amount of steel scrap, these alloys were studied experimentally in casting trials and subsequent analyses. 75 wt% of steel scrap was chosen as the maximum amount, as steel scrap fraction of up to 80% are used in industrial environment. Alloy VI can be regarded as a "mixed" alloy composed of equal shares of pig iron and steel scrap (8 wt% each).
Herein, the required additives (e.g. carburizing agent, ferrosilicon FeSi75, etc.) have been added to the samples to be eventually comparable to the composition of the reference alloy EN-GJS-400-15 according to DIN EN 1563 (C = 3.5 wt%, Si = 2.5 wt%, Mn < 0.2 wt%, P < 0.03 wt%, S < 0.02 wt%, Mg = 0.04 wt%). The detailed charging composition of all investigated alloys is depicted in Fig. 2. After defining the system boundaries and collecting the required economic and environmental inventories, the carbon footprints and the relevant costs of the different compositions are then calculated. Simultaneously, a series of four experimental tests was carried out in order to analyze the effect of increasing steel scrap content of the respective samples.

Environmetal and Economic Assessments
The environmental assessment (i.e. carbon footprint) has been conducted in accordance with ISO 14067 [30]. Herein, the analysis is classified into four phases (i.e. goal and scope definition, inventory analysis, impact assessment and interpretation). In terms of goal and scope (i.e. first phase), the study investigates the possibility of minimizing the environmental impact of the cast iron products via using more secondary inputs (i.e. steel scrap). Hence, the scope and boundaries of the analyses are the input materials and the processes of charging and smelting. As shown in system boundaries (Fig. 3), the study does not take into account all upstream and downstream processes that are not impacted by the charging composition, such as mold fabrication. Also, the treatment of the kiln exhaust gases was discarded as its environmental impact doesn't influence the analyses. As the main study's objective is to investigate the different charging compositions and the effect of increasing steel scrap content on the microstructure and mechanical performance, one ton of liquid cast iron that fulfills the specifications of EN-GJS-400-15 was selected as a functional unit. This unit ensures an intuitive understanding of the result variables and good comparability with the results of other studies either on cast iron or other metallic alloys such as [11,15]. The same system boundaries, inputs and functional unit have been also used to derive the production cost of each alloy.  (Tables 1 and 2) are collected for the second phase (i.e. inventory analysis). As the emission factors of some materials were not found in the Ecoinvent database (version 3.5) [31], their values have been adopted based on [32][33][34]. The carbon emissions associated with transportation are based on the distance between the materials' manufacturers and the location of analyses (i.e. NRW). As all alloying elements (except pig iron) are produced in Germany, it is assumed that they have been transported via trucks. For pig iron, different transportation modes were used as it is produced outside Germany (i.e. Brazil). The value of estimated distances are indicated in Tables 3 and 4. In terms of energy, the required amount to melt one ton of cast iron is normally in the range of 500-1000 kWh, depending on the carbon content [35]. Herein, a survey was conducted to ask some regional producers about their specific energy consumption, which results in a lower range (i.e. 450-750 kWh/ton). Hence, an average value of 650 kWh/ton was considered for the analyses.
The steel scrap and waste ductile iron are considered end-of-life flows and thus their carbon footprint is assumed as zero. It should be noted that the allocation of the environmental impact is a controversial topic in the environmental assessments while addressing waste streams and byproducts. For example, if the environmental impact should be allocated based on the mass or the monetary value. The studies of [36,37] explain numerous allocation methods and show their significant impact on the outcomes. Also,  the studies of [38][39][40][41] address the theme of metal recycling and suitable methods to determine the environmental impact associated with the produced metals and scrap. According to [42,43], there is no one right allocation method and the analysts normally have flexibility while modelling. As there is no clear agreement on one superior approach, this study adopts a cutoff approach, via which the carbon footprint is calculated within the defined system boundaries. Therefore, the environmental impact is allocated to the primary production and no environmental burdens are allocated to the waste streams. This approach has already been used by other studies such as [44], which considered a zero carbon footprint for the steel scrap used in the steel production process. For the third phase (i.e. impact assessment), the calculations have been implemented via OpenLCA software (version 1.10.3) using the collected life cycle inventories [45]. As study focuses on the carbon footprint, the impact category of global worming potential (GWP100) was selected and (CML-IA baseline) was used as a life cycle impact assessment (LCIA) method. The last phase (i.e. interpretation) is discussed in the following section (results and discussion) along with the economic and technical assessments. For the economic assessment, the prices of material inputs have been retrieved based on the purchasing prices of a German foundry located in North Rhine-Westphalia (NRW).

