Abstract
Electroplating wastewaters are composed of a mixture of metallic ions. The process commonly applied to treat these residues generates a large amount of toxic sludge and does not allow metal recovery. In this context, the use of an adsorption technique to separate the metallic ions from the wastewater and recuperate it by desorption was proposed. For the process to be more environmentally interesting, a solid residue from the agro-industry was used as an adsorbent: the powder of passion fruit shells. The adsorbent was characterized by SEM, TEM, BET, FTIR, and pH-PZC. The adsorption experiments were carried out in monoelementary solution of Ni2+, Cu2+, and Zn2+—to analyze the fit to the kinetic and isotherms models—and in the multi-elementary electroplating wastewater. The desorption was evaluated with three eluents. The results obtained show the effectiveness of the process in mono- and multi-elementary solutions, reaching an adsorption capacity of 44.82 mg g−1 for Ni2+, 1.10 mg g−1 for Cu2+, and 0.20 mg g−1 for Zn2+ on the wastewater. The three ions showed a better fit to the Freundlich isotherm model. Zn2+ was adjusted to pseudo-second order, Cu2+ to Elovich model, and Ni2+ to pseudo-first order. It was possible to recover more than 99% of Zn2+ and Ni2+, and 45% of Cu2+ using acid eluent. Therefore, the method proposed in this study was effective to recover the metallic ions in electroplating wastewater, opening up the possibility of treating these wastes in an eco-friendly way.
Graphical Abstract
Similar content being viewed by others
References
de Brião GV, de Andrade JR, da Silva MGC, Vieira MGA (2020) Removal of toxic metals from water using chitosan-based magnetic adsorbents: a review. Environ Chem Lett 18:1145–1168. https://doi.org/10.1007/s10311-020-01003-y
Ramos BP, Menezes GO, Boina RF, Paiano MS (2019) Casca de maracujá como adsorvente de íons metálicos em efluente de galvanoplastia. Braz. J Dev 5:6076–6091. https://doi.org/10.34117/bjdv5n6-119
Singh V, Ram C (2016) Physico-chemical characterization of electroplating industrial effluents of chandigarh and haryana region. J Civ Environ Eng. https://doi.org/10.4172/2165-784X.1000237
Cardoso SL, Costa CSD, da Silva MGC, Vieira MGA (2020) Insight into zinc(II) biosorption on alginate extraction residue: kinetics, isotherm and thermodynamics. J Environ Chem Eng 8:103629. https://doi.org/10.1016/j.jece.2019.103629
Ali RM, Hamad HA, Hussein MM, Malash GF (2016) Potential of using green adsorbent of heavy metal removal from aqueous solutions: adsorption kinetics, isotherm, thermodynamic, mechanism and economic analysis. Ecol Eng 91:317–332. https://doi.org/10.1016/j.ecoleng.2016.03.015
Chaturbedi A, Patil S, Ramachandran R, Shapley NC (2020) Adsorption of positively and negatively charged heavy metal ions from wastewater by heteroaggregates of biopolymer particles. Colloids Surf A Physicochem Eng Asp 602:124789. https://doi.org/10.1016/j.colsurfa.2020.124789
Saxena A, Bhardwaj M, Allen T, Kumar S, Sahney R (2017) Adsorption of heavy metals from wastewater using agricultural–industrial wastes as biosorbents. Water Sci 31:189–197. https://doi.org/10.1016/j.wsj.2017.09.002
Zhu R, Chen Q, Zhou Q, Xi Y, Zhu J, He H (2016) Adsorbents based on montmorillonite for contaminant removal from water: a review. Appl Clay Sci 123:239–258. https://doi.org/10.1016/j.clay.2015.12.024
Singh NB, Nagpal G, Agrawal S, Rachna, (2018) Water purification by using adsorbents: a review. Environ Technol Innov 11:187–240. https://doi.org/10.1016/j.eti.2018.05.006
Faria DL, Lopes TA, Mendes LM, Guimarães Júnior JB (2020) Valorization of wood shavings waste for the production of wood particulate composites. Matéria (Rio Janeiro). https://doi.org/10.1590/s1517-707620200003.1080
Hsu L-C, Tzou Y-M, Chiang P-N, Fu W-M, Wang M-K, Teah HY, Liu Y-T (2019) Adsorption mechanisms of chromate and phosphate on hydrotalcite: a combination of macroscopic and spectroscopic studies. Environ Pollut 247:180–187. https://doi.org/10.1016/j.envpol.2019.01.012
RochaScarattiMoura-Nickelda SilvaGurgel Adeodato VieiraPeraltaPeraltade NoniPeralta Muniz Moreira ACCGCDTLMRMRAARF (2020) Economical and technological aspects of copper removal from water using a geopolymer and natural zeolite. Water Air Soil Pollut 231:361. https://doi.org/10.1007/s11270-020-04722-8
Bergna D, Hu T, Prokkola H, Romar H, Lassi U (2020) Effect of some process parameters on the main properties of activated carbon produced from peat in a lab-scale process. Waste Biomass Valorization 11:2837–2848. https://doi.org/10.1007/s12649-019-00584-2
FAO (2020) World food and agriculture—statistical pocketbook 2020. FAO, Rome
Clarke REJ, Bloom SR, Tan T (2016) Encyclopedia of food and health, 1st edn. Elsevier, New York
Tovar AK, Godínez LA, Espejel F, Ramírez-Zamora R-M, Robles I (2019) Optimization of the integral valorization process for orange peel waste using a design of experiments approach: production of high-quality pectin and activated carbon. Waste Manage 85:202–213. https://doi.org/10.1016/j.wasman.2018.12.029
Anderson SJ, Sposito G (1991) Cesium-adsorption method for measuring accessible structural surface charge. Soil Sci Soc Am J 55:1569–1576. https://doi.org/10.2136/sssaj1991.03615995005500060011x
Instituto Adolfo Lutz (2008) Métodos Físico-Químicos para Análise de Alimentos, 4th ed. São Paulo
APHA APHA (2017) Standard methods for the examination of water and wastewater, 23rd ed.