Technical Assessment
To conduct the experimental tests, 250 kg of casting batches of alloys II-V were produced based on waste ductile iron (EN-GJS-400-15), ferrosilicon (FeSi75), steel scrap and a carburizing agent. The steel scrap used is a low-alloy stamping scrap from a profile stamping machine. The chemical compositions of this consumed steel scrap (steel No. 1) is illustrated in Table 5. For melting of the alloys, a 250 kg medium-frequency induction furnace from Otto Junker was used. The ingot materials were heated and melted to 1520 °C. This temperature was held for approximately 5 min in order to remove the impurities from the melt. Subsequently, 1.3 wt% of Mg pre-alloy (VL 63O) was placed onto the bottom of a treatment and pouring ladle. At 1520 °C the melt was poured into the treatment ladle for conducting the magnesium treatment. By adding magnesium to the melt, a nodular graphite morphology is obtained in the as-cast microstructure. After deslagging the melt surface, 0.35 wt% of cerium-containing inoculant SMW 605 is stirred into the melt just before pouring in order to ensure stable solidification of carbon. Cerium acts as a graphite nucleating agent in the inoculant and favors graphite precipitation during solidification of the alloy. Due to the availability, the cover scrap used for alloys II and V was steel No.1, and No.2 for alloys III and IV, according to Table 5.
After the Mg treatment and inoculation, the melt was poured at approximately 1380 °C. For each alloy, two of the casting geometries indicated in Fig. 4 was produced, which consisted of two Y II standard test blocks, one Y IV standard test block according to DIN EN 1563 and one additional insulated cylinder [48,49]. Therefore, the casting blocks are represented with a thermal modulus of 0.96 cm (Y II ), 1.74 cm (Y IV ) and 3.29 cm (cylinder) serving as an indicator for the solidification time. The corresponding cooling curves and solidification times are given in Fig. 5. For each casting geometry one metallographic specimen of each test block was machined for metallographic analyses. Additionally, one tensile test specimen out of Y II -and two tensile test specimens were machined out of both Y IV -and cylinder geometries, respectively. The tensile specimens are taken from the test blocks according to the positions marked in red in  Fig. 4 and a length of 110 mm. The quasi-static tensile tests are then carried out according to EN ISO 6892-1 [50]. The specimens marked in green in Fig. 4 are used as metallographic specimens. The specimens are ground stepwise with silicon carbide grinding paper and then polished with a diamond suspension. Following the preparation steps, a digital image analysis is performed. Graphite analysis is used for this purpose and is carried out in accordance with DIN EN ISO 945-4 standard [51]. For this purpose, five images are taken of each specimen at ×100 magnification with a resolution of 2600 × 2600 pixels. Subsequently, the images are characterized using ImageJ image analysis software. To be considered as graphite particles, there must be a minimum graphite particle area of 25 μm. A detailed qualitative evaluation of the adjusted microstructure is carried out by taking pictures of the cast specimens in the Nital-etched state using a Nital-solution consisting of 3% HNO 3 and 97% alcohol (C 2 H 5 OH). Immediately after etching, five images are taken of each sample under the light microscope at ×100 magnification. Following the image acquisition, the pearlite content is also quantified using the ImageJ software.

Carbon Footprint and Costs
The carbon footprint and the relevant costs of the investigated samples are depicted in Fig. 6. The carbon footprint of alloy I is the highest (868.5 kg CO 2 eq./ton), of which more than 50% is attributed to the energy required for melting Fig. 5 Representative cooling curves for specimen locations in the casting geometries that were produced according to [52] (M values are the thermal modulus of the specimen) Fig. 6 The carbon footprint and costs of the relevant inputs and approximately 30% is the embedded emissions of the pig iron input (i.e. 145.9 kg CO 2 eq.). Contrariwise, adding 25 wt% steel scrap (i.e. alloy II) results in the lowest carbon footprint (lower than 650 kg CO 2 eq./ton). Such significant reduction can be attributed mainly to abandoning the pig iron. Increasing the steel scrap content to 40% in alloy III has caused a minor retreat in the emissions savings, as the carbon footprint has reached 677 kg CO 2 eq./ton. By adding low-alloyed steel scrap, the silicon and carbon content of a cast iron alloy decreases considerably. To compensate for this deficit, corresponding carbon and silicon-containing materials must be added to the alloy (i.e. carburizing agent and FeSi75). However, the production of these inputs is accompanied with significant CO 2 emissions (i.e. 3.5 and 4 t CO 2 eq./ton, respectively).
Therefore, adding more steel scrap in the next samples (i.e. IV and V) is associated with a continuous increase in the carbon footprint. However, the carbon footprints of the samples with steel scrap are still lower than sample I. Finally, the mixed alloy (sample VI) has approximately the same carbon footprint as sample V. Despite the low proportion of steel scrap and relinquishing the carburizing agent and FeSi75, the embedded emissions of the pig iron increase the final value. In terms of the costs, sample II also has the best outcome and recorded the lowest costs (approximately 300 EUR/t). Counterintuitively, the alloy with the highest steel scrap (i.e. sample V) has the highest production costs, due to the need to add more expensive additives in order to meet the required specifications.
Herein, it should be highlighted that there are some differences between the conditions in the lab and in industrial facilities that can influence the outcomes slightly. The energy requirement for melting depends, among other things, on the quality of the input materials. For example, clean input materials (i.e. water-, oil-and rust-free) can reduce the combustion as well as the amount of generated slag. A specific energy of approximately 500 kWh/t can be assumed for slagging the sand associated with input materials and a similar consumption can be expected for the rusted materials [53]. For example, if the steel scrap used in alloy V contains 5% impurities, an additional 19 kWh will be required, resulting in approximately 14 kg CO 2 eq. emissions. Herein, it is of particular importance that the scrap used is blasted beforehand to remove any unnecessary residues. Another aspect, which is normally monitored in the laboratory, is the composition of the materials. Knowing the precise compositions of the consumed materials can enable the operator to specify the required charge and electricity input. As a result, the material and energy requirements can be minimized, which means that melting times can be shortened and the operations can be optimized.
Moreover, recovering the waste heat can also decrease the associated carbon emissions. As discussed, the process heat required for the melting process is by far the most energyintensive process in the foundry industry. Hence, using this heat efficiently afterwards is one of the best ways to achieve CO 2 savings. However, this heat is currently released into the environment as an unused source of energy in many foundries. There are already various examples of how this waste heat can be utilized. For example, the air in the hall and the water in sanitary facilities can be heated with the exhaust air from air compressors [54]. The waste heat can also be used to dry raw and input materials. This process reduces melting times, which in turn reduces the energy requirement. However, the operation times is one of main challenges, as the thermal energy is often only available for a few hours per day when the material is being melted. Hence, storing this heat (e.g. via a heat accumulator) is mandatory in order to be able to use it as an energy source at other times.