Silva EL, Pipi ARF, Magdalena AG, Piacenti-Silva M (2020) Aplicação dos modelos de Langmuir e Freundlich no estudo da casca de banana como bioadsorvente de cobre (II) em meio aquoso. Matéria (Rio Janeiro). https://doi.org/10.1590/s1517-707620200002.1056
Abdelaziz OY, Hulteberg CP (2017) Physicochemical characterisation of technical lignins for their potential valorisation. Waste Biomass Valorization 8:859–869. https://doi.org/10.1007/s12649-016-9643-9
da Silva JS, da Rosa MP, Beck PH, Peres EC, Dotto GL, Kessler F, Grasel FS (2018) Preparation of an alternative adsorbent from Acacia Mearnsii wastes through acetosolv method and its application for dye removal. J Clean Prod 180:386–394. https://doi.org/10.1016/j.jclepro.2018.01.201
da Rosa MP, Igansi AV, Lütke SF, Sant’Anna Cadaval TR, do Santos ACR, de Oliveira Lopes Inacio AP, de Almeida Pinto LA, Beck PH (2019) A new approach to convert rice husk waste in a quick and efficient adsorbent to remove cationic dye from water. J Environ Chem Eng 7:103504. https://doi.org/10.1016/j.jece.2019.103504
Beakou BH, El Hassani K, Houssaini MA, Belbahloul M, Oukani E, Anouar A (2017) A novel biochar from Manihot esculenta Crantz waste: application for the removal of Malachite Green from wastewater and optimization of the adsorption process. Water Sci Technol 76:1447–1456. https://doi.org/10.2166/wst.2017.332
Mondal S, Majumder SK (2019) Honeycomb-like porous activated carbon for efficient copper (II) adsorption synthesized from natural source: kinetic study and equilibrium isotherm analysis. J Environ Chem Eng 7:103236. https://doi.org/10.1016/j.jece.2019.103236
Wang Y, Feng Y, Zhang X-F, Zhang X, Jiang J, Yao J (2018) Alginate-based attapulgite foams as efficient and recyclable adsorbents for the removal of heavy metals. J Colloid Interface Sci 514:190–198. https://doi.org/10.1016/j.jcis.2017.12.035
Guo X, Wang J (2019) A general kinetic model for adsorption: theoretical analysis and modeling. J Mol Liq 288:111100. https://doi.org/10.1016/j.molliq.2019.111100
Giles CH, MacEwan TH, Nakhwa SN, Smith D (1960) Studies in adsorption. Part XI. A system of classification of solution adsorption isotherms, and its use in diagnosis of adsorption mechanisms and in measurement of specific surface areas of solids. J Chem Soc. https://doi.org/10.1039/jr9600003973
Neelaveni M, Santhana Krishnan P, Ramya R, Sonia Theres G, Shanthi K (2019) Montmorillonite/graphene oxide nanocomposite as superior adsorbent for the adsorption of Rhodamine B and Nickel ion in binary system. Adv Powder Technol 30:596–609. https://doi.org/10.1016/j.apt.2018.12.005
Jing N, Zhou AN, Xu QH (2018) The synthesis of super-small nano hydroxyapatite and its high adsorptions to mixed heavy metallic ions. J Hazard Mater 353:89–98. https://doi.org/10.1016/j.jhazmat.2018.02.049
Es-sahbany H, Berradi M, Nkhili S, Hsissou R, Allaoui M, Loutfi M, Bassir D, Belfaquir M, El Youbi MS (2019) Removal of heavy metals (nickel) contained in wastewater-models by the adsorption technique on natural clay. Mater Today Proc 13:866–875. https://doi.org/10.1016/j.matpr.2019.04.050
Ngabura M, Hussain SA, Ghani WAWA, Jami MS, Tan YP (2018) Utilization of renewable durian peels for biosorption of zinc from wastewater. J Environ Chem Eng 6:2528–2539. https://doi.org/10.1016/j.jece.2018.03.052
Mohammadi R, Azadmehr A, Maghsoudi A (2021) Enhanced competitive adsorption of zinc and manganese by alginate-iron oxide-combusted coal gangue composite: synthesizing, characterization and investigation. J Environ Chem Eng 9:105003. https://doi.org/10.1016/j.jece.2020.105003
Demiral H, Güngör C (2016) Adsorption of copper(II) from aqueous solutions on activated carbon prepared from grape bagasse. J Clean Prod 124:103–113. https://doi.org/10.1016/j.jclepro.2016.02.084
White RL, White CM, Turgut H, Massoud A, Tian ZR (2018) Comparative studies on copper adsorption by graphene oxide and functionalized graphene oxide nanoparticles. J Taiwan Inst Chem Eng 85:18–28. https://doi.org/10.1016/j.jtice.2018.01.036
Acknowledgements
The authors are grateful to São Paulo Research Foundation (FAPESP) for the financial support of this study (Grant Number 2015/09170-1 and Grant Number 2016/22976-8).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Additional information
The contributing editor for this article was João António Labrincha Batista.
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Ramos, B.P., Perez, I.D., Wessling, M. et al. Metal Recovery from Multi-elementary Electroplating Wastewater Using Passion Fruit Powder. J. Sustain. Metall. 7, 1091–1101 (2021). https://doi.org/10.1007/s40831-021-00398-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40831-021-00398-4