Sensitivity Analysis and Validation
As the cutoff approach allocates no emissions to the steel scrap and waste ductile iron, the study conducts a sensitivity analysis in order to illustrate the impact of secondary resources' footprint on the outcomes. Herein, an emission factor of 200 kg CO 2 eq./ton is assumed for the steel scrap and waste ductile iron. 1 Additionally, a sensitivity analysis is conducted for the scrap price, as the price of steel scrap has been increasing in the last years and the figure used in the basic analysis is relatively high compared with the price in 2016 (below 200 EUR/ton) [56]. Therefore, a lower steel scrap price (i.e. 200 EUR/ton) has been considered in the sensitivity analysis to illustrate the relevant impact on costs. The results of both changes are illustrated in Fig. 7. As expected, the carbon footprint has increased with various intensities due to the different steel scrap and pig iron content in the alloys. Although alloy II still has the lowest carbon footprint (i.e. 837 kg CO 2 eq./ton), it recorded the highest increase (i.e. 29.1%). Alloy I also still has the highest carbon footprint (i.e. 1031 kg CO 2 eq./ton), but its relative increase is the lowest (i.e. 18.7%). As can be seen, the impact of the steel scrap price also depends on the alloys' compositions. While the costs of alloy I remains the same, the costs of alloy V decreases 18% to 341.7 EUR/ton, which is the highest relative and absolute decrease.
To validate the environmental and economic analyses, the results have been compared with other studies. The study of [11] reported 300 kg CO 2 eq. for producing 248.5 kg cast iron, which can be converted to approximately 1.2 ton CO 2 eq./ton cast iron. Also, the study of [15] concluded 706 kg CO 2 eq. for manufacturing one ton cast iron. As this study's outcomes range between 650 and 1030 kg CO 2 eq./ton cast iron, the calculated values can be considered reasonable. The deviations between the values can be explained by the different system boundaries, alloy compositions and differing carbon footprints of the inputs. For example, the calculations of [11] used higher emission factors for pig iron and ferrosilicon alloy. For the associated costs, the average ductile cast iron price at the factory gate in NRW is 1437.5 EUR/t [57]. In addition, according to [58], the materials and energy inputs contribute to 40% of the final costs. Therefore, the calculated costs of the investigated flows should be reasonable (277-417 EUR/t) as the calculations did not include some materials such molding and energy inputs such as warmth maintenance.

Technical Performance
In order to make sure that the alloys fulfill the standard requirements when steel scrap and additives are used, alloys II-V were produced and studied with regard to their chemical composition and microstructural and mechanical properties.

Chemical Composition
All alloys were produced and casted in accordance with ductile iron grade EN-GJS-400-15 (DIN EN 1563). Hence, a targeted carbon content of 3.4 wt% and silicon content of 2.5 wt% was set for each alloy. However, for producing the alloys, different contents of steel scrap and recycled material Fig. 7 The sensitivity analysis of the carbon footprint and costs were used according to Fig. 2. As indicated in Table 6, the carbon and silicon contents could be held quite constant by setting different amounts of steel scrap and recycled material. Furthermore, the magnesium, aluminum and copper contents remain constant regardless of the selected composition of the charging. The variations of the residual magnesium content between the individual alloys of approximately 0.02 wt% are considered to be process-dependent. However, it can be noted that the chromium and manganese content exhibit a significant increase due to the growth of the steel scrap content from 25 wt% in alloy II to 75 wt% in alloy V. Above steel scrap contents of 40 wt%, significant Cr contents of 0.056 wt% occur. The Mn content, on the other hand, increases continuously with increasing steel scrap content up to 0.378 wt% in alloy V. Based on the chemical compositions that have been shown, ferrite and pearlite formation temperatures T α and T p and the eutectoid temperature interval were calculated according to [59], indicated in Eqs. 1-3. 2 The results of these calculations are shown in Fig. 8. It can be observed that the stable eutectoid temperature decreases significantly more than the metastable eutectoid temperature with increasing steel scrap content. This leads to a reduction of the eutectoid temperature interval with increasing steel scrap content in the alloy. The reason for this is the increased content of pearlite-stabilizing elements, including in particular Cr and Mn. Due to the reduction of ΔT, an increased pearlite content has to be expected in the corresponding alloys. In order to verify this hypothesis, microstructural analyses were further carried out with the aim of quantifying the respective phase fractions of the alloy (graphite, matrix phase). Figure 9 shows representative microstructural images for the study after Nital-etching of alloys II-V, arranged in order of increasing steel scrap content from top to bottom and increasing thermal modulus from left to right. With higher steel scrap content, an increasing pearlite content can be observed. All of the produced alloys show significant pearlite fractions from about 25 to 50%. This confirms the previously assumed difficulties associated with the use of steel scrap or the accompanying elements contained within it.

Microstructure
Herein, there is an overlapping of different effects. On the one hand, less pearlite is generated at larger moduli. On the other hand, a higher graphite nodule count leads to shorter carbon diffusion paths. As a result, ferrite formation instead of pearlite formation is promoted in these areas. Furthermore, there is a clear trend indicating higher pearlite contents with increasing thermal modulus, as confirmed by Fig. 10. At low thermal modulus, higher undercooling occurs and therefore a higher nodule count is generated leading to shorter diffusion paths for carbons during further solidification and cooling. Therefore, carbon atoms must diffuse to existing graphite precipitates in a shorter time range. A lower carbon diffusion time leads to a higher roundness of graphite particles and a higher nodularity of the sample. Figure 11 summarizes the effect of different steel scrap additions on both the pearlite fraction in the microstructure and the eutectoid transformation interval. Figure 12 shows the results of the graphite analysis using automatic image evaluation. In the four-test series, there is no noticeable difference with regard to nodularity. Comparing a casting modulus of 0.8 cm with a higher wall thickness, it is noticed that the thinner components have a higher nodularity in most cases, which is corresponding to the literature [9,60]. The nodularity of the 0.8 cm module is on average 70%. In contrast, the average nodularity of the larger wall thicknesses is 49%. The count of graphite nodule decreases with increasing thermal modulus. For a casting modulus of 3.29 cm, the average nodule count is 73 1/mm 2 . In contrast, the casting modulus of 0.8 cm exhibits a nodule count of 179 1/mm 2 on average (+ 105 1/mm 2 ). (1)

Mechanical Properties
As shown in Fig. 13, the minimum requirement for tensile strength (UTS = 400 MPa for a wall thickness of up to 30 mm according to DIN EN 1563) has been achieved in all adjusted alloys. In some cases, the strengths are well above 500 MPa. The UTS increase significantly with increasing the steel scrap content. For example, it exhibits a UTS of 490 MPa at a steel scrap content of 25% and 610 MPa at a content of 75% steel scrap. A significant correlation between the pearlite fraction in the microstructure and the UTS can be observed from Fig. 14. The influence of the modulus on the strength is reflected in a decrease in strength; this applies across the board to all steel scrap contents. The standard specifies a yield strength of 250 MPa for the material EN-GJS-400-15. This value was exceeded in all samples, as indicated in Fig. 15. The same trend as for the tensile strength can be observed, with similar or slightly decreasing values from 25 to 60 wt% steel scrap content. Alloy V shows a strongly increased yield strength. The desired elongation at fracture of 15% could be achieved in specimens with moduli of 0.96 and 1.74 cm up to a content of 60 wt% steel scrap (see Fig. 16). It can be noted that the elongation at fracture of the cylindrical specimens of up to 5.5% is significantly lower. When 75 wt% steel scrap is used in alloy V, no sufficient elongation at fracture was found in any of the cases investigated, so this alloy does not meet the requirements of EN-GJS-400-15 and cannot be used. This observation is attributed to the higher amount of pearlite-and carbidestabilizing elements that are added to the melt due to higher amounts of steel scrap. Maximum amounts of Mn in alloy V and a pearlite content of 52% in the microstructure confirm these results, as they are acting as crack initiation sites during the mechanical testing of the alloys.

Conclusions and Outlook
The analyses have clearly depicted the correlation between the technical, economic and environmental aspects of the cast iron production. The environmental analyses show that the addition of steel scrap up to a content of 60 wt% results in significant CO 2 savings compared to an alloy with 15 wt% pig iron and no steel scrap. Therefore, using steel scrap is superior from an environmental perspective. However, exceeding a certain threshold (i.e. 25 wt%) can lead to a relapse due to the ferrosilicon and carbon that have to be added (to yield comparable composition and technical performance), which have high embedded carbon emissions. For the investigated alloys, the use of steel scrap is recommended with a content between 25 and 40 wt% with lower emissions of 25 wt%. A comparable result could be taken from the cost calculations; the costs also increase with the steel scrap content due to the required expensive additives such as ferrosilicon and carburizing agents. The results of this study show that the use of steel scrap is only profitable up to just under 40 wt% from an economic point of view.
Similar conclusions can be also drawn from the results of the experimental tests. It can be seen that the mechanical    properties according to DIN EN 1563 could be safely achieved or slightly exceeded at low moduli for all investigated alloys. However, the required elongation at fracture could not be achieved in alloy V with an addition of 75 wt% steel scrap due to the increased pearlite content in the microstructure. The reason for this is the elevated content of pearlite-stabilizing elements, in particular Mn, that originate from the steel scrap. Comparing the different results, it becomes apparent that the use of steel scrap up to a proportion of 60 wt% can be recommended from a technical and metallurgical perspective, as both the UTS, YS and elongation at fracture are met according to the technical requirements (UTS = 400 MPa, YS = 250 MPa, A = 15% for wall thicknesses lower than 30 mm). However, the limiting factor is the wall thickness which lowers the mechanical properties generally. However, the elongation at fracture remains the critical factor, as it decreases due to the increased pearlite content as a result of the higher steel scrap contents. For a steel scrap content of 75 wt%, an elongation at fracture of only 12.9% is achieved in a wall thickness of 25 mm.
Apart from the input materials, energy consumption is generally responsible for the largest proportion of the carbon footprint. Therefore, minimizing the energy requirements and recovering the waste heat can lead to lower GHG emissions. Herein, the existing practices in the foundries should be further investigated and available efficiency measures have to be adopted. Moreover, shifting the electricity mix towards more renewable energies should result in a carbon-neutral melting process. Herein, eliminating the fossilbased technologies such copula furnace and increasing the share of electricity-based ones such as induction furnaces are also crucial. Similarly, adopting more climate-neutral production processes for the other material inputs can reduce the embedded emissions such as employing iron reduced via hydrogen or using biogenic carbon and carbon capture and storage (CCS) while producing the other inputs.
The framework presents a scientific frame by which the technical, economic and environmental impacts can be investigated and optimized. The main advantage of the presented method is the possibility to be adopted easily by the foundries. It is a very cost-effective approach as it does not need innovative technologies with high capital costs such as furnaces. However, the study is still introductory and further analyses have to be performed. As increasing the steel scrap consumption by the cast industry can influence the supply in the steel industry, intersectoral analyses will be needed to determine where steel scrap should be used to achieve the best environmental impact. Also, the analyses focus on a specific type of cast iron and certain alloys. Therefore, further alloys and metals have to be investigated.
The industry should consider all the CO 2 -intensive processes in foundries. Due to the variety of the casting technologies and the large number of products, a "onesolution-fits-all" approach will be ineffective. Hence, more investigations and better classification are needed in order to derive diverse mitigation strategies that can suit a widerange of the producers. Conducting such investigations and adopting sophisticated measures also necessitates systematization and acquiring all energy-related data in the foundries. Therefore, establishing energy management systems is also mandatory in order to improve the energy use continuously and achieve the planned energy savings.
There are some limitations and uncertainties of the presented outcomes. First, although the study strived for considering actual industrial parameters such as prices and emission factors, these values may not be the same for all producers, especially in other regions. Second, some laboratory practices may not be adopted in the foundries and vice versa, such as scrap cleaning. Third, the study used a certain type of the melting furnace, while the foundries may use other furnaces with different efficiencies and energy consumption. Fourth, the study adopted a cutoff approach and scenario analysis for the carbon footprint of secondary inputs. Hence, using another allocation approach can result in different outcomes and conclusions. Therefore, additional studies are needed to compare allocation methods in order to derive an agreed-upon approach. Moreover, the environmental analysis focused exclusively on determining the carbon footprint of different alloys. Therefore, integrating more environmental impact categories could provide more insights and conclusions.